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Platinum Metals Rev., 1991, 35, (4), 255

Subject Index to Volume 35

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Absorption, H, by Pd, a 154, 157
Acetalisation, by Rh(III)triphos complexes, a 44
Acetals, activation, a 111
Acetone Oxime, carbonylation, a 163
Acetonine, synthesis, a 163
Acetophenone,a 44, 239
Acetylene, reactions, a 40, 159, 163, 236
Adsorption, by IrOx/Ti electrodes, a 157
CO, onIr/Al203, a 42
on Pt electrode, effects, a 102
on Pt-Rh/Al2O3, a 159
on Pt( 100},reaction monitoring 188
on Rh catalysts, a 41
H, by Pd/glassy C electrodes, a 157
AIROF,a 113
Alcohols, allyl, cyclopentannulation, a 110
allylic, for enol production, a 111
cinnamyl, hydrogenation, a 40
C7, from syngas reaction, a 159
ethyl, chemisorption on Pt, Pd, Rh, Ru,  
bonding study, a 38
flow rate sensor, a 106
from α -alkene hydroformylation, a 43
methyl, chemisorption on Pt, Pd, Rh, Ru,  
bonding study, a 38
electrooxidation, on Pt, a 35, 108, 157, 232
on RuO/C, a 36
extensive use in fuel cells, Grove Symp. 209
formation, from CO hydrogenation, a 237
synthesis from syngas, a 41
phthalic, electrooxidation, a 111
primary, aerobic oxidation, a 163
allylation, a 111
synthesis from CO+H2, a 42, 109
Aldehydes, activation, a 111
formation by hydroformylation, a 43, 239
Alkanes, bridged polycyclic, by RuO4, a 45
dehydrogenation, a 159, 239
production 152, 161, 195
Alkenes, hydrogenation, homogeneous, a 161, 162
reactions, a 161, 163, 238, 239
hydroformylation, a 43, 239
Alkenyl Iodonium Salt, coupling with olefins, a 238
Alkylation, asymmetric Pd allylic, a 161
Alkylation-Alder Ene, cyclisation, a 110
Alkylthiols, formation, a 152
Alkyl-Boron Compounds, polymerisation, a 43
Alkynes, 1-Alkynes, reactions, a 44, 111, 161, 162
Allenes, carbopalladation, a 44
Allyl Benzene, hydroformylation, a 110
Allylation, primary alcohols, a 111
Allylic Acetates, for α, β -unsaturated ketones, a 111
Allylsilanes, synthesis, a 162
Aluminium, grain boundary reaction with  
Pd-Ag-Cu, a 153
Amines, carbonylation 70
Ammonia, carbonylation 70
for HCN synthesis, a 160
in nitric acid production, a 236
oxidation, on knitted gauze 58
photoproduction, from N2, by Pt/CdS system, a 104
reaction with CO, a 108
sensor 200
Amorphisation, on milling Pd-Si, a 154
platinum metals, solid state 83
Aniline, for diphenylurea, a 238
Anion, tandem capture-cyclisation, by Pd(0), a 161
Annulation, by Pd catalyst, a 110
Aromatisation,n -heptane, n -hexane, a 39, 40, 107
Aryl Halides, carbonylation 70
Aryl Iodides, coupling, a 237
reaction with vinyl-, cyclopropane/butane, a 43
Aryldithiocarbamates,a 237
Aryl-Aryl, exchange, a 238
Ascorbic Acid, oxidation, by Ru complexes, a 233
Barrier Layers,a 45, 46, 112, 113, 164, 240
Benzene, formation, a 160, 236
Benzonitrile, electrocatalytic hydrogenation, a 103
Bismuth, effect on lactose oxidation, a 40
Bonding, fusion, a 235
Book Reviews, Precious Metals Science  
and Technology 93
The Platinum Yearbook 1991 137
“Platinum 1991” 132
Bushveld Igneous Complex 132
Butane,n -, hydrogenolysis, isomerisation, on Pt, a 235
Butanediols, electrooxidation, a 111
Cameras, IR 45, 64
Cancer, anti-tumour Pt complex, a 46
metal complex anti-cancer drugs, review, a 46
Capacitors, with Pt/Ta barrier layers, a 112
Carboannulation, vinylic cyclopropanes,  
cyclobutanes, a 43
Carbon Oxides, CO, adsorption, on Ir/Al2O3, a 42
on Pt. Rh, Pt-Rh catalysts, a 159
on Rh(I). Rh(I)/TiO2, a 41
chemisorption, on Pt-Sn/Al2O3. a 107
on Pt/Al2O3, TiO2, a 235
CO-NO, Ce, K effects on Rh/Al2O3, a 41
cycling, for Pd/Al2O3 restructuring, a 40
detection in presence of NO, SO2, a 235
effect on ethene hydrogenation, a 107
on H permeation through Pd, a 32
electrooxidation, see Electrodes  
for aromatic nitro compound reduction, a 162
for diphenylurea, a 238
hydrogenation, on Rh catalysts, a 109, 160, 237
on Ru clusters/inorganic oxides, a 42
interaction with O, on Ir/Al2O3, a 42
on Rh/Al2O3, displacement by PH3. a 109
oxidation, on Pt/SnO2, a 107
on PdCl2-CuCl2/AI2O3,C, a 109
poisoning on Pd/SiO2, characterisation, a 41
reaction with NH3, a 108
see also Synthesis Gas  
self poisoning on Pt{100} surfaces 188
sensors, a 38, 106, 158
CO, CO2, hydrogenation. high pressure, a 40
low fuel cell emissions. Grove Symp. 209
CO2, effects on H permeation through Pd. a 32
hydrogenation, on Rh/TiO 2 , Rh/Nb2O3, a 41
Carbon Tetrachloride, hydrodechlorination. a 43
Carbonitriles,α -methoxy. formation, a 111
Carbonylation, reactions, a 43, 161, 163
by Ru carbonyl complexes 70
Carbopalladation, allenes. a 44
Carboxylic Acids, reactions, a 43. 111
Carboxylicα -Amino Acids, synthesis, a 161
Catalysis, biphasic, a 162
by cluster compounds 10
by Ru carbonyls 70
heterogeneous, a 39–42, 106–110, 159–160, 235–237
homogeneous, a 42–45, 110–112, 161–163.237–239
three-way, SAE conference 94
Catalysts, EUROPT-1, for CH4 conversion 195
for diesel engines 178. 187
Iridium, wire, for HCN synthesis, a 160
Iridium Complex, stabilised by O donor  
ligand, hydrosilylation, a 44
Ir/Al2O3, CO+O2 adsorption, interactions, a 42
Ir/support, precursor stoichiometry, a 107
Osmium Complex, OsHCl(CO)(P’Pr3)2,  
hydrosilylations, a 162
[H 2 Os3 (CO)9]1/poly -naphthalene, olefin  
isomerisation, a 111
Palladium Complexes, Pd acetate + di-imine  
ligands, vinylations, a 43
PdCl2(dppf), polymerisations, a 43
PdCl2 (PhCN) 2, aryldithiocarbonimidate  
rearrangement, a 237
PdCl2(Ph3P)2, styrene  
hydrocarboxylation, a 161
PdCl2/Ph2PC6H4SO3Na, heptene  
hydrocarboxylation, a 238
Pd(0), tandem cyclisation-anion capture, a 161
alkylation of allyl substrate, a 110
Pd(0)Ln+vinylic/arylic halides,  
carbopalladations, a AA
Pd(II), Alder ene reaction, a 110
Pd(II) acetate, carbo-, heteroannulation, a 43
Pd(II), alkyne-cyclopalladations, a 111
Pd(II)+onium salts+triphenylphosphine,  
for diphenylurea, a 238
Pd(OAc)2, β -vinylation, a 161
C-C coupling, a 238
Pd(OAc)2, H2+CC14 reaction, a 43
Pd(OAc)+2, Pd(PPh3)4, PdCl2, coupling  
reactions, a 237
Pd(OAc)2(PPh3),+Cu iodide, vinyl  
triflate reactions, a 238
Pd(OAc)2+( + )DIOP. asymmetric  
alkylations, a 161
Pd(O2CC2H5)2, mild CH4 oxidation 126
Pd(PFu3)2Cl2, cyclohexenone annulation. a 238
Pd(PPh3)2(C6H4-p -CH3)I. aryl-aryl  
exchange, a 238
Pd2(dba)3,CHCI3, coupling reactions, a 161
(DlAN)Pd(olefin), hydrogenations. a 161
[Pd(pyridine. phosphine)l(BF4)2,  
dimerisations, a 110
[(dppp)Pd(solvent)2][X]2, carbonylations. a 161
Palladium, industrial uses, review, a 44
poisoning by metal ions, a 108
Pd, Pd-Pt, Pd-Rh/C, SiO2, TiO2, propylene  
oxidation, a 160
PdCl2, PdCl2,-CuCl2,/Al2O3, CO oxidation, a 109
PdCl2+ Keggin-type heteropoly anions, reductive  
carbonylation. a 43
PdCl2/CuCl2/HOAc, propylene oxidation, u 43
PdS/Al2O3, hexene-1 hydrogenation. a 159
Pd(111), sulphided. C2H2 cyclisation. a 236
Pd(Pt)/Al2O3, S poisoning, a 108
Pd-Bi/C, lactose oxidation, a 40
Pd/AlPO4, styrene hydrogenation. a 159
Pd/Al2O3, CH4 oxidation/combustion, a 108
CO-NH3 reaction, a 108
surface restructuring on CO cycling. a 40
Pd/Al2O3-SiO2+Na, Fe, Mn oxides,  
preparation, structure, properties, a 108
Pd/a-AI,0,, C,H, hydrogenation. a 236
Pd/C, reaction of pyrimidine nucleosides+  
vinyl/allylic triflates. a 160
Pd/F-polymer Nafion, olefin conversion, a 106
Pd/HY, pretreatment, Cr promoter effects, a 109
Pd/HY, /NaHY, /NaY, methylcyclopentane  
conversions, a 160
Pd/La2O3, in high pressure IR cell.  
hydrogenation. a 40
Pd/MgO, phenol hydrogenation. a 236
Pd/NaY, /CaY zeolites, HC conversions, a 160
Pd/PTFE/Nafion, cyclohexene hydrogenation. a 106  
Pd/rare earth oxide, support effects, a 109
Pd/SAPO-11,1-hexene conversion, a 40
Pd/SiO2 characterisation. MCP  
hydrogenolysis. a 41
promoted. MeOH synthesis, a 41
Pd/support, H combustion, a 160
Pd/γ -Al2O3, C2H2-C2H4 hydrogenation. a 40
Platinum Complexes, bis(divinyltetramethyl-  
disiloxane)Pt. colloid formation, a 110
Pt blues. H2 evolution, a 43
PtX2(CO)(C6H10), synthesis, a 237
[Pt(C2H4)(( + )-DIOP) + PtCl2(( + )-DIOP)].  
hydroformylation. a 42
Pt(II)-NaI-HC1O4-H2O, vinyl halogcnidc  
reduction, a 161
Pt-H.+Ph2Si(C = CCMe3)2, ring systems,  
alkenyl silanes, a 42
with phosphinito ligands. hydroformylation. a 43
cis -lPtCl2(PPh3O2,1/SnCl2, olefin  
hydroformylation, a 110
Platinum, diolefin(dialkyl)Ptdl) hydrogenation. a 236
in nitric acid production, a 236
Pt, Pd, Rh, Ir, acetylene hydrogenation,  
C effects, 159
Pt black, for Pt complex hydrogenation 236
Pt clusters/chelate resin-Na, Mg, Al  
complexes, preparation, a 40
Pt oxides/TiO2, CdS, aqueous photocatalytic  
cyclisation, a 36
Pt planes, olefin hydrogenation, a 159
Pt(111), CH3I, CO coadsorption, a 235
Pt-Au colloids, H2photoevolution 22
Pt-Ce/SiO2, microstructure, reactivity, a 108
Pt-Co/C, O electroreduction, a 103
Pt-Ga/Al2O3,n -hexane conversion, a 39
Pt-Ir/Al2O3,n -heptane aromatisation, a 107
Pt-Ir/Al20,, -T102, /TiOj, support effects, a 236
Pt-Ir/support, precursor stoichiometry, a 107
Pt-Ni-Nb-Sn-Pt, HCHO electrooxidation, a 157
Pt-Re-S/Al2O3-Cl, reforming reactions, a 39
Pt-Re/Al2O3, dehydrogenation, preparation, a 107
Pt-Sn/Al2O3, chemisorption, XPS, a 107
n -heptane aromatisation, a 107
[PtCl2 (SnCl3) 2]2 /γ— Al2 O3, alkane dehydrogenation, a 159
Pt/, Pt-Rh/Al2O3, CO adsorption, a 159
Pt/Al2O3, cinchona-modified, ligand-accelerated catalysis, a 39
ethene hydrogenation, CO effects, a 107
S poisoning, SMSI, a 235
Pt/Al2O3, pillared clay, hydrocracking,  
isomerisations, a 159
Pt/AI2O3-Cl, deactivation on coking, a 235
Pt/C, H oxidation, a 232
Pt/F-polymer Nafion, olefin conversion, a 106
Pt/H-mordenite,n -heptane hydroconversion, a 107
Pt/KL,n -hexane aromatisation, a 40
Pt/nylon, Sn-Pt/nylon, liquid-phase hydrogenation, a 40
Pt/Pr6O+1 1, alcohol production, from syngas, a 159
Pt/PTFE/Nafion, cyclohexene hydrogenation, a 106
Pt/Rh, low-level moisture generation, a 106
Pt/SnO2/SiO2, CO low temperature oxidation, al07  
Pt/support, precursor stoichiometry, a 107
Pt/TiO2, H photoevolution from H2O-MeOH, a 233
resistance to H2S, a 39
S poisoning, SMSI, a 235
Pt/TiO2-ZrO2,n -hexane reforming, a 236
Pt/ZrO2, polycrystalline, MeOH oxidation, a 108
Rhodium, chiral cationic water soluble  
complexes/cation exchange resins, a 42
Rh colloids, hydrosilylation, a 238
Rh/RC(p -C6H4SO3Na)3, alkene  
hydrogenation, a 239
wire, HCN synthesis, a 160
Rhodium Complexes, asymmetric  
hydrosilylation, a 239
BINAP-Rh(I), photocatalytic asymmetric  
reduction, a 37
Cp*(P(OMe)3)Rh(C2H4)(H)+,  
dimerisations, a 162
Rh chiral phosphine ligands, asymmetric  
hydrogenolysis, a 162
Rh chiral/3-alkyl phenanthroline,  
hydrogenation, a 44
Rh phosphine chelate complexes,  
reductions, a 162
RhCl(CO)(PR3)2, pentane  
dehydrogenation, a 158
RhPh2PPy, styrene hydroformylation, a 239
Rh(II) carboxamides, preparation,  
cyclopropanation, a 111
Rh(II)perfluorobutyrate, hydrosilylation, a 162
Rh(PMe3)2Cl(CO), alkane  
dehydrogenation, a 239
Rh(+)/DIOP, alkene hydroboration, a 238
Rh-phosphine, hydroformylation, a 44
Rh-tris(o -tert -bufyl-p -methylphenyl)phosphite,  
hydroformylation, a 239
Rh6(CO)16 +amine, nitroanisole,  
nitrotoluene reduction, a 239
tricyclohexylphosphine Rh(H)Cl2,  
chloroarene hydrogenolysis, a 162
[RhCl3(triphos)], acetalisations, a 44
[Rh(COD)Cl]2 (S)-phephos, asymmetric  
hydrosilylation, a 44
[Rh(COD)Cl]2 +TMS–CN, acetyl reaction, al 11  
[Rh(CO)2Cl]2 +phosphanorbornadiene,  
hydroformylations, a 162
[Rh(diphosphine)(solvent)2]+, enol  
production, a 111
Rh(0) colloidal particles, hydrogenation, a 162
Rh(I), Rh(I)/TiO2, CO adsorption, 1-hexene  
hydrogenation, a 41
Rh-Ag/TiOj, MCP hydrogenolysis, a 41
Rh-Ce/SiO2, microstructure, reactivity, a 108
Rh-Co-Cu/TiO2, H2 +CO reaction, a 42
Rh-Co/Al2O+3, MgO, SiO2, propylene  
hydroformylation, a 237
Rh-Mn/SiO2, CO hydrogenation, a 109
Rh/Al2O3, CO adsorption, a 159
CO displacement by PH3 a 109
ethene hydrogenation, CO effects, a 107
in solar reactor, a 37
interaction with N2, a 155
protection from oxidative degradation, a 109
Rh/Al2O3 +Ce, K, NO-CO reaction, a 41
RI1/Al2O3-K2CO3, exchange functionalisation 140  
Rh/γ -Al2O3 ZrO2, ZnO, MgO,  
characterisation, a 237
Rh/MgO, for H/CO reaction, a 237
Rh/Nb2O5, CO2, hydrogenation, a 41
Rh/SiO2, NCO formation, a 41
Rh/TiO2, CO2 hydrogenation, a 41
[HRh(CO)(PPh3)] /membrane,  
hydroformylations, a 109
Rh4(CO)12/TiO2, CO hydrogenation, a 160
Ruthenium, chiral, synthesis, a 111
Ru dusters/inorganic oxides, preparation  
from Ru3(CO)12, a 42
RuO4, C-H bond activation in alkanes, a 45
Ruthenium Complexes, K[Ru(EDTA-H)Cl]2H2O,  
NH3 photoproduction, a 104
RuCl(OAc)(PPh3)3 triple system,  
aerobic oxidation, a 163
RuCl2(PPh3)3 +NaOH, ketone  
hydrogenation, a 239
RuCl3.3H2O, naphthalene  
electrooxidation, a 233
RuHI(tppts)3, propionaldehyde  
hydrogenation, a 112
RuX2L4, ether oxygenation, a 45
Ru(acac)3 , for naphthalene  
electrooxidation, a 233
Ru(cod)(cot), codimerisation, a 163
Ru(NH4)2Cl6, for naphthalene  
electrooxidation, a 233
Ru2(CO)4 carboxylates, hydrogenation, a 163  
Ru3(CO)12 +tricyclohexylphosphine,  
alkene hydroformylation, a 239
decarbonylation, a 163
lRuBr2(Me2SO)3], PPh3 oxidation, a 163
[Ru2 (CO)4 (Me2 CNO)2 (Me2 CNOH)2],  
carbonylation, a 163
[(bpy)(trpy)RuO]2 +, diol oxidations, a 111
[(Ph3P)2N][H3Ru4(CO)1 2], for  
cyclohex-2-en-l-one, a 45
Ru-Co/CeO2, H-CO reaction, a 160
Ru-Ge, Pb, Sb, Si, Sn/Al2O3, dispersed,  
properties, a 110
Ru/C, quinoline hydrogenation, a 110
Ru/SiO2, C3H6 hydroformylation, a 237
Ru/zeolite-A, preparation, size effect, a 42
Ru3(CO)1 2 +bpy/Mg silicate, water gas  
shift reaction, a 110
(( -Allylruthenium, for ketone synthesis, a 111
Catecholborane, for alkene hydroboration, a 238
Ceramics, support for Pd-Ag membrane, for  
H permeation, a 154
Cerium, additions to Rh/Al2O3, NO-CO reaction, a 41
Chemical Reaction Fronts on Pt(100| 188
Chemical Vapour Deposition,a 38. 152
Chemisorption, CO, H, O 107, 235
CO, MeOH, EtOH, on electrodes, a 38
Chenevix, Richard, palladium discovery 141
Chloroarenes, hydrogenolysis, a 162
Chloroform, formation, a 43
Chloronitrobenzenes, reduction, a 162
Chloroperbenzoic Acid, reaction with  
[Ru(PPh3)3Cl2], a 45
Cholesterol, sensor, a 165
CHP Systems, Grove Symp. 209
Chromium, catalyst promoter, a 109
for corrosion protection, a 163
grain boundary reaction with Pd-Ag-Cu, a 153
Cinnamaldehyde, hydrogenation, a 40
Cisplatin,a 46
Clusters, complexes, a 156
polymetallic activation 10
Coal, conversion, a 112
Coatings, IrO2-Ta2O5/base metal electrodes, a 157
Pd, by electroless deposition, a 105
on Mo-W-Cr alloys 133
Pd modified aluminide 82
Pt, by electroless deposition, a 105
Pt thin films, ion beam deposited, a 112
Rh, in reed switches, a 165
Cobalt,a 153
Codimerisation, acetylenes+alkenes, a 163
Coking, in catalysts, a 235
Colloids, Pt, Pt-Au, Rh, Ru, Ag, a 22, 34, 110, 238, 239
Composites, superconducting 2
Conductors, molecular, [Pd(tmp)] 2 [ReO4], a 156
Conferences,12th Natl. Fuel Cell Seminar, 1990 17
2nd Grove Fuel Cell Symp., London, 1991 209
2nd Intl. Symp. Metal-H Systems, Banff, Sept. 1990 24, 195
Intl. Symp. Polymetallic Activation, Palma, Sept. 1990 10
Magneto-Optic Recording International Symposium, Tokyo, 1991 134
SAE Intl. Congress and Exposition, Detroit, Feb.-Mar. 1991 94
Corrosion, in contracts, a 165
photo-, CdS in Pt/CdS dispersions, a 104
protection, in Mo-W-Cr-Pd alloys 133
resistance, Cr+PGM additives in acids, a 163
F ion on IrO/TiO ceramic electrode, a 35
Fe40Cr3Ru steel, a 34
of Ir-Ni electrodes, for OER, a 106
platinised porous Ti electrodes, a 35
Crucibles, Ir, Pt 2, 23, 156
Crystallisation, heavy metal fluoride glass, a 164
Crystals, Pd-Ni-P, a 102
Pt basal single electrodes, a 34
Pt complex oxides, formed in crucibles, a 156
Rh-Cu single, solidification, a 155
RuSe2, a 155
single, Ir, plastic deformation 196
single, Pt, Rh, Pd, surfaces, in H2SO4, a 228
Y44Ru25, Er3Ru2, a 34
n -Si, Pt doped, a 228
Cyclic Voltammetry, for Ru-Ti alloys, a 103
Cyclisation, reactions, a 36, 161, 160
Cyclohexane, reactions 27, 39, 160
Cyclohexanpne,a 36, 236
Cyclohexene, reactions 74, 106, 110
Cyclohexenone, annulation, a 238
Cyclohexylamine, carbonylation 70
Cyclopentene, hydroformylation, a 110
Cyclopropanation, catalysts for, a 111
Cyclopropane, reaction, on RuNaA[ZS], a 42
Cyclo-2-en-l-one, reactions, a 45
Decarbonylation,(Ir6(CO)16] isomers, a 237
Decomposition, formamide, a 108
hydrazine, a 155
NO, on Pt{ 100} 188
Dehydroaminoacid, derivatives, hydrogenation asymmetric, a 42
Dehydrogenation, alkanes, a 159, 239
cyclic C5, C6 hydrocarbons, a 107
pentane, a 158
Dental, alloys, tarnishing tests, a 46
Detectors, alcohol, with RuO2/C electrode, a 106
ammonia 200
cholesterol, a 165
CO, in presence of NO, SO2, a 235
CO, a 38, 106
H 85, 106, 234, 235, 240
H, O, Pd/SnO2 model sensor, a 106
IR, visible, UV, by Schottky diodes, a 164
IR, a 45, 64, 208
laser power, a 158
luminescent, using Ru complexes, a 105
O, CH4, H2, O2, by Pd/SnO2, Pt/TiO2, a 158
O2, a 38, 106, 158
strain gauges 65
titration monitor, by Ir oxide device 137
Deuterium, enriched by T in giant Pd cluster, a 230
in self assembly of catalysts, a 236
Deuterium Exchange, in styrene, a 161
Dienes, reactions, a 40, 44, 107, 159, 237
synthesis, a 161, 163
Diesel Engines, emission control 94, 178, 187
Royal Commission on exhaust control 187
Diffusion, H, in Pd-Ag, α -Pd, PdSiH alloys, a 103, 153, 230
Ir dimers, Ir adatoms, on Ir(l 10), a 155
membranes 33, 138
see also Permeability 33, 138
Diffusion Couples, Pd-AI, kinetics, a 32
Dihydrobenzofurans, production, a 43
Dimerisation, reactions, a 110, 162
Dimethyl Oxalate, selective reduction, a 163
Diodes, Pt-Ti/p -InGaAs/n -InP, hole trap levels, a 46
Diols, electrooxidation, a 111
Dioxetane, 1,2-, decomposition, chemiluminescence, a 233
Diphenylsilane, for hydrosilylations, a 239
Diphenylurea, N,N′-, synthesis, a 238
Disproportionation, cyclohex-2-en-1-one, a 45
Dissociation, NO, a 155
DNA, photo chemical cleavage, a 105
Electrical Contacts, Al-Pd-Si interconnects, a 113
Au flashed Pd, a 165
corrosion, resistance characteristics, a 165
electroplated Ni/PdNi/Au, a 234
in reed switches, a 165
in ULSI, a 240
ohmic, Pd-In/n -GaAs, Pd/Sb(Mn)p -GaAs, a 165
Pt/Ti/p -InAs, a 46
PtSi/Ge-Si/Si, a 112
Pt-Ti/p -InGaAs/n -InP, diodes, a 46
Schottky, a 234
Electrical Resistivity, in Fe-C/Al2O3/Fe-Ru, a 231
Pd solid solution alloys, +H, a 33
U-Pt/Pd/Rh-In alloys, a 32
Electricity, efficient generation by fuel cells 209
photoproduction from light, a 37
Electrochemical Cells, Pt/CaF2/Pt, in O2, a 102
Electrochemistry,a 34-36, 102-104, 157–158, 232–233
Electrochromism, AIROFs, a 113
Electrodeposition, Pd-Ni films 208
Electrodeposition,a 38, 105, 106, 234
Electrodes, anodes, DSA, a 95, 105
Pt, urea oxidation, a 35
Pt/porous SiC + H3PO4, coal conversion, a 112
cathodes, high temperature,  
Pt + (Bi2O3)0.7(Er2O3)0. 3, a 233
Pd thin film disc, H insertion, a 157
Pt, Pt/Nafion/PE, in O sensor, a 38, 158
F ion-IrO/TiO ceramic, effluent treatment, a 35
for OER, preparation, a 106
gas diffusion, Pt, uranous nitrate production, a 164
Ir oxide, in titration monitor 137
IrO2-Ta205/Ta, /Ti, a 157
IrOx/Ti, adsorption properties, a 157
Ir-Pt/Nafion, 117/Pt-Ir, in HC1 electrolysis, a 35
IrxTi, –x02/Ti, preparation, activity, stability, a 36
Pd, implantated by K, Li, a 103
Pd, Pt-Pd, for ethylene glycol oxidation, a 103
photo, Pt-InP, etched, a 104
TiO2/SiO2/Pt, response to gases, a 36
ultramicro, TiO2/SiO2/Pt, gas response, a 36
platinised porous Ti, corrosion resistance, a 35
platinised Pt, in cholesterol oxidase sensor, a 165
polymer/polymer/Pt, preparation, a 35
Pt, adsorbed CO effect, a 102
basal single crystal, a 34
CO electrooxidation, a 232
for glucose oxidation, a 232
in cell with Ru naphthalene oxidation, a 233
in O sensor, a 158
in phenol oxidation, waste water control, a 232
porous in Pt/CaF2/Pt cell, a 102
Pt, Pd, Rh, Ru, chemisorption of CO,  
MeOH, EtOH, bonding study, a 38
Pt, Pt/C+metal oxides, MeOH oxidation, a 35, 232
Pt black, Pt/WO3, for H detection, a 38
Pt disk fabrication, a 234
Pt gauze, trans -[PtHCl(PEt3)2l oxidation, a 35
Pt, Pd, Rh, Ru/poly(pyrrole-viologen)/glassy  
C felt, for hydrogenations, a 103
Pt rotating disc, for O2 reduction, a 233
Pt(bpy)(CN) 2/Pt, spectrochemical properties, a 233
Pt-SPE membrane, in fuel cell, a 163
Pt/C, for H oxidation, support porosity, a 232
in PEM, a 240
Pt/SnO2, Pt/WO3, in CO sensor, a 38
RuO/C, MeOH oxidation, O evolution, a 36
RuO2+TiO2, SnO2 activated, a 104
RuO2/C, for alcohol detection, a 106
Ru,Ti, –xO2/Ti, catalytic activity, a 36
[RhII(L)2 Cl2]+ BF4, hydrogenations, H2 evolution, a 36
Electroless Deposition, Pt, Pd, Ni, a 105
Electroless Plating, for Pd thin films, a 38
Electrolysis, HC1, by SPE electrodes, a 35
Emission Control,1991 SAE conference reports 94
diesel exhaust 178, 187
fuel cell benefits, Grove Symp. 209
Energy, more efficient sources, Grove Symp. 209
Enols, catalytic production, a 111
Enones, conjugated, electrocatalytic hydrogenation, a 103
Enthalpy, of formation, RuGe, RhGe, PdGe, a 154
Environment, fuel cell benefits to 17, 209
Enynes, 1,6-, cycloisomerisation, a 110
Esters,a 45, 161
Etching, Pt foils, in O plasma, a 38
Pt-InP photoelectrodes, a 104
Ethane, hydrogenolysis, catalyst activity a 236
Ethene, hydrogenation, a 107
Ethers, luminescence, oxygenation, a 45, 104
Ethyl 2-Formylpropanoate, synthesis, a 162
Ethyl Acrylate, hydroformylation, a 162
Ethyl Chloride, formation, a 43
Ethyl Pyruvate, hydrogenation, a 39
Ethylanthraquinone, 2-, hydrogenation, for Pd catalyst studies, a 108
Ethylbenzene, from styrene, a 236
Ethylene, from vinylhalogenides, a 161
reactions, a 40, 109, 162, 236
Ethylene Glycol, reactions, a 103, 163
Ethyne, effect on ethene hydrogenation, a 107
E.E.C., diesel exhaust control 178, 187
research support 10
Faraday, Michael, history 222
Films, anodic Ir oxide films, charge storage, a 113
Pt, focused ion beam deposition, a 112
Fischer-Tropsch, catalysts, a 160
Fission, PGM waste reprocessing, a 202
Formaldehyde,a 157. 163
Formamide, decomposition, a 108
Formic Acid, electrooxidation, a 157
Fuel Cells,a 45, 240
12th Natl. Fuel Cell Seminar 17
2nd Grove Fuel Cell Symp., London, Sept. 1991 21. 209
history 201
MeOH, a 163
phosphoric acid, a 45
Fuel Oil, for syngas production, temperature measurement, a 113
Functionalisation, of Rh catalysts, by K 140
Gadolinium Oxide, reaction with Pd+H, a 154
Gauzes, knitted, for NH3 oxidation 58
Geology, British Columbia 16
Pt deposits in USSR 96
Glass, formation, Pd-Ni-P, a 102
Zr-Ba-La-Al-Na fluorides, Pt nucleation, a 164
Glasses, Pd0.835,Sl0.165, structure changes, a 33
Pd40Ni40P20, internal friction, a 229
Pt-Al, thin films 83
Glucose, oxidation, on Pt electrode, a 232
Graphite, oxidation, on Pt{100} 188
Heptane,n -, reactions, a 39, 107
Heptene, -1, hydrocarboxylation, a 238
Heteroannulation, vinylic cyclopropanes, cyclobutanes, a 43
Heterocyclisation, C2H2,a 236
Hexane, isomers, a 160
Hexane,n -, reactions, a 39, 40, 41, 236
Hexene, 1-, reactions, a 40, 41, 42, 70, 111, 159
Hexene,n-, Et3SiH addition, a 110
History, Michael Faraday 222
“Palladium; or, New Silver” 141
Hydrazine, decomposition, a 155
Hydroboration, of alkenes, a 238
Hydrocarbons, adsorption with H2S, H2, on Pt, a 152
conversions, a 160
diesel engine emissions, catalysts for 178, 187
low MW, production from coal, a 112
synthesis from CO + H2, a 42
Hydrocarboxylation, reactions, a 161, 238
Hydrochloric Acid, electrolysis, a 35
Hydrochlorination, olefins, a 237
Hydroconversion,n -heptane, n -nonane, a 107, 109
Hydrocracking,a 39, 159
Hydrocyanic Acid, synthesis, a 160
Hydrodechlorination, CCI4, a 43
Hydroformylation, alkenes, a 43, 239
ethyl acrylate, a 162
ethylene, C3H6, on Rh catalyst, a 109
oct-1-ene, a 239
olefins, a 110, 162
polybutadiene, a 44
propylene, a 237
styrene, 1-hexene, a 42. 239
Hydrogen, absorption, by Pd-Al-La-Ni alloy, a 154
adsorption states on Pt electrodes, a 34
catalytic recombination with O, for moisture generator, a 106
chemisorption, a 107, 157, 235
coadsorption with H2S, HC, on Pt, a 152
codeposited with Pd plating, a 106
detection with CO sensor, a 38
diffusion, in Pd, Pd alloys, a 33, 103, 153, 230
electrooxidation, on Pt/C, a 232
embrittlement of steel, Pt implanted, a 228
evolution, by RhIII complex polymers, a 36
from H2O-MeOH, a 233
on silicides, a 35
from H2O photoreduction, by Pt blues, a 43
in Pd 24, 33
in uranous nitrate production, a 164
insertion into Pd disc cathodes, a 157
metal systems 195
oxidation, on Pd/support, a 160
permeation, through Pd, Pd-Ag membrane 32, 138, 154
photoevolution 22, 104
photospillover, in ZnO/Pd system, a 105
reaction with NO, on Rh, a 155
Schottky device response to, a 240
see also Synthesis Gas  
sensors 85, 106, 158, 234, 235
use in fuel cells, Grove Symp. 209
Hydrogen Peroxide, photoproduction, a 233
Hydrogen Sulphide, effects with Pt, a 39, 152
Hydrogenation, acetophenone, a 44
acetylene, a 159
alkenes, a 161, 162, 239
asymmetric, dehydroaminoacid derivatives, a 42
unsaturated carboxylic acid, a 111
buta-l,3-diene, isoprene, a 159
cinnamyl alcohol, cinnamaldehyde, a 40
CO, in a continuous flow microreactor, a 160
on basic axides, a 237
on Rh-Mn/SiO2, a 109
on Ru clusters/inorganic oxides, a 42
CO, CO2, on Pd/La2O3, a 40
conjugated enones, styrene, benzonitrile, a 103
CO2, on Rh catalysts, a 41
cyclohexanone, a 36
cyclohexene, a 106
C2H2, C2H4, C3H6, a 236
C2H2-C2H4, a 40
diene, olefin, a 40
dimethyl oxalate, a 163
diolefin(dialkyl)Pt(II) complexes, a 236
ethene, a 107
ethyl pyruvate, a 39
ethylanthraquinone, 2-, for Pd catalyst studies, a 108
hexene-1, a 41, 159
phenol, a 236
propionaldehyde, a 112
quinolines, on Ru/C, Raney Ni, a 110
styrenes, a 159
transfer, ketones, aliphatic, aromatic, a 239
of cyclohex-2-en-l-one, a 45
Hydrogenolysis, asymmetric, Na epoxysuccinate, a 162
biphasic, a 162
chloroarenes, a 162
ethane, for catalyst activity, a 236
methylcyclopentane, on Rh-Ag/TiO2, a 41
methylcyclopropane, a 41
n -butane, a 235
Hydrolysis,cis -PtCl2(NH3)2, a 38
Hydrosilylation, alkynes, a 44, 162
asymmetric, acetophenone, a 44, 239
phenylacetylene, a 162
Pt colloid formation, a 110
Rh colloid catalysis, a 238
Imines,a 111. 161
Imino Acids, photocatalytic cyclisation, a 36
Impedance, Pt/SiO2, ultrathin films, a 32
Indans, production, a 43
Indium, grain boundary reaction with Pd-Ag-Cu, a 153
Indolines, production, a 43
Integrated Circuits,a 112,113
Interconnects, Al-Pd-Si metallisation, a 113
Ion Beam Mixing, Pd-Ni, low temperature, a 33
Ion Plating, for Pt-GaAs Schottky contacts, a 234
IR, imaging, sensors, a 45, 164, 208
IR cell, for high pressure spectroscopy, a 155
Iridium, crystal cleavage 23
diffusion on Ir(110) surfaces, a 155
plastic deformation 196
radioactive, reprocessing 202
thin films, a 38
Iridium Alloys, Ir-Al quasicrystals 21
Ir-Ni, for OER electrodes, a 106
Ir-Ta, amorphous, diffusion barriers, a 46
Iridium Complexes, polymetallic activation 10
[Ir6(CO)16], isomer synthesis in NaY zeolite, a 237
Iridium Oxide, AIROFs, a 113
coatings for DSA electrodes 95, 105
in titration monitor 137
IrOx.nH2O clusters, redox states in H2O photoreactions, a 105
Iridium Silicide, in IR imagers 64
Isocyanate, formation, a 41, 108
Isomerisation, direction of 28
reactions, a 39, 110, 111, 159, 235
Isomers, in Pt, Pd complexes 28
Isoprene, hydrogenation, a 159
Johnson, Percival Norton, palladium discovery 141
Johnson Matthey, Prince of Wales Award  
for Innovation 201
“Platinum 1991” 132
Joining, PtSi fusion bonding, a 235
   
Ketones,a 111, 161, 239
   
Lactose, oxidation, a 40
Langmuir-Blodgett Films,a 102, 233, 234
Lasers,a 107, 158
Lead Alloys, Pb-Cu-Sn-Se-Pd, microstructural stability, a 33
Luminescence, in Pt(bpy)(NH3)22+-anthraceno-crown ether, a 104
in Ru(II)polypyridine complexes, a 105
quenching, Ru(bpy)32+, a 37, 158
Ru(bpy)3Cl2, a 233
Magnetism, Ce-Ru-Si-Ge, a 102
diamagnetic transition in Pt ID complex, a 153
effect on Ru multilayer films, a 231
FeRuGaSi thin films, a 155
Fe(PdxPt,–x)3,a 101
in Fe-Pd alloys, a 33
in Pd/Co multilayers, a 31, 101, 234
in Pt complex oxides formed in crucibles, a 156
in Pt/Co, a 31, 112, 152
in U-Pt/Pd/Rh-In alloys, a 32
in [Pd(tmp)]2[ReO4, a 156
of Pt resistance thermometer, a 113
Pt-Fe-Nb system, a 152
Pt/Fe multilayers, a 152
Pt3Mn-Pt3Fe, paramagnetic susceptibility, a 228
Pt3Mn0.9Fe0.1, a 229
Magneto-Optics, conference report 134
in Co/Pt, Co/Pd multilayers 31, 112
thin, ultrathin Pt/Co, a 152
Manganese, catalyst promoter, a 109
Medical,a 46, 165
ami-tumour complexes, a 46
dental alloys, a 46
Membrane Reators 27, 164
Membranes, for H diffusion, a 33
F-polymer Nafion, PTFE/Nafion, supports, a 106
Pd, H permeation through, CO, CO2 effects, a 32
Pd-Ag, for H permeation 138, 153, 154
Pd/ZnO, H photospillover, a 105
see also Thin Films  
Mercaptans, formation, a 152
Merensky Reef 132
Metallisation, systems, a 165, 240
Metallisations, Au-Sn/Pt, Al-Pd-Si, a 112, 113
Methane, formation, a 237
gas detector, a 158
reactions, a 108, 126, 160, 195
Methanol, fuel cells 163, 209
see Alcohols, methyl  
Methyl Acrylate, dimerisation, a 162
Methyl Formates, decomposition into syngas, a 163
Methyl Trifluoroacetate, from CH4 126
Metliylcyclohexane, selective dehydrogenation, a 107
Methylcyclopentane, reactions, a 41, 107, 160, 235
Methylcyclopropane, hydrogenolysis, a 41
Methylnaphthalene, 2-, oxidation, a 233
Methylstyrene,α-, hydrogenation, a 236
Methyl-2-Oxobutanoic Acid, 3-, photocatalytic asymmetric reduction, a 37
Microscopy, scanning electron, with RuO4 in imaging, a 39
Mineralogy, in Canada 16
Mirrors, Rh/C multilayer X-ray, a 39
Moisture, generator, a 106
Molybdenum, Pd catalyst promoter, a 43
Morphology, back scattering electron detector, a 39
Pt/graphite thin film, a 152
Pt/SiO2, 25Ǻ, a 32
   
Naphtha, reforming, a 39
Naphthalenes, oxidation, a 233
NEMCA, for MeOH oxidation, a 108
Neohexene, Et3SiH addition, a 110
Nicholson, William, palladium discovery 141
Nickel, high temperature reactions with SiC, a 153
Nitric Acid, process gas filtration, a 236
production, on knitted gauze 58
Nitroanilines, reduction, a 162
Nitroanisole,p-, reduction, a 239
Nitroanthraquinone, 1-, reactions, a 162
Nitrobenzene, reactions 43, 70, 162, 238
Nitrogen, reactions, a 104, 155
Nitrogen Oxides, NO, dissociation, reaction with H on Rh, a 155
NO-CO, Ce, K effects on Rh/Al2O3, a 41
self poisoning on Pt{100} 188
Nitrotoluene, reduction, a 239
Nonane,n-, hydroconversion, a 109
Noril’sk-Talnakh, Pt deposits 96
Nuclear Fuel, PGM reprocessing 202
Nucleosides, C-5 alkyl, production, a 160
   
Octane,n-, hydrocracking, isomerisation, a 159
Oct-1-ene, hydroformylation, a 239
Olefins, couplings, a 161, 238
reactions, a 40, 110, 111, 159, 162, 237
Optical Switch, in Langmuir-Blodgett film, a 234
Organofluorophosphines, complexes, preparation, properties 86
Osmium, polycrystalline, thermionic emission, a 230
Osmium Alloys, Al-Os quasicrystals 21
Osmium Complexes, Os organofluorophosphines 86
Os polyhydrides, paramagnetic, a 37
OsH4(PMe2Ph)3, concurrent photodissociation, a 37
OsO4, oxidant 31
Os-ammines, a 231
Os3Pt(CO)11(PPh3)2, a 156
polymetallic activation 10
Pt4Os6(CO)22(COD), Pt5Os6(CO)2l(COD)2, a 156
[OsCl(NO)(PiPr3)2], synthesis, a 232
Oxidants,(Ph4)[RuO2(OAc)Cl2], a 45
Oxidation,2-methylnaphthalene, naphthalene, a 233
alcohols, primary, aerobic, a 163
alkanes, bridged polycyclic, a 45
ammonia, on knitted gauze 58
CO, on Pt{100} crystals, reaction monitoring 188
CO, a 107, 109
electro-, CO, on Pt electrode, a 232
diols by Ru complex, a 111
ethylene glycol, a 103
glucose, a 232
H, a 232
HCHO, a 157
HCOOH, MeOH, a 157
MeOH, on Pt, a 35, 36, 108, 232
Pd, elcctrodissolution, a 157
phenol, water pollution control, a 232
Fe40Cr2Ru steel, corrosion resistance, a 34
graphite, on PtjlOO} 188
H, a 160
internal, in Pd-40Ag-lRE alloys, a 33
lactose, on Bi-Pd/C, a 40
methane, by Pd 108, 126
photo, H2O, ascorbic acid, a 105, 233
propylene, propylene glycol, a 43, 160
Pt/Ni crystals, a 101
resistance, in Pd coated Mo-W-Cr-Pd alloys 133
Rh, high temperature, a 34
triphenylphosphine, a 163
urea, a 35
[Ru(PPh3)3Cl2], a 45
trans -[PtHCl(Pet3)2], a 35
Oxygen, catalytic evolution, from MeOH, a 36
catalytic recombination with H, for moisture generator, a 106
chemisorption, on Pt-Sn/Al2O3, a 107
evolution, by IrOx-Ta2O5/Ta electrodes, a 157
electrodes for, a 106
from HCIO4, a 104
from H2SO4, a 95
interaction with CO, on Ir/Al2O3, a 42
interaction with Pt/CeO2 sensors, a 158
reduction electrocatalysts, a 103
reduction in H2SO4+phenanthroline, on Pt rotating disc, a 232
sensor, a 38, 158
Oxygenation, aliphatic ethers, a 45
Oxyhexatriene, cyclisation, a 238
Palladium, addition, to stainless steel, a 163
to Au-Cu dental alloys, a 46
α -Pd, H permeation in, a 103
amorphous interphase with InP, a 153
cluster, Pd561,Phen60(OAc)160, a 230
clusters, on mica, scanning force microscopy study, a 229
compounds, cyclopalladated, reaction with alkynes, a 111
EuPd2Si2, valence change under pressure, a 229
Fe(PdxPt, _x),, magnetism, a 101
PdGe, enthalpy of formation, a 154
[Pd(tmp)]2[ReO4], a 156
electrodes, see Electrodes  
electrodissolution, a 157
electroless deposition, a 105
glasses, Pd40Ni40P20, internal friction, a 229
history, discovery, a 141
in contacts, a 113, 165
in detectors, sensors, see Detectors  
in membrane reactor, a 164
in Schottky contacts, a 240
ion beam mixing in Ni, a 33
membrane reactors 27
membranes, a 32, 105
modified aluminide coatings 82
nanocrystalline, mechanical behaviour, a 154
Ni/PdNi/Au, composite for contacts, a 234
Pd(lll). crystal surface in H,SO4,a 228
Pd(lll), sulphided, for C2H2 cyclisation. a 236
Pd-Al thin film, phase formatrion, a 153
Pd-H systems, Intl. Symp. 24, 195
Pd/Al diffusion couple, a 32
Pd/Co 31, 101, 134, 234
Pd/SnO2, for gas sensor, a 106, 158
PdxC1 –x, thin films, electrical properties, a 101
plating, with H codeposition, a 106
radioactive, reprocessing 202
rod, electrochemical charging, a 233
thin films, a 38. 154. 229
ultrafine particles, for H absorption. adsorption, a 157
Palladium Alloys, assessed for contact characteristics, a 165
Pd solid solution, electrical resistivity, a 33
Pd-Ag, H permeation 138. 153. 154, 230
Pd-Ag-Cu. grain boundary reactions, a 153
Pd-40Ag-lRE, internal oxidation, a 33
Pd-Ag-Y(Gd), diffusion characteristics, a 33
Pd-Al-La-Ni, H absorption, a 154
Pd-Au, lattice expansion, a 154
Pd-Au-Cu, dental, tarnishing tests, a 46
Pd-Cr, in strain gauges 65
Pd-C-Mg, a 229
Pd-Er, preparation, metallography, a 154
Pd-Fe, sputter deposited, a 33
Pd-H systems, Intl. Symp. 24
Pd-Ho, preparation, metallography, a 154
Pd-Mo-W-Cr, oxidation resistance 133
Pd-Ni, H insertion into thin films, a 157
plating bath 208
Pd-Ni-P, crystal nucleation, glass formation, a 102
Pd-Pb-Cu-Sn-Se, microstructural stability, a 33
Pd-Pt-U, magnetic transport properties, a 32
Pd-rare earth oxides, coupled reduction, a 154
Pd-Si, a 154, 229. 230
Pd-Si-H, H diffusion, electromigration. a 230
Pd-Te, system constitution, a 33
Pd-Zr, amorphisation 83
Palladium Complexes, H.PdCl6, effect on Ag imaging colloids, a 36
isomers 28
ortho-palladated imines, mesogens, a 231
Pd organofluorophosphines 86
PdLCl2, Pd(L-H)2, Pd(L-2H), a 231
Pd(II)-Sn, a 103
polymetallic activation 10
[Pd(3,3′-bipyridazine)2][C1O4]2, a 102
[Pd2X4(PPrn3)2] + l,4-benzodiazepines, a 231
[Pd9As8(PPh38], [Pd9Sb6(PPh3)8], a 156  
Palladium Silicides, alloy glasses, structure changes, a 33  
for H evolution, a 35  
mechanical alloying, a 154  
Pd2Si, in ULSI, a 240  
see also Palladium Alloys, Pd-Si    
Patents 47-56, 114-124, 166-176,241-249  
Pentane, dehydrogenation, a 158  
Pentene, 1-, hydroformylation, a 110  
Permeability, see also Diffusion    
Permeation, H, through Pd 32, 138, 154
Phase Changes, at Pd/InP interface, a 153
at Pt/GaAs, Si/Pt/GaAs interfaces, a 153
in Al-Pd thin films, a 153
Phase Diagrams, CeRu2(Ge-Si)2, a 102
Fe(PdxPt1–x)3, a 101
Pd-Te, a 33
RuO2-Bi2O3-CuO, a 155
Phenol,a 232, 236
Phenylacetylene, hydrosilylation, a 162
Phenylcarbamate, N-, formation, a 43
Phenylpropanal, 2-, from styrene, a 42
Phosphine, displacing Co on Rh catalyst, a 109
Phosphonicα -Amino Acids, synthesis, a 161
Photocatalvsis,a 36-37, 43, 104-105, 158. 233-234
Photodissociatitm, OsH4 (PMe, Ph)3. a 37
Photolysis, Ru(II) diimine. a 105
Plating, electroless. Pt. Pd. Ni. a 105
Pd. with H codeposition. a 106
Platinum, addition to YBaCuO superconductor, a 229
compounds. Fe(PdxPt1–x)3, magnetism, a 101
Pt3Mn-Pt3Fe, paramagnetic, a 228
Pt3Mn0.9,Fe0.1, magnetism in. a 229
CVD, a 152
deposits, in USSR 96
doped heavy metal fluoride glass, a 164
n -Si crystals, a 228
electrodes, see Electrodes  
electroless deposition, a 105
equilibrium shape, surface energy, a 101
etching foils, a 38
high temperature reactions with SiC. a 153
hydrous oxide films, a 102
implanted in steel, reduced embrittlement. a 228
in electrical contacts, a 46
in high temperature superconductivity 2
in Schottky NH, sensor 200
ion beam deposition, a 112
multilaycrcd thin films, preparation, structure, a 228
Pt(100). Pt(l11), for adsorption, a 152
Pt(lll). reactions, a 228. 235
Pt-GaAs. in Schottky contacts. a 234
Pt-H bond cleavage, a 35
Pt/CdS dispersions, photocorrosion. a 104
Pt/CdS.Ag,S/RuO,. for NH, production, a 104
Pt/Co. in magneto-optic devices 31. 112. 134. 152. 228
Pt/Fe thin film multilayers, anisotropy. a 152
Pt/GaAs, Si/Pt/GaAs. intermixed phase, a 153
Pt/mica disks, fabrication, a 234  
Pt/Ni. oxidation prevention, a 101  
Pt/pyrolytic graphite, thin film morphology, a 152  
Pt/Ta. Pt/Ti. barriers, a 112
Pt/TiO2, gas sensor, a 158
Pt{100}. chemical reaction fronts 188
radioactive, reprocessing 202
thick films, laser power detection, a 158
thin films, a 38. 101
ultrafine particles, for electrooxidations. a 157
ultrathin films, /SiO2. properties, a 32
underlayers, in YBaCuO superconductors, a 240
“Platinum 1991” 132
Platinum Alloys, in PAFC fuel cells, a 45
Pt-Al. amorphisation 83
quasicrystals 21
Pt-Co/C, for O electroreduction. a 103
Pt-Fe-Nb, magnetic, thermal properties, a 152
Pt-Pd. solid solution, for ethylene glycol oxidation, a 103
Pt-Rh. gauze, for NH, oxidation 58
Pt-Rh, Pt-Rh-Au, volatilisation, a 32
Pt-U-In. magnetic, transport properties, a 32
Pt-Y-B, properties, a 32
Platinum Complexes, anti-cancer, a 46
CODPt(CD3)2, Pt surface alkyls. a 236
isomers 28
Os3Pt(CO)11(PPh3)2, a 156
o -vinyl Pt(IV), a 161
polymetallic activation 10
Pt blues, for H2 photoevolution, a 43
Pt organofluorophosphines 86
PtCI2 (bis(aminomethyl)dimethylsilanel, anticancer, a 46
Pt(bpy)(CN)3/Pt electrodes, spectroscopic properties, a 233
Pt(bpy)(NH3)22+, luminescence, a 104
Pt(II)-diaminobiotin, synthesis. characteristisation, a 231
Pt-Sn bimetallic, a 34
Pt4Os6(CO)22(COD), Pt5Os6(CO)21(COD)2, a 156
R2Ba2CuPtO8, R2Ba3Cu2PtO10, Ba4CuPt2O9, a l56
[PtI2(L1)][BF4], a 231
[Pt(3,3′-bipyridazine)2][CIO4]2, a 102
[Pt(en)2][Pt(en)2I2](C1O4)4. magnetism in, a 153
[Pt(L1][BF4],a 231
[Pt2(μ -C=CHPh)(C(≡CPh)(Pet3)]BF4, photochemical atom-transfer, a 104
cis -PtCl2(NH3)2, hydrolysis products, a 38
cis -[PtCl2(PPh3)2], a 231
trans- [PtHCl(Pet3) 2], electrochem ical oxidation, a 35
trans -[Pt(H)X(PPh3)2], a 231
Platinum Silicides, for H evolution, a 35
from SiC/Pt high temperature reactions, a 153
fusion bonding, a 235
in IR imagers 45, 64, 208
PtSi, columnar grains, a 32
contact to Ge-Si/Si, a 112
in Schottky diodes, a 164, 228
in ULSI, a 240
PtSi/Si(100), formation, a 240
Poisoning, by metal ions, of Pd catalysts, a 108
catalysts by S, a 39, 108, 235
CO, onPd/SiO2, a 41
self, CO, NO on Pt{ 100} 188
Pollution Control,1991 SAE conference reports 94
diesel exhaust 178, 187
electrolyte effluent treatment, a 35
phenol in waste water, a 232
radioactive PGM waste 202
Polyaldehydes, from polybutadiene, a 44
Polymerisation,a 43, 110
Polymers, co-, Ru complex+ DDA, in L-B films, a 233
layered conducting/Pt, a 35
+ RuO4, in electron detector, a 39
Potassium  
Prince of Wales Award for Innovation 201
Promoters,10,11-dihydrocinchonidine, a 39
Bi, on Pd/C, a 40
Ca, K, La, on Pd/SiO2 catalysts, a 41
Cr, to Pd/HY catalysts, a 109
Mn, V, a 109, 160
Mo, V, in PdCl2 + Keggin-type anions, a 43
Propadiene, effect on ethene hydrogenation, a 107
Propan-2-ol, for ketone hydrogenation, a 239
Propene, hydroformylation, a 109
Propionaldehyde, hydrogenation, by RuHI(tppts), a 112  
Propylene, reactions, a 43, 160, 236, 237
Propylene Glycol, oxidation, a 160
Propylene Glycol Monoacetate, formation, a 43
Pyrimidine Nucleosides, reaction with triflates 160
Quasicrystals, in Al-Rh, -Pd, -Ir, -Os, -Pt, -Ru 21
Quinolines,a 110
Radioactivity, reprocessing PGM waste 202
Rapid Thermal Processing, for electrical contacts, a 46  
Rare Earths, new compounds with Ru, a 34
Reed Switches,a 165
Reforming, reactions, a 39, 236
Resistance Thermometers, Pt, stability, a 113
Resistors, Pt, in thermal conductivity meter, in mine pit, a 234
RuO2 thick film, thin film, a 113,235
thick film, a 155, 240
Reviews, electrocatalysts for PAFC, a 45
metal complex anti-cancer drugs, a 46
Pd catalysts in industry, a 44
see also Conferences  
Rhodium, coatings in reed switches, a 165
compounds, RhGe, enthalpy of formation, a 154
Rh2O3,a 34
(CsMe5)Rh(PMe3)H2, a 156
foil, hydrazine decomposition, a 155
oxidation, high temperature, a 34
radioactive, reprocessing 202
Rh(l11), reactions, a 155, 228
Rh/C multilayers, for soft X-ray use. a 39
thin films, a 38
on Ag{001}, Au{001}, a 230
Rhodium Alloys, Rh-Al quasicrystals 21
Rh-Cu, single crystal solidification, a 155
Rh-Pt, Rh-Pt-Au, volatilisation, a 32
Rh-U-In, magnetic, transport properties, a 32
Rhodium Complexes, Cp*Rh, electrochemical reduction, a 36
polymetallic activation 10
Rh(2,4,6-Me3C6H2)3, a 34
Rh[P(OPh)3]3[P(OC6H4)(OPh)2], a 156
[Cp*RhCl]2, electrochemical production, a 36
[RhIII(L)2Cl2] + BF4, films, electrochemical properties, a 36
Royal Commission on Environmental Pollution,  
report on diesel exhaust 187
Ruthenium, colloids, of Ru double salt, a 34
compounds, anti-cancer properties, a 46
RuGe, enthalpy of formation, a 154
RuSe2 crystal growth, a 155
RuTiSnO, O evolution, a 104
LiRuO2,a 36
effect on Fe40Cr steel, a 34
in thick film resistors, a 240
radioactive, reprocessing 202
Ru(0001), thin Cu films on, a 230
Ru-rare earth systems, a 34
Ruthenium Alloys, FeRuGaSi thin films, magnetism, structure, a 155
Ru-Al quasicrystals 21
Ru-Al-Mn-Si, icosahedral, a 231
Ru-Ni, for OER electrodes, a 106
Ru-Ti, electrochemistry, a 103
Ruthenium Complexes, oxidants 31, 45
polymetallic activation 10
Ru organofluorophosphines 86
Ru(bpy)32+, for H2 evolution, using Pt blues, a 43
luminescence quenching, a 37, 158
Ru(bpy)32+ on Vycor glass, photo properties, a 37
Ru(II) bipyridine, optical switching, in L-B film, a 23
Ru(II)polypyridines, photo properties, a 105
[Ru(η,-C5H5)(CS2)(PPh3)2]+, a 156
(Ph4)[RuO2(OAc)Cl2], a 45
[RuL2(μ -(CN)Ru(CN)L2′)2]light to electricity conversion, a 37
[Ru(bipy)2(L-L′)](PF6)2, photolysis, a 105
[Ru(bpy)2(CN)2]2Ru(bpy)(COO)2)22–, antenna sensitised, a 37
[Ru(bpy)2(Vbpy)]2+, copolymers, in L-B films, a 233
preparation, characterisation, a 158
[Ru(bpy)x(bpz)3–x]2+, H2O2 photoproduction, a 233
[RufMeLXCOXPPhjJjfCl)], a 34
[Ru(PPh3)2(m -ClC6H4CO2)Cl2], formation, a 45
[Ru(saloph)Cl2], carbonylations 70
[Ru(_SH2)(PPh3)(′S4′)]THF, structure, a 232
[RuII/EDTA-H)(CO)], carbonylations 70
[(7,i-C5Hi)L2RuNC-aryl] +, a 102
[(TPP)Ru(CO)]-, reaction with Mel, a 158
Ruthenium Oxides, Bi,Ru,O7, reaction  
with CuO in resistors, a 155
RuO2, coatings for DSA, a 105
in resistors, a 113, 155, 240
reduction to LiRuO2, a 36
RuO2/Al, interface properties, a 113
RuO2/C, electrode in alcohol detector, a 106
RuO4, + polymer blends, for back scattering electron detector, a 39
Schottky Barrier Detectors, in IR imaging 45, 208
Schottky Barriers, sensors, a 158, 200
Schottky Contacts, preparation, a 234, 240
Schottky Diodes,a 106, 164, 228
Semiconductors, technology, compared to superconductors 2
Sensors, see Detectors  
Silacyclobutene, formation, a 42
Silicon, crystals, Pt doped, a 228
reaction with Pd, a 229
Single Crystals, Pt, for adsorptions, a 152
Pt{100}, for chemical reaction monitoring 188
SMSI, in CO2 hydrogenation on Rh, a 41
in Pt/Al2O3, Pt/TiO2, a 235
Sodium Epox) succinate, asymmetric hydrogenolysis, a 162
Solar Energy, adsorption using Rh/Al2O3, a 37
Solar Reactor,a 37
Solder, Sn/Pb temperature cycling with Pd/Ag, a 165
Solidification, RhCu single crystals, a 155
Sputtering, gas effect, on Pt/Co multilayers, a 228
SQUIDs, magnetometry, a 101
Stainless Steel, improved properties, a 34, 163, 228
Strain Gauges for high temperatures 65
Styrene reactions, a 42, 103, 110, 111, 159, 161, 239
Sulphur, catalyst poison, a 108, 235
role in catalytic reforming, a 39
Sulphuric Acid, O evolution from 95
Superconductors, high temperature 2
YBaCuO, Pt additions to, a 229, 240
Surfactants, to stabilise Rh(0) colloidal particles, a 162
Symposia, see Conferences  
Synthesis Gas, alcohol, hydrocarbon synthesis, a 41, 42, 109, 159
for hydroformylations, a 239
production, a 113, 163
reaction on Fischer-Tropsch catalyst, a 160
Temperature Measurement,a 113, 208
Thermal Conductivity Meter, for coal mines, 234
Thermocouples, PtRh30/PtRh6, for extreme conditions, a 113
Thick Films, Pd, in contacts, a 165
Pd/Ag, conductor metallisation, a 165
Pt, for laser power detector, a 158
resistors, a 235, 240
Thin Films, amorphous metals 83
a-IrTa, diffusion barrier, a 46
capacitors, a 112
Cu on Ru(OOOl), a 230
FeRuGaSi multilayers, structure, magnetic properties, a 155
Fe-C/AI2O3/Fe-Ru multilayers, electrical restivity, a 231
hydrous oxide/Pt, a 102
Langmuir-Blodgett, a 102, 233, 234
Pd, disc electrodes, H insertion, a 157
grown by electroless plating, a 38
in sensors, see Detectors interaction with SiGe/Si(100), a 229
Pd-Ag alloys, conductivity, a 230
Pd-Al, phase formation, a 153
Pd-Co, multilayers, a 234
Pd-Cr strain gauges 65
Pd/InP, amorphous phase formation, a 153
PdxC1–x, preparation, electrical properties, a 101  
Pt, ion beam deposited, a 112
Pt, Ir, Rh, Ni, Re, grown by OMCVD, a 38
Pt, Rh, Pd, in metallisation systems, a 240
Pt oxides, growth, characterisation, a 101
PtSi/Si(100), by codeposition, MBE system, a 240
Pt/Co multilayered, magneto-optics, a 112, 152, 228
Pt/Fe multilayers, magnetism, a 152
Pt/GaAs, amorphous phase formation, a 153
Pt/highly oriented pyrolytic graphite, annealing, morphology, a 152
Pt/Mn/Sb, multilayered, preparation, structure, a 228
Pt/SiO2, ultrathin, impedance, morphology, a 32
Rh on AujOOl}, Ag{001(, growth, a 230
RuO2 resistors, a 113
see also Membranes  
YBaCuO/Pt/YSZ/Hastelloy, superconducting, a  
Thiophene, formation from C2H2, a 236
Tin,a 34, 153
Triflates, reactions, a 160, 161, 238
Trifluoroacetimidoyl Iodides,a 161
Trimethylpentane, 2,2,4-, hydrocracking, isomerisation, a 159
Triphenylphosphine, oxidation, a 163
Tritium, enrichment of D in giant Pd cluster, a 230
ULSI, barrier metals for, a 240
Uranous Nitrate, production, a 164
Urea, oxidation, on Pt anodes, a 35
USSR, Pt deposits 96
UV, Schottky barrier detector, a 164
Vanadium, Pd catalyst promoter, a 43
Vehicles, fuel cell propelled, Grove Symp. 209
Vinyl-4-Pentynoic Acid, 5-,a 238
Vinyl Acetate,β -vinylation, a 161
Vinylation, reactions, a 43. 161
Vinylbromides, B substitution, a 161
Vinylhalogenides, reduction, a 161
Vinylic Cyclopropane, heteroannulation,  
carboannulation, a Volatilisation, Pt-Rh alloys, a 43
Voltammograms, Pt(lll), Pt(110), Pt(100) surfaces, a 32
Water, low-level moisture generator, a 106
photoreactions, a 43, 105
treatment, pollution control, a 232
Water Gas Shift Reaction 70, 110, 163, 164
Wear, characteristics of contacts, a 165
Wires, Ir, plastic deformation 196
Ir, Rh, for HCN synthesis, a 160
superconducting 2
Wollaston, William Hyde, palladium discovery 143
X-Rays, mirror construction, a 39
Zinc Oxide, dielectric, in Pt/Co magneto-optics, a 112

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