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Platinum Metals Rev., 1958, 2, (4), 146

Subject Index to Volume 2

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a =abstractPage
Alkyl- α-furyl-carbinols, selective hydrogenation, a 139
Amines, preparation, a 103
toxicity to catalysts, a 33
toxicity in chlorobenzene hydrogenation, a 103
Ammonia, catalytic oxidation, early developments 129
kinetics 85
toxicity to catalysts, a 33
2-Butyne-1, 4-diol, electrolytic hydrogenation with various cathodes, a 137
electrolytic partial hydrogenation of, a 31
Catalysis,
catalyst selection, a 67
for hydroisomerisation of waxes, a 33
reaction rate, increase by radiation of reactant, a 67
study by graphical method, a 102
theory of active atomic groupings, a 138
Catalysts,
choice of for selective behaviour, graphical treatment 124
dilute-supported in the chemical industry, a 138
electron bonds & catalytic properties, a 102
Palladium, pharmaceutical manufacture 86
recombination of radiolytic gases, a 32
selective oxidation in organic chemistry, a 33
structure, dependence on pre-treatment, a 31
Pd-Al2O3, deuterium-hydrocarbon reactions, a 67
α-methylstyrene hydrogenation, kinetic studies, a 32
Pd-BaSO4, hydrogen sorption, dependence on quantity of catalyst and carrier, a 139
hydrogenation of quinols & quinol acetates, a 68
Pd-black, determining structure of indole alkaloids, a 104
Pd-C, hydrogen sorption, dependence on quantity of catalyst & carrier, a 139
hydrogenation of olefins, rate studies, a 31
perhydrogenation of rosin, a 103
preparation of amines & hydrazo compounds, a 103
selective hydrogenation of alkyl- α-furyl-carbinols, a 139
Pd-CaCO3, hydrogenation of 20-dehydrocholesteryl acetate, a 139
(Lindlar), synthesis of pseudoionone homologues, a 68
Platforming, new-type 23
Platinised nickel-chromium, oxidation of SO2 & H2S, a 67
Platinised platinum, SO2 oxidation, a 67
Platinum, butane isomerisation 89
gauze, ammonia oxidation kinetics 85
in HCN manufacture 7
in HNO3 manufacture, a 102
in the U.S.S.R., a 102
hydrogenation of 20-dehydrocholesteryl acetate, a 139
iron ore reduction with hydrogen, a 32
methane combustion mechanism, a 102
HNO3 manufacture, early developments 129
oxidation of waste gases, a 32
pharmaceutical manufacture 86
platinised, potential of, a 31
reactions of hydrocarbon radicals on, a 32
Pt-Al2O3, electron diffraction of, a 67
flue gas combustion, a 68
heat recovery from refinery gases, a 68
lyophilic colloid, a 102
α-methylstyrene hydrogenation, kinetic studies, a 32
in Oxycat unit 110
petroleum reforming, research in the U.S.S.R., a 139
Pt-Al2O3-Cl, hydroisomerisation of paraffin wax, a 33
Pt-Al2O3-SiO2, n -nonane hydrogenation, a 103
Pt-black, thermal activation & deactivation, kinetics, a 138
toxicity of ammonia & amines, a 33
Pt-C, addition of triethylsilanc to methyl methacrylate, a 104
isomerisation of tetrahydrofuran homologues, a 139
selective oxidation in organic chemistry, a 33
PtO2, amine toxicity in chlorobenzene hydrogenation, a 103
hydrogenation of indole alkaloid derivatives, a 104
selective oxidation in organic chemistry, a 33
surface area & poisoning resistance, a 138
Pt-SiO2, petroleum reforming in U.S.S.R. 91, 139
Pt-SiO2-Cl, hydroisomerisation of paraffin wax, a 33
Pt-silica gel, thermal activation & deactivation, kinetics, a 138
Pt-supported, in HCN manufacture 7
Platinum Metals, deuterium-hydride reactions, a 67
review, a 138
Rh-Al2O3, chemisorption of CO, a 67
Cathodic Protection,
of oil-well casing, current requirements for, a 68
platinum-faced Ti anodes for 45, 104
review, a 33
Cermets, platinum metals in 53
Chlorobenzene, hydrogenation, toxicity of amines to catalysts, a 103
20-Dehydrocholesteryl Acetate,
hydrogenation, a 139
Deuterium, electrolytic separation from hydrogen, a 137
reactions with hydrocarbons, a 67
saturated hydrides, a 67
Electrical Contacts,
contamination, examination by plastic replica method 94
iridium-platinum in Electro-matic traffic control 12
metal migration, a 69
palladium, erosion mechanisms, a 140
metal transfer, dependence on current & inductance, a 69
in relays for line selector, a 104
palladium-silver-gold, effect of dust on, a 68
platinum metals & alloys as, review, a 140
selection of materials, a 104
Electrochemical Control Devices, ‘solions’, a 69
Electrodeposition of,
Iridium 60
Palladium, from KOH solutions, a 137
mechanical stresses in, a 137
Rhodium, effect of additives on, a 137
electronic applications, a 105
in homopolar generator 54
& other platinum metals, technical uses, a 137
Electrodes,
Iridium, oxygen coating on, a 65
Palladium, behaviour in oxidising solutions, a 30
-black, hydrogenation of 2-butyne-1, 4-diol, a 137
cathode, separation of hydrogen & deuterium, a 137
mechanism of hydrogen producing reactions, a 31
oxide film formation, dependence on c.d. & pH, a 137
& palladium-nickel cathodes, hydrogen producing mechanisms, a 100
Pd-D, comparison with Pd-H, a 101
Pd-H cathodes, effect of pH on hydrogen producing reactions, a 101
potential-determining mechanisms, a 66
Platinum, action of cations on polarisation potential, a 65
anode, effect of oxidation on behaviour, a 100
in partial hydrogenation of 2-butyne-1, 4-diol, a 31
for perchlorate preparation, a 66
for persulphate manufacture, surface, state, a 100
-based cathode in electron tubes, a 140
behaviour in oxidising solutions, a 30
-carbon, use in electron microscopy, a 99
cathode, hydrogen isotope separation on, a 101
hydrogenation of 2-butyne-1, 4-diol, a 137
in long-life valves, a 140
in thermionic valve 2
for use in dissolution of reactor fuel elements, a 101
-coated Ti anodes, use in industrial electrolysis 127
effect of a.c. on oxygen overpotential in H2SO4 solution, a 65
on insulation ageing of ceramic dielectrics, a 104
in electrochemical control devices, a 69
-faced Ti anodes 45, 104
gas-bubble formation on in H2O electrolysis, a 31
hydrogen evolution mechanism on, a 30
oxide films on, a 15
formation, dependence on c.d. & pH, a 137
investigation, a 30
Electro-matic Traffic Control, Ir-Pt contacts in 12
Electron Tubes with clean electrodes, Pt cathode in, a 140
Ethylene, chemisorption & surface reactions on Pd, a 139
Fuel Elements, stainless steel-UO2, dissolution of, a 101
Fume Elimination, from catalytic cracker, a 68
Oxycat unit, description & use 110
from paint stoving plant, a 103
Furnaces, electric resistance, design of 38
for use with X-ray diffractometer, a 66
Pt-Rh, automatic temperature programming & recording, a 66
Glass fibre formation, mechanism of 82
production, a 34
lithium silicate, effect of Pt on
crystallisation, a 68
-metal bonds, wettability of to Pt, a 33
seals, new method, a 138
Homopolar Generator, Rh plating in 54
Hydrazo Compounds, preparation, a 103
Hydrocyanic Acid, manufacture 7
Hydrogen, diffusion through Pd 16
isotopes, electrolytic separation, a 137
factor on metal electrodes, a 101
measurement of when dissolved in water, a 138
mechanism of diffusion through Pd, a 64
Hydrogen Sulphide, catalytic oxidation, a 67
Indole Alkaloids, oxidation-reduction studies, a 104
Iridium,
corrosion of metals in contact with, a 136
crucibles for high temperature use 83
research on & uses, review, a 135
thermal e.m.f., stability of, a 135
Iridium Alloys,
Iridium-Palladium, constitution, a 30
Iridium-Silicon, structure of IrSi, a 65
Iridium-Tantalum, sigma phase, a 30
Iron Ore, catalytic reduction with hydrogen, a 32
Mercury Vapour Lamps, reducing infra-red radiation 128
Methane, combustion, mechanism, a 102
Methyl Methacrylate, addition to triethylsilane, a 104
α-Methylstyrene, hydrogenation of, kinetic studies, a 32
Nitric Acid Manufacture, development, a 102
early developments 129
new plant, a 102
in U.S.S.R., review, a 102
Olefins, hydrogenation, rate studies, a 31
Osmium,
reduction of Os8+ state, a 31
research on & uses, review, a 135
thermal conductivity & electrical resistivity, a 135
Osmium Alloys,
Osmium-Silicon, structure of OsSi, a 65
Osmium-Tantalum, sigma phase, a 30
Osmium-Tungsten, sigma phase, a 30
Osmium-Uranium, preparation, a 29
Oxidation, selective with noble-metal catalysts, a 33
Oxycat, description & use in fume elimination 110
flue gas combustion, a 68
heat recovery from refinery gases, a 68
in paint stoving plant, a 103
Palladium,
additions to stainless steel to increase acid resistance 117
behaviour in oxygen at high temperatures 95
chemisorption of CO2, a 67
column for separating tritium & hydrogen, a 101
conductivity & Hall constant, effect of deformation, a 64
corrosion of metals in contact with, a 136
deoxidation with Al, a 101
diffusion of hydrogen through 16, 64
ethylene chemisorption & surface reactions, a 139
heat capacity below 4·2°K, a 29
research on & uses, review, a 135
vapour pressure, a 99
wire, for measuring hydrogen dissolved in water, a 137
Palladium Alloys,
Palladium-Bismuth, phase diagram & superconductivity, a 100
Palladium-Cobalt, hydrogenated, paramagnetic studies on, a 64
Palladium-Deuterium, β-phase structure, a 65
electrode mechanisms, a 101
Palladium-Hydrogen 16, 136
electrochemical behaviour, a 66
hydrogen producing reactions on Pd-H cathodes, a 101
α-Pd-H, electrochemical reactions, a 31
β-phase structure, a 65
thermodynamic properties of Pd2H & Pd2D, a 29
Palladium-Iridium, constitution, a 30
Palladium-Iron, constitution, a 136
Palladium-Nickel, electrical resistivity, a 64
Palladium-Nickel-Arsenic, superconductivity in, a 65
Palladium-Nickel-Manganese, constitution & properties, a 136
Palladium-Rhodium, electronic heat coefficient, a 30
Palladium-Ruthenium, deoxidation with Al, a 101
Palladium-Selenium, superconductivity, a 100
Palladium-Silver, Hall coefficient, temperature dependence, a 30
phase diagram & properties, a 99
resistivity change on deformation, a 30
Palladium-Titanium, corrosion resistance, a 136
Palladium-Uranium, constitution, a 29
Perchlorates, electrolytic preparation, a 66
Persulphate, effect of a.c. on electrolytic formation, a 65
Petroleum Refining, butane isomerisation 89
catalytic cracking, heat-recovery from tail-gases, a 68
catalysts, Pt recovery from 92
Houdriforming at Emsland Refining Co., a 33
at Tidewater refinery, a 32
hydroisomerisation of paraffin wax, a 33
importance of Pt in 48
n -nonane conversion, a 103
Platformer at Mina al Ahmadi refinery, a 103
Platforming, new catalyst for 23
Powerforming, a 32
recent developments, review, a 103
recent patents, a 139
reforming, aromatics from, a 103
reforming at new Sohio refinery, a 139
reforming, research in the U.S.S.R. 91, 139
upgrading of gasolines, economic method, a 139
Pharmaceuticals, catalysts in the manufacture of 86
Platinum,
additions to stainless steel to increase acid resistance 117
behaviour in oxygen at high temperatures 95
bushings for glass fibre production, a 34, 82
-carbon electrode in electron microscopy, a 99
chemisorption of CO2, a 67
compounds, preparation, a 101
conductivity & Hall constant, effect of deformation, a 64
corrosion of metals in contact with, a 136
creep strength, short-time tests, a 135
effect on crystallisation of Li2O.4SiO2 glass, a 68
impermeability to oxygen, a 135
melting, history of 55
oxide, hydrated, X-ray study, a 30
structural changes on heating, a 65
recovery from reforming catalysts 92
research on & uses, review, a 135
self-diffusion, a 99
strength at high temperatures, effect of non-metallic additions, a 64
tape, for effecting glass-metal seal, a 138
wetting by glass, a 33
Platinum Alloys,
Platinum-Bismuth, phase diagram & superconductivity, a 100
Platinum-Gold, grain-size & age-hardening, a 135
in metal film potentiometers, a 104
metallising, use in mercury vapour lamps 128
quenching vacancies in, a 64
Platinum-Gold-Rhodium, grain-size & age-hardening, a 135
Platinum-Iridium, behaviour in oxygen at high temperatures 95
creep strength, short-time tests, a 135
Platinum-Iron, magnetic susceptibility of Pt3Fe, a 99
Platinum-Palladium, behaviour in oxygen at high temperatures 95
creep-strength short-time tests, a 135
Platinum-Rhenium, electrical resistivity, a 29
Platinum-Rhodium, behaviour in oxygen at high temperatures 95
creep strength, short-time tests, a 135
electric furnace windings 38
quenching vacancies in, a 64
thermal e.m.f., stability of, a 135
Platinum-Titanium, constitution, a 136
corrosion resistance, a 136
Platinum-Titanium-Uranium,
effect of Pt additions on structure, a 99
Platinum-Uranium, constitution, a 29
Platinum Metals, behaviour in oxygen at high temperatures 95
research on & uses, review, a 135
in silicide cermets 53
Potentiometers, metal & metal oxide film, a 104
precision wire-wound, design of 74
Pseudoionone & isomers, total synthesis, a 103
synthesis of homologues, a 68
Quinols, catalytic hydrogenation, a 68
Radiolytic Gases, catalytic recombination, a 32
Reactor Fuel Elements, temperature measurement 63
Relays, high speed in line selector, a 104
Resistance Thermometers, platinum, in accurate measurement of temperature, a 105
use in precision calorimetry, a 102
Resistance Wire, noble-metal, for precision potentiometers 74
Rhodium,
behaviour in oxygen at high temperatures 95
chemisorption of CO2, a 67
corrosion of metals in contact with, a 136
research on & uses, review, a 135
structure of 61
thermal e.m.f., stability of, a 135
Rhodium Alloys,
Rhodium-Iron, constitution, a 136
Rhodium-Palladium, electronic heat coefficient, a 30
Rhodium-Uranium, preparation, a 29
Rosin, catalytic perhydrogenation, a 103
Ruthenium,
research on & uses, review, a 135
thermal conductivity & electrical resistivity, a 135
Ruthenium Alloys,
Ruthenium-Iron, constitution, a 136
Ruthenium-Silicon, structure of RuSi, a 65
Ruthenium-Tungsten, sigma phase, a 65
Ruthenium-Uranium, constitution, a 29
Steel, stainless, increasing acid resistance 117
Sulphur Dioxide, catalytic oxidation, a 67
Temperature Control, of steel tapping 116
Temperature Measurement, accurate, methods of, a 105
continuous, of liquid steel, a 69
of open-hearth furnace roof, thermocouple sheaths for, a 69
of reactor fuel elements 63
of steel castings, with intermediate-metal thermocouple, a 140
of steel, comparison of thermocouples, a 141
new developments, a 69
Tetrahydrofuran, isomerisation of homologues, a 139
Thermal Fuses, Pd-Au alloys for 28
Thermocouples,
Platinum/Rhenium-Platinum, thermoelectric potentials of, a 29
Platinum/Rhodium-Platinum, in the accurate measurement of temperature, a 105
care of 120
continuous steel temperature measurement with, a 69
control of tapping temperatures in steel plants with 116
errors in, due to interdiffusion, a 141
immersion, development of for Russian steel industry, a 141
review of developments in, a 141
sheaths for, a 105
intermediate metal, for metal/mould interface temperature measurements, a 140
measurement of reactor fuel-element temperature 63
in the non-ferrous foundry 90
steel temperature measurement in U.S.S.R., a 69
testing sheaths for open-hearth furnace roof temperature measurement, a 69
use in precision calorimetry, a 102
Titanium, anodic protection by Pt coating, a 104
platinum-coated, as anode in industrial electrolysis 127
-faced, as anode 45
Transatlantic Telephone Cable, platinum-cored valves in 2
Triethylsilane, addition to methyl methacrylate, a 104
Tritium, separation from hydrogen, a 101
Valves, thermionic, Pt-cored cathode in 2
for underwater installations, design of, a 140
Waste Gases, heat recovery from, a 32

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