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Platinum Metals Rev., 1959, 3, (4), 157

Subject Index To Volume 3

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Acetaldehyde, new method of preparation139
Acetylene, selective hydrogenation of, a 30
Ammonia, 
   catalytic oxidation, modern developments2
   catalytic oxidation by ozone, a 70
Benzocyclobutene, preparation of, a 31
Bromoplatinic acid, in detection of alkaloids and organic bases, a 149
Bushveld Igneous Complex, geology and economics of94
Catalyst Bases, in hydrocarbon isomerisation, comparison of Al2O3 and SiO2-Al2O365
Catalysis, heterogeneous, development in industry, a 151
Catalysts, 
development by BASF, a 29
industrial methods for testing of, a 151
Iridium, hydrogen chemisorption on, a 149
in petroleum industry, review, a 70
   new USA patents, a 151
OsO4, hydroxylation of codeine, a 31
Palladium, chromatographic study of surface catalysis, a 70
   deuterium exchange of cyclopentanone and cyclohexanone, a 30
   manufacture of hydrogen peroxide54
   oxidation of hydrogen in CO, a 70
Pd/Al2O3, ether-deuterium exchange reactions, a 150
Pd/BaSO4, polymerisation in presence of, a 111
Pd-black, oxidation of hydrogen in CO, a 110
Pd/CaCO3, preparation of dl -ricinoleic acid, a 31
Pd/C, debenzylation of ethers and esters, a 71
   dehydrogenation of methyl reserpate and yohimbine, a 72
   formation of 1-pyrroline, a 72
   hydrogenation of bicyclic unsaturated ketones, a 71
   hydrogenation of castor oil, a 30, 111
   hydrogenation of fats, a 71
   hydrogenation of methyl linoleate, a 71
   hydrogenation of unsaturated compounds, a 110
   hydrogenation of unsaturated sulphides and sulphones, a 31
   preparation of benzocyclobutene, a 31
   preparation of papaverine, a 30
   reduction of azido compounds, a 72
   synthesis of 5-hydroxytryptophan, a 111
   synthesis of indoles, a 31
Pd-Cl2, determination of phosphite, a 70
Pd/silica gel, hydrogenation of acetylene on, a 111
Pd/SrCO3, hydrogenation of bicyclic unsaturated ketones, a 71
Platinum, deuterium exchange with hydroxyl groups, a 30
   deuterium oxide exchange of aromatic compounds, a 30
   film, in HCN manufacture11
   gauze, for nitric acid manufacture, modern developments2
   oxidation of alcohols71
   partial oxidation of gaseous hydrocarbons, a 150
   pentane isomerisation9
   preparation of indoles, a 31
   reforming and hydroforming processes, a 71
   reforming with RD-150, a 110
   synthesis of HCN, a 109
Platinum Metals, hydrogenation of acetylene, a 30
   hydrogen reduction of cyclopentanone, a 30
   ozone oxidation of ammonia, a 70
Pt/Al2O3, aromatisations with, a 150
B exchange experiments, a 150
   deactivation of, a 70
   dehydrogenation of cyclohexane, a 110
   deuterium exchange reactions on, a 151
   Powerforming, a 70
   structure and mode of action, a 149
Pt/Al2O3/halogen, reactivities of naphthenes over, a 110
Pt/Al2O3/SiO2, aromatisation of gasoline and preparation of C6H12, a 152
   deuterium exchange reactions on, a 151
Pt/C, aromatisation of gasoline, a 71
   deuterium exchange reactions on, a 151
   heavy water production118
   hydrogenation of hexafluorobenzene99
   oxidations with, a 31
Pt/HF/Al2O3, effects of Pt and HF contents, a 29
PtO2, hydrogenation of allocholesterol, a 111
   hydrogenation of bicyclic unsaturated ketones, a 71
   hydrogenation of cortisol, a 151
   hydrogenation of α-ketols, a 31
   hydrogenation of methyl linoleate, a 71
   hydrogenation of polydimethylene-acetylene, a 150
   preparation of p- and m -aminomethyl-cyclohexylcarboxylic acids, a 111
Pt/SiO2, deuterium exchange reactions on, a 151
Pt/silica gel, preparation and catalytic properties, a 149
Review, Catalysts in Action, a 70
Rh/Al2O3, ether-deuterium exchange reactions, a 150
   formation of 1-pyrroline, a 72
   hydrogenation of cortisol, a 151
Rh/Pt, gauze, in NH4NO3 manufacture, a 149
   synthesis of HCN109
Ruthenium, As (III)-Ce (IV) reaction, a 151
   paraffin wax synthesis59
Ru/Al2O3, adsorption of gases on, a 109
   adsorption rate of hydrogen on, a 109
Ru/C, selective hydrogenation of defines, a 150
Ru-Cu, hydrogenation of CO on, a 111
RuO2, preparation of cyclohexyl-alkylamines, a 31
Study by X-ray scattering, a 28
Cathodic Protection, 
   experiments with trailing Pt anode, a 152
   for naval vessels, a 112
   potential applications of Pt-clad anodes38
   Pt-Pb bi-electrodes for, a 32
   Pt-Pb bi-electrodes44
Cermets, 
   bonding techniques, survey, a 152
   Pt-bonded silicides and borides46
Chemical Plant, Pt-clad Mo, a 24
Codeine Derivatives, use of OsO4 in hydroxylation, a 31
Corrosion, inactivation of Ti & activation of other metals by Pt ions, a 27
Cyclohexylalkylamines, preparation of, a 31
Deuterium, 
   exchange reactions with n -C4H10, a 151
   exchange reactions over platinum metal films, a 110
   reactions with cyclopentanone and cyclohexanone, a 30
   reactions with hydroxyl groups, a 30
Deuterium Oxide, reactions with aromatic compounds, a 30
Dosimeter, PdO film, a 69
Electrical Contacts, 
   contamination by organic deposits19
   contamination, prevention in sealed relays22
   Pd-Ag, use in telephone relays, a 112
   Rh plating of, in printed circuits16
   Rh-plated Ag, a 112
Electrodeposition of, 
Iridium, survey, a 148
Palladium, effect of some organic substances, a 28
   survey, a 148
Platinum, from chloroplatinic acid, a 28
   survey, a 148
   on zirconium8
Rhodium, anti-corrosion properties, a 69
   bright and thick deposits, a 69
   effect of addition agents on stress and cracking, a 108
   effect of wetting and brightening agents, a 69
   on printed circuits16
   survey, a 148
Ruthenium, survey, a 148
Electrodes, 
noble metal & Pd alloy, potentials, a 27
Pd and Pd-clad Fe, transport of hydrogen through, a 68
Pd-H, atomic hydrogen overvoltage on, a 148
Platinum, anode, synthesis of 
   C30-triterpenes, a 108
   anodes, cathodic protection with, a 112
   anodes, electrolysis of perchloratcs, a 28
   anodes, use in organic electrolytic processes131
   anodic process in H2SO4 electrolysis, a 69
   coarsening by a.c. electrolysis, a 68
   cyclic a.c. voltammetry with, a 108
   effect of γ -irradiation on potential, a 27
   effect of surface oxidation in voltammetry, a 108
   electrochemical behaviour of O3 on, a 148
   micro, oxidation of indole alkaloids, a 28
   passivation of, a 148
   polarisation phenomena at, a 148
   preparation of reproducible surfaces, a 27
   rotating, in polarographic analysis, a 149
   wire cathode in the ‘solion’, a 112
Pt-Pb, as inert anodes in cathodic protection, a 32
   uses in cathodic protection44
Pt-clad Ta or Ti anodes for cathodic protection38
Pt/Ti anodes, development, a 68
Electroless Plating, palladium, a 109
Furnaces, 
   Pt-alloy wound, use in creep tests, a 69
   Rh-Pt, for glass fibre manufacture66
Glass, 
   effect of Pt in lead glasses17
   fibre manufacture66
   wetting of Pt by128
L-Gulose, preparation of, a 31
Heavy Water, production of118
Hydrocracking, study of reactions in hydrocarbon isomerisation65
Hydrocyanic Acid, 
   manufacture11
   manufacture, a 109
Hydrogen, 
   absorption by single crystals of Pd, a 107
   adsorption on Ru-Al2O3, a 109
   diffusion in Pd, a 67
   permeation of and diffusion through Pd, a 67
   sorption on Pd films, a 70
   transport through Pd-clad electrodes, a 68
Hydrogenation, 
   of acetylene, a 111
   of anthraquinone54
   of carbon monoxide, a 111
   of fats, a 71
   of fatty oils, a 30
   of α -ketols, a 31
   liquid phase, of CO59
   of unsaturated compounds, a 110
Hydrogen Peroxide, manufacture, new plant54
Indoles, synthesis, a 31
Iridium, 
   electrochemical properties100
   gamma radiography with Ir19212
   Poisson’s number, during elastic stress, a 24
Iridium Alloys, 
Iridium-Antimony, metallographic & X-ray study of system, a 26
Iridium-Boron, structure of IrB1−2, a 108
Iridium-Platinum, resistance of films of, a 112
Iridium-Thorium, constitution, a 26
with V, Cr, Nb, Mo, Ta & W, survey of systems for σ-phases, a 27
Iridium Compounds, magnctochemistry of, a 146
Lead, anodic protection by contact with Pt, a 32
Lustres, on ceramics60
Magnets, permanent Pt-Co, processing & properties, a 25
Molybdenum, protection against oxidation at high temperatures, a 24
Nitric Acid, manufacture, modern developments2
Osmium Alloys, 
Osmium-Thorium, constitution, a 26
with V, Cr, Nb, Mo. Ta & W, survey of systems for σ-phases, a 27
Osmium Hexafluoride, magnetic properties, a 146
Osmocene, structure of, a 148
Oxidation, 
   of alcohols, a 71
   of hydrogen in carbon monoxide, a 70, 110
Oxidation Reactions, study by thermocouple method, a 32
18O-Water, purification, a 148
Palladium, 
   absolute thermoelectric power at high temperatures, a 25
   diffusion of hydrogen, in, a 67
   electrical resistance in acid solution, a 147
   electrochemical properties100
   films, deuterium exchange reactions over, a 110
   films, hydrogen sorption on, a 70
   films, surface reactions on, a 109
   permeation of and diffusion of hydrogen through, a 67
   Poisson’s number, change during elastic & plastic stress, a 24
   single crystals, absorption of hydrogen by, a 107
   with PdO2, as film resistor, a 147
Palladium Alloys, 
with transition elements, magnetic properties, a 68
Palladium-Bismuth, composition, a 108
Palladium-Boron, constitution, a 108
Palladium-Chromium, magnetic properties, a 26
Palladium-Copper, electrical resistance at liquid He temperatures, a 25
   sorption of hydrogen by, a 147
   superstructure of Cu3Pd, high temperature study, a 147
Palladium-Gold, electrical resistance at liquid He temperatures, a 25
Palladium-Hydrogen, α-Pd-H, 
   electrochemical determination of saturation pressure and heat of solution, a 27
   electrode potentials, a 69
Palladium-Molybdenum, constitution, a 108
Palladium-Niobium-Zirconium, 
   corrosion resistance under irradiation, a 26
   use in nuclear reactors, a 26
Palladium-Platinum, electrical resistance in acid solution, a 147
Palladium-Platinum-Hydrogen, constitution, electrode potentials and electrical resistances, a 67
Palladium-Rhodium, constitution, a 146
Palladium-Silver, electrical resistance at liquid He temperatures, a 25
   electrical resistance in acid solution, a 147
   magnetic susceptibility at low temperatures, a 26
Palladium-Titanium, composition, a 26
   corrosion resistance88
Palladium-Vanadium, constitution, a 68
Palladium Compounds, 
   structure of, a 146
   palladium chloride, use in preparation of CH3CHO139
Palladium Oxide, 
   film, use in dosimeter, a 69
   with Pd, as film resistor, a 147
Paraffin Wax, synthesis59
Perchlorates, electrolysis of, a 28
Petroleum Refining, 
   catalysts, a review, a 70
   Complexforming, a 152
   hexane isomerisation, Penex process, a 110
   Penex process at Borger, Texas, a 150
   pentane isomerisation, Penex process9
   Powerforming, a 70
   principal developments, review, a 150
   reforming at Sinclair’s Houston refinery, a 110
   reforming, investigation of chemical processes, a 29
   reforming, review, a 29
   reforming, studies of naphthene reactivities, a 110
   synthesis of benzene derivatives, a 71
   units at Tulsa refinery of D-X Sunray Oil Co., a 71
Platinum, 
   absolute thermoelectric power at high temperatures, a 25
   catalytic properties, effect of adsorbed gases on, a 151
   chemisorption of hydrogen on thin films, a 29
   control grids, a 72
   decorative uses for ceramic lustres60
   dishes for preparing phosphors, a 148
   effect in lead glasses17
   electrical resistivity, Hall coefficient and magnetoresistance, at low temperatures, a 146
   electrochemical properties47
   element in aircraft thermometer, a 72
   films, deuterium exchange reactions over, a 110
   foil, in purification of 180-water, a 148
   gauze, in the ‘solion’, a 112
   history of deposits in New Granada140
   hot-wire anemometer, a 109
   in cell for polarisation studies, a 148
   irradiation effects, a 24
   kinetics of chlorine oxidation on, a 147
   oxidation, rate measurement, a 24
   point defects in, a 24
   Poisson’s number, change during elastic & plastic stress, a 24
   protection of Mo against oxidation at high temperatures, a 24
   pyrolysis tube, synthesis of hexafluorobenzene99
   strength-creep relationship, a 107
   wetting by molten glass128
Platinum-Alloys, Platinum-Aluminium, study of Pt-rich alloys, a 25
Platinum-Boron, structure of PtB, a 108
Platinum-Carbon, film, in electron metallography, a 109
Platinum-Cobalt, effect of irradiation on magnetic properties, a 107
   magnetic properties, a 25, 146
Platinum-Gold, catalytic properties, a 150
   film components used with transistors, a 152
   in metal film potentiometers, a 146
   in metal film resistors, a 147
   resistance of films of, a 112
   thermodynamics of, a 67
Platinum-Gold-Silver, constitution, a 67
Platinum-Iridium, resistance of films of, a 112
Platinum-Iron, magnetic properties, a 107, 146
Platinum-Iron-Nickel, studies of Fe3Pt phase, a 25
Platinum-Molybdenum, constitution, a 67, 146
   for control grids, a 72
Platinum-Nickel, resistance of films of, a 112
Platinum-Niobium-Zirconium, corrosion resistance under irradiation, a 26
Platinum-Palladium, electrical resistance in acid solution, a 147
Platinum-Titanium, corrosion resistance88
Platinum-Uranium, composition, a 107
Platinum Metal Alloys, with uranium, a 26
Platinum Metals, binary alloys, structure92
   co-ordination chemistry of90
   electrochemical properties47
   films of, temperature coefficients of resistance, a 112
   paramagnetic resonance in compounds of137
   South African resources94
   ternary oxides, of a 147
Platinum Oxides, properties47
Radiography, Ir192 as source12
Refinery Capacity, West German, in 1957, a 29
Relays, high-speed in switching arrays, a 152
Resistance Thermometers, 
   platinum, calibration of, a 113
   platinum, in production of hexachlorocyclohexane, a 112
   platinum, review78
Resistors, high temperature, noble metal films147
Rhodium, 
   allotropy of, a 146
   ductility of, a 107
   electrochemical properties100
   films, deuterium exchange reactions over, a 110
   Poisson’s number, during elastic stress, a 24
Rhodium Alloys, 
Rhodium-Bismuth, constitution, a 68
Rhodium-Boron, structure of RhB, a 108
Rhodium-Molybdenum, constitution, a 108
Rhodium-Palladium, constitution, a 146
Rhodium-Silicon, structure of Rh2Si, a 108
dl -Ricinoleic Acid, synthesis, a 31
Ruthenium, 
   atomic and electronic heat at low temperatures, a 67
   electrochemical properties100
   physical properties, a 25
Ruthenium Alloys, 
Ruthenium-Boron, structure of Ru7B2, a 108
Ruthenium-Molybdenum-Uranium, constitution, a 26
Ruthenium-Silicon, structure of Ru2Si, a 108
Ruthenium with U-Zr, U-Nb and U-Mo γ-phase-alloys, a 27
Ruthenium Tetroxide, as an oxidant for organic compounds, a 68
Ruthenocene, structure of, a 148
‘Solion’, development of, a 112
Sulphides, hydrogenation of, a 31
Sulphones, hydrogenation of, a 31
Surface Moisture, measurement of,145
   in zinc blast furnace93
   of soaking pit136
Temperature Measurement, 
   automatic recording dilatometer, a 69
   continuous, of liquid glass18
   in aircraft engine control, a 72
   in the glass industry, a 112
   in high-speed aircraft, a 72
   in iron and steel vacuum metallurgy, a 113
   in production of hexachlorocyclohexane, a 112
   of molten glass66
   of molten iron and steel56
   of rocket exhaust gases, a 152
   of roofs of oxygen-blown steel furnaces, a 32
Thermocouples, 
immersion, practical survey, a 73
Iridium: Iridium-Rhodium, measurement of rocket exhaust gases, a 152
Platinum metals, for aircraft engine control, a 72
Platinum: Rhodium-Platinum, 
   continuous glass temperature measurement18
   control of soaking pit temperature136
   error in surface temperature, a 73
   for microscope hot-stage attachment, a 149
   for oxygen-blown steel furnace, roof temperature measurement, a 32
   in iron and steel vacuum metallurgy, a 113
   measurement of rocket exhaust gases, a 152
   quick-immersion56
   use in creep tests, a 69
   use in dilatation studies, a 69
   use in study of oxidation reactions, a 32
   use in zinc blast furnace93
Platinum sheathed, a 112
Triterpenes, synthesis, a 108
Tritium-Labelled Water, preparation, a 30

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