Platinum Metals Rev., 1977, 21, (1), 33
NEW PATENTS: January 1977
METALS AND ALLOYS
Ruthenium Powder Metal Alloy
general motors corp. U.S. Patent 3,957,451
A sintered powder metal alloy contains about 75−85% Ru dispersed in a matrix of 15−25% of a pre-alloyed composition consisting of 65−80% Ni, 5−10% Cr, 5−15% W, 4−6% Si and 2−6% Fe. The surface of the Ru powder is soluble in the pre-alloyed composition for ductility and has good oxidation and spark erosion resistance at temperatures as high as ∼2000°F. The alloys are used for electrical contacts and sparking electrodes.
Modified Iridium-Tungsten Alloy
u.s. energy research & development administration U.S. Patent 3,970,450
An Ir base alloy composition having enhanced impact resistance consists of 20–50 p.p.m. Al, 20–100 p.p.m. Fe, 5–20 p.p.m. Ni, 50–100 p.p.m. Rh, 15–50 p.p.m. Th and Ir as the balance.
Palladium-Silver Alloy for Use in Nuclear Reactors
commissariat a l’energie atomique French Appl. 2,285,172
For the introduction of gaseous H2 into H2O, such as for the hydrogenation of pressurised H2O in a nuclear reactor, a helicoidal tube of a 77% Pd-23% Ag alloy is employed.
Intermetallic Ferromagnetic Compounds
Ruthenium-Containing Developers for Photography
eastman kodak co. U.S. Patent 3,964,912
A Ru divalent or trivalent cationic complex, such as a hexammine, ethylenediamine or bipyridine complex, is used to accelerate photographic development.
secretary of state for trade and industry British Patent 1,447,363
A polarographic or coulometric cell consists of a solid body of material surrounding a Pt conductive filament, and has a Au-Ag counter electrode.
hooker chemicals & plastics corp. U.S. Patent 3,956,083
Brine electrolysis and other processes may be carried out using an anode having a valve metal substrate coated with a SnO layer doped with Te and with an outer layer of a Pt group metal or oxide, such as RuO2.
Electrodes Having Silicide Surface
p.p.g. industries inc. U.S. Patent 3,963,593
In a brine electrolysis cell the anode is improved by providing a surface of an electroconductive, electrocatalytic silicide chosen from silicides of the Pt group metals on a valve metal substrate. Pt3Si is the preferred silicide.
ELECTRODEPOSITION AND SURFACE COATINGS
Silicon Metal Joints
p.p.g. industries inc. U.S. Patent 3,956,098
A Si fabrication consists of a Si member, an electrodeposited coating of Pd, Pt, Cu, Ni, Sn, Al, Zn, Ag, or Au and a second metallic member bonded to the Si member by an electrically conductive epoxy resin bonding material bonded to the electrodeposited coating.
e. i. du pont de nemours & co. U.S. Patent 3,963,590
Polyoxymethylene may be treated with quinoline or butyrolactone before etching and Pd sensitisation to improve the adherence of the subsequent metal coatings.
Osmium or Rhenium Coated Cutting Wire
lumalampan ab sweden French Appl. 2,284,403
A cutting or sawing wire is coated by various substances, including Os or Re in the form of crystals, obtained from a gaseous phase reaction.
Palladium-Nickel Alloy Plating
schering a.g. German Offen. 2,506,467
Ni and Pd may be electrodeposited together from an aqueous ammoniacal bath containing the metals in complex form, particularly with amino acids, keto acids, amines and the like. Glycine and alanine are suitable compounds.
LABORATORY APPARATUS AND TECHNIQUE
Determination of Total Oxygen Demand
Flame Ionisation Detector
pye ltd. British Patent 1,451,795
The detector has a burner head metallised with a Pt-based alloy in particular areas to provide electrical connection between the burner and external circuitry.
Electrolytic Cell Gas Sensor
chen-yen chou et al . U.S. Patent 3,955,268
A solid state electrolytic cell gas sensor head is made from a mixture of transition metal and non-metallic oxides with a small amount of Pt group metal oxide added. This mixture is formed into a paste and coated on a collector wire and a heater wire to form a bead. For example 2% Pt oxide may be added to an Al2O3-SiO2 mixture.
Selective Metallisation of a Cathode Ray Tube
n.v. philips gloeilampenfabrieken Dutch Appl. 75.00616
A photoresist technique is used to produce a mask on a phosphor layer which is then used for sensitising with Pd, Pt, Au, Ag or Cu ions before chemically plating with Ni, Ag, Co, Sn, Cu or Au.
Production of Purified Water
canadian patents and developments ltd. British Patent 1,451,471
Distilled H2O is vaporised and the vapour passed with a stream of pure O2 over a catalyst consisting of at least one of Pd, Rh, Ru, Pt, Ir, Fe, Co, or Ni, at 600−900°C. The vapour is then condensed and the steps are repeated until the degree of purity required is obtained.
Method for Making Bimetallic Catalysts
exxon research & engineering co. U.S. Patent 3,956,191
Bimetallic catalysts are prepared by contacting a catalyst consisting of Ag metal in the form of a powder having a surface area of 0.01−1.0 m2/g as such or present on a refractory metal oxide support with an aqueous solution consisting of a salt of a second metal: Pt, Ir or Au. The catalyst has surface alloys or multimetal clusters of the two metals, and it is used in fuel cell electrodes, petroleum processing, etc.
Honeycomb Structure for Countercurrent Gas Flow
w. r. grace & co. U.S. Patent 3,960,510
A two-stage catalytic reactor for the exhaust system of an internal combustion engine consists of concentric tubes of porous ceramic, coated with Ni oxide and a Pt group metal.
Reductive Alkylation of Ammonia
merck & co. inc. U.S. Patent 3,962,338
The reductive alkylation of NH3, a primary amine or a secondary amine, where the amine substituents are straight or branched chain lower alkyl groups, optionally hydroxy substituted, takes place by the dropwise addition of a glyceraldehyde using a Pt, Pd or Raney Ni catalyst to provide a S-1,2-dihydroxy-3-aminopropane.
universal oil products co. U.S. Patent 3,963,643
A catalyst with 0.1−5% Pt group metal on Al2O3 is reacted with a Friedel Crafts metal halide in an amount sufficient to introduce from about 2−15% combined halogen into the composite. Then the composite is contacted at a temperature of 100−600°C in a non-reducing atmosphere with a polyhalogen compound containing at least 2 Cl atoms. The product is an improved hydroconversion catalyst.
NOx Reduction and Catalyst
johnson matthey & co. ltd. U.S. Patent 3,963,827
A process for the reduction of an oxide of N2 typically present in an automobile exhaust uses a supported catalyst consisting of an inert material impregnated or coated with a mixture or alloy consisting of 5−75% Ru, up to 30% selected base metal, the lanthanides and the actinides and the balance, ≥5%, Pt. The catalyst may also be used in some oxidation reactions.
Ruthenium Catalyst for Exhaust Gas Purification
johnson matthey & co. ltd. U.S. Patent 3,972,837
The catalyst for use in the reduction of pollution from car exhaust gases is made up of a ceramic honeycomb having layers of a catalytically active refractory metal oxide and a catalytic layer comprising a mixture of Pt and one or more compounds selected from the group consisting of CaRuO3, MgRuO3, BaRuO3, SrRuO3 and a mixture of MgO and RuO2.
Rhodium Hydroformylation Catalyst
phillips petroleum co. U.S. Patent 3,956,177
New catalysts are obtained by the reaction of LnRhXm, where X is Br, Cl or I, L is a cyclic diene or triene, n is 1 or 2, m is 1 or 2 and n+m is 2 or 3, a hydrazine or Group IA, IIA or IIIA metal and a phosphine or phosphite. In an example the conversion of hexene to mainly heptaldehyde is catalysed by the reaction product of cyclododecadiene Rh dichloride, Na hydride and trinaphthyl phosphite in THF.
dow corning ltd. U.S. Patent 3,960,810
Siloxane compositions containing components with Si-vinyl and Si-H groups are cured using Rh halide complexes with carbonyl or mercaptan ligands, for example, a methyl hydrogen siloxanemethyl vinyl siloxane mixture was catalysed by the addition of a 3% solution in toluene of RhCl3 (Bu2S)3 to provide 40 p.p.m. Rh, of total composition.
Separation and Purification of Platinum, Rhodium and Iridium
matthey rustenburg refiners (proprietary) ltd. U.S. Patent 3,960,549
A solution containing Ir, Rh and Pt is reduced to convert Ir(IV) to Ir(III). The Pt is then extracted with a secondary amine or quaternary ammonium halide or hydroxide. The Ir(III) is reoxidised to Ir(IV) and this may be extracted with secondary amine or quaternary ammonium compound.
Separation of Palladium from Other Platinum Metals
matthey rustenburg refiners (proprietary) ltd. U.S. Patent 3,967,956
Pd which is present in a solution with at least one other Pt group metal is separated and purified by adjusting, as necessary, the pH of the solution to make it acidic, contacting the acidic solution with an oxime solvent and separating the organic phase containing substantially all of the Pd present in association with the oxime solvent.
Manufacturing Laser Glass
general electric co. British Patent 1,449,215
Laser glass is made in a vessel formed of or having a lining of Pt or an alloy consisting of at least 90% Pt and ≤10% Ru or Au. He gas is bubbled through the melt for sufficient time to remove any bubbles of gas formed during the batch reaction, and the melt is refined in the presence of a dry gas stream consisting of one or more of Ne, Ar, etc.
Stirring of Molten Glass
pilkington brothers ltd. U.S. Patent 3,971,646
A stirrer for stirring molten glass consists of a stirring member for immersion in the molten glass and a driven rotary shaft extending upwards from the stirring member to a roof of the furnace. This shaft is fitted with a stationary hollow casing formed of a material which contains a high percentage of Pt.
ELECTRICAL AND ELECTRONIC ENGINEERING
Electric Switching Device with Contacts
u.s. secretary of the navy U.S. Patent 3,971,110
An electron-emitting cathode containing a matrix of Ir or another Pt group metal is produced by mixing the matrix metal with Ag powder, shaping the mixture and then sintering the electrode at a temperature where the Ag evaporates. The active material, such as Ba, is deposited in the pores of the matrix.
Electrical Connection to a Molten Glass Container
johnson matthey & co. ltd. French Appl. 2,286,114
A combined method of electrical connection and thermal gradient control is described in which a lug made of a low resistance alloy of one of the Pt group metals, Al, Cu, Ag or Au is immersed in a bath of liquid metal alloy such as Ga-In-Sn eutectic held in a Cu reservoir. The method is useful in applications where a rigid mechanical connection produces excessive strain. An example of use is in the manufacture of glass fibre.
Electrical Resistance Element
johnson matthey & co. ltd. Dutch Appl. 76.02012
Temperature sensitive resistance elements for resistance thermometers having a robust construction and exhibiting stable temperature coefficients of resistance are formed on the outside and/or inside of a tubular or cylindrical element of electrically non-conducting material. The electrical track is deposited as a spiral, zig-zag, crenellated or other elongated path and is composed of a layer of fused vitreous material containing a particulate metallic conducting phase. The metallic particles are selected from Au, Ag, Pt, Pd, Rh, Ir, Ru, Fe, Co, Ni, Cu and alloys thereof. The device may be used in I.C.E. exhaust or fuel injection control.
High Temperature Electrostatic Probe
british leyland truck and bus division ltd. and loughborough university of technology British Patent 1,447,046
The probe includes an electrical conductor extending longitudinally inside a ceramic tube. A ceramic plug terminates one end of the conductor and a Ni-P alloy coating covers the external surface of the tube and the exposed external surfaces of the plug. The outer surface of the tube is activated with PdCl2.
Semiconductor Temperature Sensor
r.c.a. corp. British Patent 1,450,265
The sensor consists of a body of semiconductive material having a region of uniform resistivity, and means for supporting the body and making electrical contact to the region consisting of cantilevered beam leads, formed of successive layers of Ti, Pt or Pd, and Au and a reinforcing layer also of Au, connected to spaced areas of the region.
Dental Restoration Combining Dental Porcelain and Improved White Gold Alloy
pennwalt corp. U.S. Patent 3,961,420
A dental restoration consists of a cast white Au alloy metal base in the shape of a tooth. The alloy consists of 50−54% Au, 27−31% Pd, 11−16% Ag, about 0.05−0.25% of Ir or Ru and a total of 4.5−8% In and Sn. Dental porcelain covers the metal base and is baked on to it.