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Platinum Metals Rev., 1999, 43, (4), 183

Subject Index to Volume 43

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a = abstract
Acetic Acid, hydrocarbonylation, to higher acids, a 44
Acrylic Acids, in Heck reactions 138
Alcohols, allyl, hydrogenation 29
   ethyl, dehydrogenation, a 43
     oxidation, by Pd/LiNbO3, via acoustic oscillations 82
   from β-ketoesters, Ru catalysed, a 45
   hydrocarbonylation 154
   methyl, carbonylation, lr/1” catalysed 105
   oxidation, by Ru, to aldehydes and ketones 94, 167
     by Ru-Co-Al-CO, hydrotalcite/O2, a 87
   primary, secondary, oxidation of 94, 167
Aldehydes, α-, β-, γ-hydroxy, by hydroformylation, a 88
   branched-chain, from styrene derivatives, a 44
   propanal, hydrogenation, a 88
Alkanes, Ru(lII) GC detector for, a 85
Alkenes, aziridination, a 175
   epoxidation, a 175
   in Heck reactions 138
   hydroformylation 154
   hydrogenation 105
   hydroxycarbonylation, a 44
   Ru(IlI) GC detector for, a 85
Alkynes, hydrogenation 105
   Ru(III) GC detector for, a 85
Allyl Ethers, hydroformylations, a 88
Aluminides, coatings for gas turbines 59
Amines, fluoroanilines synthesis 29
   heterocyclic, synthesis, a 174
Amino Acids, “unnatural”, synthesis of 138
Ammonia, decomposition to N2, with Pt/TiO2, a 174
   oxidation 44, 105
     in nitric acid manufacture 62, 167
   synthesis, K2[Os3(CO)ll]/“Sibunit” C catalyst, a 132
     K2[Ru4(CO)13/“Sibunit” C catalyst, a 132
Antenna Effect, [Ru(bpy)3]2+ photoactive dendrimers 69
Arenes, hydrogenation 114, 133
Aryl Bromides, in Heck reactions 138
Autocatalysts, manufacture of 70, 168
Aziridination, of alkenes, a 175
Ball Milling, high energy, a 175
Ballard, fuel cells 14, 149
Battery, high performance metal hydride alloy for 50
   rechargeable 50
Biaryls, from coupling reactions, a 44, 87
Biphasic, see Catalysis Book Reviews, “Catalysis of Organic Reactions” 29
   “Cisplatin: Chemistry and Biochemistry of a Leading Anticancer Drug” 103
   J. Mol. Catal. A: Chem ., carbonylation reactions 154
Cancer, drugs, AMD473, JM216, oxaliplatin 103
     BBR3464 103, 158
     book review 103
   Pt(IV) complexes as antitumour agents 61
Capacitors, epitaxial, SrRuO3/(Ba, Sr)TiO3/SrRuO3, a 45
Carbon, fibres, as base for porous Pt nanofibres 61
Carbon Oxides, CO2, from CO, over O-Ru(0001), a 172
     supercritical, as a reaction medium 29, 61, 87, 130
   CO, absorption on platinised Pt electrodes, a 173
     desorption, on Pt/CeO2, Pt/ZrO2−CeO2, a 86
     from methane, a 43
     hydrogenation, a 132
     oxidation, on Pt(100), a 86
     oxidation to CO2, over O-Ru(0001), a 172
     tolerance of anodes, for PEMFCs, a 88
Carbonylation, catalysts for, journal review 154
   see also Hydrocarbonylation
Carbonyls, a 41, 84, 133, 173
Carboxylic Acids, from alkenes, Pd catalysed, a 44
Catalysis, biphasic 29, 44, 154
   book review 29
   in carbonylation reactions, journal review 154
   catalyst recycling 105
   combinatorial chemistry techniques 105
   heterogeneous, a 43-44, 86-87, 131-132, 174
   homogeneous, a 44-45, 87-88, 132-133, 174-175
   in microreactors, for screening of catalyst libraries 105
   PGM Conference 158
Catalysts, auto-, manufacture of 70, 168
   in cold-plasma reactors, for VOCs, CH4 oxidation 109
   combined homogeneous and heterogeneous 114
   homogeneous, molecular modelling of 154
     recovery, using filtration membranes, a 175
     separation 158
   kinetic screening, using reaction calorimetry 158, 175
   removal from olefin metathesis products, a 175
   “tethered complex on a supported metal”, TCSM 114
   three-way, 28, 86, 119, 131, 168
   for 2- and 3-wheeled vehicles 13
Catalysts, Iridium, Ir/Al2O3, NH3 oxidation 105
     pyridine hydrodenitrogenation, a 132
   supported, hydrogenation of halogenated nitro aromatics 29
Catalysts, Iridium Complexes, lr/I, methanol carbonylation 105
Catalysts, Osmium, K2[Os3(CO)11]/“Sibunit” C, for NH3 synthesis, a 132
Catalysts, Palladium, Cu-Pd/γ-Al2O3, Cu-Pd/SiO2, a 86
   Pd complexes/support, hydrogenation reactions 29
   Pd-Ni/polymer, styrene hydroesterification, a 44
   Pd-Rh, CeO2− and non-promoted, exhaust aftertreatment, a 86
   Pd/Al2O3, for margarine production 74
   Pd/γ-Al2O3], sol-gel preparation of, a 174
   Pd/C, CFC-115 hydrodechlorination, a 86
     electrodeposition of Pd, a 173
     heterocyclic amines formation, a 174
     in heterogeneous Heck reactions 138
   Pd/CeO2, model catalyst, a 131
   Pd/CeO2-ZrO2 solid solutions, model catalyst, a 131
     with Pr, model catalyst, a 131
   Pd/HFAU(17) zeolite, o -xylene oxidation, a 86
   Pd/LiNbO3, acoustic oxidation of C2H5OH 82
   Pd/metal oxides, NO reduction, a 44
   Pd/MgO, CaO and R.E. oxides, CH4 conversion, a 43
   Pd/mixed oxides, CH4 oxidation, a 86
   Pd/SiO2-CeO2, model catalyst, a 131
   Pd/styrene-divinylbenzene, ethyl acetate synthesis, a 131
   Pd/support, animation of aldehydes and ketones 29
   Pd/ZrO2, CH4 combustion, a 132
   PdCl2/Al2O3, for margarine production 74
   Pt-Pd/CaCO3, hydrogenation of nitro aromatics 29
   Pt/Pd, for poly(diphenylsiloxane) formation, a 130
     for poly(diphenylsilylenemethylene) formation, a 130
   Rh-Pd-Cu, combinatorial catalyst library, a 131
Catalysts, Palladium Complexes, allyl aryl ethers, electrochemical cleavage, a 174
   bis(dibenzylideneacetone)Pd, for allyl, phenyl and vinyl siloxane coupling, a 132
   2, 3-dichloropyridines, alkoxycarbonylation, a 87
   with N ligands, kinetic screening, a 175
   orthopalladated triaryl phosphites, biaryl couplings, a 44
   Pd(0) B1AN, alkyne hydrogenation 105
     for coupling reaction 105
   Pd2(dba)3-BINAP-NaO′Bu, Buchwald-Hartwig coupling 29
   Pd with bidentate N ligand, for H2O2 synthesis, a 133
   Pd phosphines with diaminopropyl dendrimers, a 175
   Pd-catalysed addition of pronucleophiles, a 174
   Pd/Xantphos/TsOH, biphasic hydroxycarbonylation, 44
   Pd(F6-acac)2, for coupling reactions, a 132
   Pd(OAc)2, Heck reactions, a 87
   Pd(OCOCF3)2, for coupling reactions, a 132
   Pd(PPh3)4, 2-, 4-chloropyridines, Suzuki coupling, a 87
   Pd(PPh3)4 formation, F-catalysed, a 87
   phospha-palladacycles. Heck reactions, a 87
   pronucleophile addition to C-C multiple bonds, a 174
Catalysts, Platinum, EuroPt-1, cinnamaldeyde hydrogenation, a 44
   Pt(100), CO oxidation, a 86
   Pt, for poly(diphenylsiloxane) formation, a 130
     for poly(diphenylsilylenemethylene) formation, a 130
   Pt inclusion compounds, in PEFCs, a 45
   Pt systems, ethyl pyruvate hydrogention 29
   Pt-Pd/CaCO3, hydrogenation of nitro aromatics 29
   Pt-Rh, CeO2- and non-promoted, exhaust aftertreatment, a 86
   Pt-Ru/C electrocatalysts, for PEMFC, a 88
   Pt-Sn, C2H6 oxidation, a 174
   Pt/Al2O3, cinnamaldeyde hydrogenation, a 44
     enantioselective hydrogenation of trifluoroacetophenone 29
     NH3 oxidation 105
     pyruvates hydrogenation, a 174
   Pt/C, cinnamaldeyde hydrogenation, a 44
     determining oxygen in polymers 40
     electrocatalysts, for DMFC, a 133
     hydrogenation of aromatic nitro compounds 29
   Pt/CeO2, automotive exhaust purification, a 86
   Pt/MgO, CaO and R.E. oxides, CH4 conversion, a 43
   Pt/Pd, for poly(diphenylsiloxane) formation, a 130
     for poly(diphenylsilylenemethylene) formation, a 130
   Pt/PVP, pyruvates hydrogenation, a 174
   Pt/SiO2, cinnamaldeyde hydrogenation, a 44
   Pt/support, amination of aldehydes and ketones 29
   Pt/TiO2, NH3 decomposition 174
   Pt/ZrO2-CeO2, automotive exhaust purification, a 86
   [Pt(NH3)4]/HZSM-5, NH3 reactions 44, 105
   PtO2, heterocyclic amines formation, a 174
   Rh-Pt-Cu, combinatorial catalyst library, a 131
Catalysts, Platinum Complexes, Pt-CNR,/Pd-SiO2, cyclohexanone hydrogenation 114
Catalysts, Rhodium, hydroformylation 29
   Rh complexes/support, hydrogenation reactions 29
   Rh nanoparticles, arene hydrogenation, a 133
   Pd-Rh, Pt-Rh, CeO2- and non-promoted, exhaust aftertreatment, a 86
   Rh-Pd-Cu, Rh-Pt-Cu combinatorial catalyst library, a 131
   Rh/Al-MCM-41, NO reduction with C3H6, a 132
   Rh/CeO2/SiO2, CO hydrogenation, a 132
   [RhI2(CO)2], acetic acid hydrocarbonylation, a 44
Catalysts, Rhodium Complexes, cationic, for styrene derivatives hydroformylation, a 44
  enamine synthesis 29
   hydroformylation, intermediates 105
   in supercritical CO2, a 87
   [Rh2(OAc)4], chiral epoxides synthesis 105
   Rh cyclopentadienes, alkene hydrogenation 105
   Rh-CNR2/Pd-SiO2, arene hydrogenation 114
   Rh-CNR3/M-SiO2, arene hydrogenation 114
   Rh-xantphos, olefin hydroformylation 105
   RhCI(PPh3)3, maleic anhydride hydrogenation, a 133
   Rh(I) chiral diphosphines, for hydrogenations, a 175
   [Rh(μ-S(CH2)3NMe2)(cod)]2, hydroformylations, a 88
Catalysts, Ruthenium, β-ketoesters hydrogenation 29
   K2[Ru4(CO)13]/”Sibunit” C, for NH3 synthesis, a 132
   MOxRuySez/C, in fuel cells, a 45
   Pt-Ru/C eietrocatalysts, for PEMFC, a 88
   Ru complexes/support, hydrogenation reactions 29
   Ru-Co-Al-CO3 hydrotalcite, oxidation catalyst, a 87
   Ru-phosphine/clay, α-keto-esters and -amides, hydrogenation, a 87
   Ru/active charcoal pellets, glucose hydrogenation, a 86
   Ru/carbon molecular sieves 29
   Ru/MgF2, for hydrodesulfurisations, a 132
   RuO42−/poly(4-vinylpyridine), oxidation catalyst 94, 167
   RuO42−/zeolite-Y, oxidation catalyst 94, 167
Catalysts, Ruthenium Complexes, nitrile hydrogenation 29
   Ru, removal from olefin metathesis, a 175
   Ru carbene, olefin metathesis, a 88
   Ru porphyrins, alkene epoxidation, a 175
   RuCl2(=CHPh)(PCy3)2, metathesis reactions, a 175
   [RuCl26-arene)]2, β-ketoester hydrogenation, a 45
   RuCl2(PPh3)3, Baylis-Hillman adduct isomers, a 133
     methyl methacrylate polymerisation 45, 102
  Ru(ll) [p -cymene(PCy3)ClRu=C=C=CPh2]1CF3SO3, olefin metathesis, a 133
   Ru(II) oxazolinylferrocenylphosphine, ketones hydrogenation, a 88
   Ru(II) polyphosphines, carbonyl hydrogenation, a 88
   [RuO2Cl2(Y-py)2], for 1 -hexanol oxidation 94, 167
Cells, rechargeable 50
Chemical Fluid Deposition, Pt films, a 130
Chemiluminescence, see Luminescence
Chlorofluorocarbons, hydrodechlorination, a 86
Cinnamaldehyde, hydrogenation, a 44
Cinnamic Acids, by heterogeneous Heck reactions 138
Cisplatin, anticancer drug 61
  book review 103
Clusters, poly(oxyethylene)-grafted Pd, synthesis of, a 129
   Pt, in A12O3, a 130
   Ru carbonyl, a 41
   see also Nanoclusters
Coatings, noble metal aluminides, for gas turbines 59
   Ru(III) detector, for olefins detection, a 85
   see also Deposition and Electrodeposition
Cobalt, Co80Pt20 films on Ru(0001), magnetic anisotropy, a 83
   Co-Pt films, magnetic properties, a 83
Colloids, Pt, polymer-stabilised, a 83
   Rh, for biphasic catalysis, a 133
Combinatorial Chemistry, in catalysis 105, 131
   Rh-Pd-Cu, Rh-Pt-Cu alloy catalysts, a 131
Conferences, 3rd Anglo-Dutch Symp. Organomet. Chem. Appi. Catal., Sheffield, March, 1999 105
   7th Int. Conf. Chem. of the PGMs, Nottingham, July, 1999 58, 158
   1998 Fuel Cell Seminar, Palm Springs, California, Nov., 1998 14
   First Int. Conf. on Health Effects from Vehicle Emissions, London, Feb., 1999 71
   HYPOTHESIS III, St. Petersburg, July, 1999 166
Int. Fall Fuels and Lubricants Meeting and Exposition, San Francisco, Oct., 1998 28
   Int. Symp. on Iridium, Tennessee, March, 2000 12
   SAE, Detroit, U.S.A., March, 1999 119
   Seventeenth Conf. on Catal. of Organic Reactions, New Orleans, 29 March-2 April, 1998 29
   Sixth Grove Fuel Cell Symp., London, Sept., 1999 17, 149
   Third Noble and Rare Metals: NRM-2000, Donetsk, Ukraine, Sept., 2000 128
Copper, Cu-Pd/γ-Al2O3, Cu-Pd/SiO2, catalysts, a 86
   CuPd, nanometric particles, a 83
Coupling Reactions, biaryl synthesis, a 44
   Buchwald-Hartwig, for fluoroanilines synthesis 29
   see also Heck Reactions
   see also Suzuki Couplings
Creep, dispersion hardened Pt materials. Ir, Pt. Pt alloys, Rh, high temperature 18
CRT™, conference 71
Cyclohexanone, hydrogenation, a 88
Cyclohexene, hydrogenation, a 88
Dehydrogenation, EtOH, a 43
Dendrimers, diaminopropyl-type, + Pd phosphines, a 175
     Pt encapsulated 113
     Ru photoactive 69
Deposition, sub-μm Pt patterning on TiO2, a 43
   see also Coatings
   see also Electrodeposition
Deuterium, interaction with C60Pt, a 172
2, 3-Dichloropyridines, alkoxycarbonylation, a 87
Diesel, aftertreatment, at SAE 119
Diffusion, self-, in Pt, a 129
β-Diketoncs, Pt complexes, synthesis of, a 172
Dispersion Hardening, Pt and Pt alloys 18
DNA, probes, a 42, 84, 173
Dye, Pt, for electroluminescent devices 12
Electrical Contacts, non-alloyed ohmic contacts, to 111-V semiconductors 2
Electrocatalysis, Os phenanthrolinedione, NADH oxidation, a 173
Electrochemistry, a 173
Electrodeposition, nanostructurcd Pd, Pd-Fe films, a 43
  Pd on conducting graphite, a 173
   Pd-Co films, for contact finish applications, a 130
   platinised Pt, a 173
   Pt microparticles in sulfonate-polyaniline film, a 43
   Pt-Ru on Au, a 173
   see also Coatings
   sec also Deposition
Electrodeposition and Surface Coatings, a 42-43, 85, 130-131, 173
Electrodes, glassy C, poly[Ru(vbpy)32−]-modified, a 131
     poly[Ru(vbpy)32−/vba]-modified, a 131
   graphite, modified by Os phenanthrolinedione, a 173
   IrO2, Pt microparticles, sulfonate-polyaniline film, a 43
   [Os(bipy)2(PVP)10Cl]+ polymer modified, a 173
   photoelectrodes n -RuS2, activation, a 85
   platinised Pt, a 173
   Pt, hydrophobic, a 42
     low loaded, for PEFCs, a 133
     porous 157
   Pt/C, by ion beam sputtering, a 130
   Pt/lr, micro-, for intracellular measurements 167
   RuO2, high dielectric thin films on Si substrate, a 45
Electroless Plating, onto catalytic Pd/ZnO thin films, a 43
   for Ni-Ru-P membrane, a 43
Electroluminescent Devices, LEDs 12
Emission Control, at SAE 28, 119
   autocatalyst first manufacture 168
   conference 28, 71, 119
   lean-burn gasoline engine aftertreatment 28, 119
   new legislation 71, 119
   plasma technology 28
   three-way catalysts 28, 86, 199, 131, 168
   two-stroke engine aftertreatment 13, 28
Epoxidation, alkenes, a 175
Epoxides, chiral, synthesis of 105
Etching, electrochemical, of Pt/Ir microelectrodes 167
of Pt/lr microscopy tips, a 174
Ethane, oxidation, over Pt-Sn, a 174
Ethers, allyl aryl, electrochemical cleavage, a 174
Ethyl Pyruvate, hydrogenation 29
Ethylene, from C2H6 oxidation, a 174
Faujasite Cages, for anchoring, Ru carbonyl clusters, a 41
Films, Co80Pt20, on Ru(0001), magnetic anisotropy, a 83
   Co-Pt, magnetic properties, a 83
   CoPtRe, for magneto-optical disks, a 175
   [Os(bipy)2(PVP)10Cl]+, electrodes, a 173
   Pd and Pd-Fe, for H2 separation, a 43
   Pd-Co, electrodeposited, a 130
   Pt, by hydrogenolysis of dimethyl(cyclooctadiene)Pt(II), a 130
     for electrodes, by ion beam sputtering, a 130
   α-PtO2, by d.c.-sputtering, a 172
   see also Thin Films
Flat Panel Displays 12, 104
Fluoroalkanes, HFC-125, synthesis, a 86
Fuel Cells, a 45, 88, 133, 175
   Ballard 14, 149
   ball milling of catalysts, for PEFCs, a 175
   conferences 14 14, 17, 149
   Demonox™ 14
   DMFC 14
   flow field plates 14
   HotSpot™ reformer 14, 149
   MCFC 149
   membrane electrode assemblies, MEA 14
   MoRuSe electrocatalyst, O2 reduction, a 45
   PAFC 14, 149
   PEMFC, automobile application 14, 149
     CO tolerance of anodes, a 88
     portable and other applications 14, 149
      stationary power plant applications 14, 149
     transit bus application 14
   (Pt0.5R0.5 (Al4)) composite catalyst, for PEFCs, a 175
   Pt electrodes, for PEFCs, a 133
   Pt inclusion catalysts, for PEFCs, a 45
   Pt-Ru/C eletrocatalysts, morphology of, a 88
   Pt/C electrocatalysts, for DMFC, a 133
   Sixth Grove Fuel Cell Symposium 17, 149
   SOFC 149
Fullerenes, C60Pt, interaction with deuterium, a 172
   polymerisation, on Pt(111) surfaces, a 129
   Pt complex, a 41
Gas Turbines, nobel metal aluminide coatings 59
Gauzes, Pt loss from 62, 167
   Pt-Pd-Rh, Pt-Rh, for nitric acid manufacture 62, 167
Glass, direct-heated Pt systems, a 88
Glasses, RuO2/glass nanocomposites, a 84
Glucose, hydrogenation, a 86
Grove Fuel Cell Symposium, Sixth 17, 149
Heck Reactions, of aromatic halides, a 87
   cinnamic acids, synthesis 138
   heterogeneous 29, 138
   in high temperature water, a 87
   homogeneous 29, 138
   in non-aqueous ionic liquids, a 87
   Pd catalysts 29, 87
Heterocycles, by hydroamination, a 174
   by hydroformylation in scCO2 29
   by hydrogenation, a 174
High Temperature, mechanical properties, of PGMs 18
History, 25 years of autocatalyst manufacture 168
   Hans Merensky 146
   Johann Wolfgang Dõbereiner 122
   Merensky Reef discovery, South Africa 146
   transport of platina to Spain, late 18th century 31
HotSpot™ Reformer, conferences 14, 149
Hydroboration, Rh catalysed 29
Hydrocarbonation, alkenes, allenes, a 174
Hydrocarbons, aromatics, oxidation, by Ru-Co-Al-CO3 hydrotalcite/O2, a 87
   sensor, Pt Schottky diodes on n -type GaN, a 173
Hydrocarbonylation, acetic acid, a 44
   alcohols, olefins, organohalides 154
Hydrodechlorination, CFC-115, with Pd/C, a 86
Hydrodenitrogenation, pyridine, a 132
Hydroesterification, styrene, a 44
Hydroformylation, alkenes 154
   allyl ethers, a 88
   heterocycle synthesis 29
   1-octene 114
   olefins 44, 105
   in supercritical CO2, a 87
   in situ spectroscopic studies 105
   styrene derivatives, a 44
Hydrogen, effects on physical properties of Pd 116
   from methane, a 43
   H2-promoted self-diffusion of Pt, a 129
   HYPOTHESIS III Symposium 166
   interaction with IrXH2(PPr’3)2, (X = Cl, 1), a 84
   non-destructive testing for, using Pd-SiO2/Si 155
   sensor, Pt Schottky diodes on n -type GaN, a 173
   separation by Pd and Pd-Fe films, a 43
Hydrogen Peroxide, biphasic synthesis of, a 133
Hydrogen Sulphide, reaction with Ru5C(CO)15, a 133
Hydrogenation, alkcncs 105
   alkyl aryl ketones, alkyl methyl ketones, a 88
   alkynes 105
   allyl alcohol 29
   arenes 114, 133
   cinnamaldehyde, a 44
   CO, a 132
   cyclohexanone, a 88
   2-cyclohexen-l-one, a 88
   cyclohexene, a 88
   ethyl pyruvate 29
   glucose,a 86
   halogenated nitro aromatic compounds 29
   α-ketoamides, α-ketoesters, a 87
   β-ketoesters, a 45
     cyclic 29
   maleic anhydride, a 133
   nitriles 29
   nitro aromatic compounds 29
   nitrobenzenes, with aldehyde substituents, a 174
   propanal, a 88
   pyruvates, a 174
   trifluoroacetophenone 29
   vegetable oils 74
Hydrogenolysis, dimethyl(cyclooctadiene)Pt(II), a 130
Hydrotalcites, Ru-Co-Al-CO3 catalyst, a 87
Hydroxycarbonylation, alkenes, a 44
Indium, R2Pd2In (R = rare earth), properties, a 83
Iridium, conference 12
   high temperature mechanical properties 18
   Ir-modified aluminides, coatings for gas turbines 59
   Pt/Ir microelectrodes, electrochemical etching of, 167
   Pt/Ir microscopy tips, electrochemical etching, a 174
Iridium Complexes, IrXH2(PPr’3)2, (X =Cl, I), interaction with H2, a 84
   PGM Conference 158
Iridium Compounds, IrO2 thin films, by reactive pulsed laser deposition, a 131
     on Si(100) substrates, a 131
   Pt/IrO2 electrodes, a 43
Isomerism, of Baylis-Hillman adducts, a 133
   of bis(2-hydroxy-4’-methylazobenzenato)Pt(II), a 129
Johnson Matthey, 25 years of, autocatalyst manufacture, 168
   autocatalyst plant for India 70
   autocatalysts, three-way 28
   CRT™, particulate filter trap 71
   Demonox™ CO clean-up unit 14
   fuel cell technology, MEAs 14
   HotSpot™ reformer 14, 149
   motorcycle catalyst test facility 13
“Platinum 1999” 118
α-Ketoamides, hydrogenation, a 87
α-Ketoesters, hydrogenation, a 87
(β-Ketoesters, cyclic, hydrogenation 29
   hydrogenation, a 45
Ketones, hydrogenation, a 88
Lean Burn, gasoline engines, at SAE 119
LEDs, 2, 12, 43
   from Ru(Il) terpyridine containing polyimides, a 130
  solid-state, from Ru(bpy)3(PF6)2 104
Liquid Petroleum Gas, sensor 165
Living Radical Polymerisation, of methacrylates 45, 102
Luminescence, chemi-, Ru complex, a 42, 43
   Os(II) dipyridophenazines, as probes for DNA, a 84
   photo-, by [Pt(thpy)(bzim)]3, a 130
   Pt cyclometallated complexes, for O2 sensor, a 85
   quenching, in Ru(II) phenanthrolines, a 85
   Ru(bipy)32+ -KBrO3, sulfite determination, a 85
   [Ru(bpy)3]2− photoactive dendrimers 69
   Ru(bpy)3(PF6)2/lTO 104
   Ru(II) bipy polyazo receptors, as anion sensors, a 130
   Ru(II) polypyridyl complexes, a 173
   Ru(II) terpyridine, a 130
Magnetism, anisotropy, of Co80Pt20 on Ru(0001), a 83
   in CaTIn2 (T = Pd, Pt), a 129
   Co-Pt sputtered films, a 83
   FePd alloy, chiral magnetic domain structures, a 172
   in R2Pd2ln (R = rare earth), a 83
Margarine, Pd catalysts, for production of 74
MEAs, in fuel cells 14
Membranes, Ni-Ru-P/ceramic, for EtOH dehydrogenation, a 43
   Pd and Pd-Fe, for H2 separation, a 43
Merensky Reef, 75th anniversary of discovery 146
Metallodendrimers, Pt, gas sensor materials, a 131
Metathesis, acyclic diene, a 175
   olefins, a 133
     removal of unwanted Ru, a 175
   ROMP catalysts 158
   Ru catalyst, recyclable, a 88
Methane, combustion, over Pd/ZrO2, a 132
   conversion to CO and H2, a 43
   oxidation, in cold-plasma reactors 109
     Pd/mixed oxides, a 86
   photodissociation on Pd, a 84
Methyl Methacrylate, polymerisation of 45, 102
MOCVD, Pt 157
     RuO2 thin films 45, 157
NADH, oxidation of, a 173
NAIL, for Heck reactions, a 87
“Naklep”, hydrogen-phase phenomenon 116
Nanoclusters, Pt/Al2O3, Pt/PVP, a 174
Nanocomposites, RuO2 glass, a 84
Nanoparticles, supported Cu-Pd catalysts, a 86
   Pd and CuPd, on NaCl(lOO), a 83
   Pt, on amorphous C film, a 130
     by electrocrystallisation, a 130
     by sonochemical reduction 108
     encapsulated by dendrimers 113
     on sol-gel modified C film, a 130
     thiol-functionalised, a 172
   Rh colloids, in biphasic catalysis, a 133
Nanostructures, single monolayer of Ag on Ru(0001) 73
Nanotechnology, Pd and Pd-Fe alloy films, a 43
   Pt porous fibres, replication of base 61
Nickel Alloys, Pd-Ni alloy composite membrane, a 85
   rechargeable battery technology 50
Niobium, NbRu alloy, shape memory effect, a 41
Nitric Acid, manufacture, gauze technology 62, 167
Nitriles, hydrogenation, Ru complexes 29
Nitrobenzenes, hydrogenation of, a 174
Nitrogen, fixation, by Ru model complexes 158
Nitrogen Oxides, NO, AMD-6221 in vivo scavenger 158
     reduction, by Pd/metal oxides, a 44
       with C3H6, over Rh/Al-MCM-41, a 132
NMR, 187Os, 103Rh, a 131
1-Octene, hydroformylation 114
Ohmic Contacts, see Electrical Contacts
Olefins, hydrocarbonylation 154
   hydroformylation 44, 87, 105
   metathesis, a 88, 133
   Ru(lII)/cryptand-coated GC detector for, a 85
Organohalides, hydrocarbonylation 154
Osmium, 187OS, NMR, a 131
Osmium Complexes, Os3(CO)12, photolysis, a 173
   [Os3(CO)12], thermal decomposition, a 84
   Os phenanthrolinedione, NADH oxidation, a 173
   [Os(bipy)2(PVP)10Cl]1, polymer film electrodes, a 173
   Os(dmpe)2H2, photochemical properties, a 84
   Os(II) dipyridophenazine, photoproperties, a 84
   PGM Conference 158
Osmium Compounds, Os-O thin films from OsO4, a 131
Oxidation, alcohols, 87, 94, 167
   aromatic compounds, a 87
   C2H5OH, on Pd/LiNbO3, using acoustic oscillations 82
   C2H6, a 174
   CH4, in cold-plasma reactors 109
     over Pd/mixed oxides, a 86
   CO, over O-rich Ru(0001), a 172
     on Pt(1OO), a 86
   NADH, a 173
   NH3, Pt complex, a 44
     to N2, and H2O 105
   silicon, Pt-enhanced, a 41
   Sn/Pt(III) surface alloys, a 83
   VOCs, in cold-plasma reactors 109
   o -xylene, over Pd/zeolite, a 86
Oxygen, evolution, by n -RuS2 photoelectrodes, a 85
   in polymers, determination of 40
   reduction, in fuel cells, by MoRuSe electrocatalyst, a 45
     by Pt catalyst, a 45
   sensors, cyclometallated Pt complexes, a 85
     Ru(II) phenanthrolines in polydimethylsiloxane, a 85
Palladium, catalytic on ZnO thin films, for electroless plating, a 43
   CVD thin films, from allyl(β-ketoiminato)Pd(II), a 129
   electrical contacts 2
   electrodeposition, on conducting graphite, a 173
   H2 effects on 116
   membranes, for H2 separation, a 43
   nanometric particles, a 83
   nanostructured films, a 43
   NiMH surface modification 50
   Pd-SiO2/Si, for hydrogen detection 155
   Pd/Ru coating, for rechargeable batteries 50
   thin films, on α- and γ-Al2O3, a 85
   with tin oxide, sensor, for liquid petroleum gas 165
Palladium Alloys, CuPd nanometric particles, a 83
   FePd films, chiral magnetic domain structures, a 172
   Pd-Cd, for contact finish applications, a 130
   Pd-Fe membranes, for H2 separation, a 43
   Pd-Fe nanostructured films, a 43
   Pd-H, superstrength, hydride TRIP-effect 116
   Pd-Ni composite membrane, a 85
   Pd-Ni-P phase transformations, a 41
   Pt-Pd-Rh catalyst gauzes 62, 167
   R2Pd2In (R = rare earth), properties of, a 83
Palladium Complexes, allyl(β-ketoiminato)Pd(II), a 129
   Pd with 1, 4-bis(3-pyridyloxy)benzene, a 83
   Pd(O2), (O2)Pd(O2) from laser-ablated Pd, a 172
   PGM Conference 158
Palladium Compounds, CaPdln2, synthesis of, a 129
   Pd clusters, poly(oxyethylene)-grafted, a 129
   UPd2Al3, heavy fermion superconductor, a 129
Patents 46-48, 89-92, 134-136, 176-178
PEMFC, fuel cells 14, 149
Petroleum, liquid gas, sensor 165
Phase Diagrams, Pd-Ga-As, Pd-ln-P, Pt-Ga-As, Pt-In-P 2
Phosphorescence, Pt dye 12
Photoconversion, a 42, 84-85, 130, 173
Photoluminescence, see Luminescence
Photolysis, UV, of M3(CO)12 (M= Os, Ru), a 173
Photoproperties, dithiocarbamate-Ru polypyridyl, a 42
   mono- and di-nuclear complexes 158
   Os(dmpe)2H2, a 84
   Os(II) dipyridophenazine complexes, a 84
   Pt-loaded TiO2 particles, a 42
   [Pt(thpy)(bzim)]3, photoluminescence, a 130
   Ru complexes, photoprobes for DNA, a 42
   [Ru(bpy)3]2+ photoactive dendrimers 69
   Ru(II) bipyridyl polyaza receptors, as sensors, a 130
   RuO2/Na2Ti3O7, photocatalyst, a 42
   n -RuS2 photoelectrodes, a 85
Photoreactions, CH4 photodissociation on Pd, a 84
   of KI solutions, a 42
   O2 reduction by immobilised [Ru(bpy)3]2+/Co(III), a 42
   Os3(CO)12, Ru3(CO)12, solvent effects, a 173
   [Ru(bipy)3]2+ derivatives, with cytochrome P450cam, a 85
   Ru(bpy)3]3+/zeolite Y with water, a 42
   water decomposition, by RuO2/Na2Ti3O7, a 42
Plasma, cold-, for VOCs and CH4 oxidation 109
Plasma Technology, for auto emission control 28
Platina, in New Granada, history 31
Plating, Pt hydrophobic electrodes, a 42
“Platinum 1999” 118
Platinum, adhesion to PVDF 145
   clusters, in Al2O3 membrane, a 130
   colloids, Pt/PVP nanoscale, a 83
   direct-heated Pt systems, in glass processing, a 88
   discovery of the Merensky Reef 146
   dye 12
   electrical contacts 2
   electrodes, high surface area 157
     hydrophobic, a 42
     Pt/C, by ion beam sputtering, a 130
   H2-promoted self-diffusion of, a 129
   high temperature mechanical properties 18
   ion beam sputtering of 145, 157
   microparticles in sulfonate-polyaniline film, a 43
   nanofibres, porous 61
   nanoparticles, by sonochemical reduction 108
     electrocrystallised on C film, a 130
     encapsulation by dendrimers 113
     thiol-functionalised, a 172
   for oxidation of silicon, a 41
   platinised, IR absorption of CO on, a 173
   porous 61, 157
   Pt(111) surfaces, polymerisation of C60, a 129
   Pt, sub-μm pattern on TiO2, a 43
   Pt/Ir microelectrodes, electrochemical etching of, 167
   Pt/Ir microscopy tips, electrochemical etching of, a 174
Platinum Alloys, Co80Pt20 films on Ru(0001), magnetic anisotropy, a 83
   Co-Pt films, magnetic properties, a 83
   CoPtRe films, as MO recording material, a 175
   high temperature mechanical properties 18
   Pt-Pd-Rh, Pt-Rh catalyst gauzes 62, 167
   Pt25Rh75(100), Pt25Rh75(111), surface segregation, a 129
   Pt-Ru, electrodeposited on Au, a 173
   Sn/Pt(III) surface alloys, oxidation of, a 83
Platinum Complexes, bis(2-hydroxy-4′-methylazobenzenato)Pt(II), isomers, a 129
   C60Pt, interaction with deuterium, a 172
   dimethyl(cyclooctadiene)Pt(II), hydrogenolysis, for Pt films, a 130
   fullerenes, a 41
   octaethylporphine Pt(II), dye 12
   PGM Conference 158
   Pt cyclometallated complexes, for O2 sensor, a 85
   Pt cyclopentadiene, MOCVD precursor 157
   Pt diketonate, cationic, synthesis, a 172
   Pt diynes, synthesis and properties of, a 84
   Pt metallodendrimers, gas sensor materials, a 131
   Pt polyynes, synthesis and properties of, a 84
   Pt(acac)2, as precursor for porous Pt nanofibres 61
   Pt(IV) complexes, as antitumour agents 61
   Pt(O2), (O2)Pt(O2), from laser-ablated Pt, a 172
   [Pt(thpy)(bzim)]3, photoluminescence, a 130
Platinum Compounds, antitumour agents 103
   CaPtIn2, preparation of, a 129
   Pt oxides, from laser-ablated Pt, a 172
   α-PtO2, sputtering of 157, 172
Polyhydrides, IrXH2PPri 3)2 (X = Cl, I), a 84
Polyimides, with Ru(II) terpyridine, for LEDs, a 130
Polymerisation, C60 on Pt(111), a 129
   living radical, of methyl methacrylate 45, 102
Polymers, determining O2 in 40
   inorganic, 1[PdPS4], [PtCl2(Pn Bu3)2] with pyrazine, a 84
   living radical 45, 102
   [Os(bipy)2(PVP),10Cl] films, electrodes, a 173
   PVDF, Pt adhesion to 145
Pronucleophiles, addition to C-C multiple bonds, a 174
Pyridine, hydrodcnitrogenation, a 132
Pyruvates, hydrogenation, over Pt catalysts, a 174
Rare Earths, R2Pd2In (R = rare earth), properties, a 83
Reactors, cold-plasma, for VOCs and CH4 oxidation 109
   membrane, for dendritic Pd catalysts, a 175
   micro-, for screening of catalyst libraries 105
   Trickle-Bed, for hydrogenations, a 86
Recording Film, CoPtRe, for MO disks, a 175
Recovery, separation of product/catalyst 158, 175
Reduction, NO, by Pd/metal oxides, a 44
O2, by [Ru(bpy)3]2 with macrocyclic Co(III), a 42
Rhodium, 103Rh, NMR, a 131
   high temperature mechanical properties 18
Rhodium Alloys, Pt25Rh25(100), Pt25Rh75(111), surface segregation, a 129
   Pt-Pd-Rh, Pt-Rh catalyst gauzes 62, 167
Rhodium Complexes, PGM Conference 158
   Rh(I) chiral diphosphine, hydrogenation catalysts, a 175
Rhodium Compounds, HfRhSi. TiRhSi, ZrRhSi, superconductivity of, a 83
   Sr3M RhO6 (M = Y, Sc, In), synthesis, a 41
Ruthenium, NiMH surface modification 50
   Pd/Ru coating, for rechargeable batteries 50
   Ru(0001), O-rich surfaces, CO oxidation, a 172
     single monolayer of Ag on, nanostructures 73
   stainless steel, surface composition, a 41
Ruthenium Alloys, Ni-Ru-P composite membrane, a 43
   Pt-Ru, electrodeposited on Au, a 173
   shape memory effect, NbRu, TaRu, a 41
Ruthenium Complexes, C5Me5Ru(PR3)2Cl, a 172
   dithiocarbamate-Ru polypyridyl, photoproperties, a 42
   PGM Conference 158
   poly Ru vbpy/vba-modified electrodes, a 131
   Ru3(CO)12, photolysis, a 173
   [Ru3(CO)12], thermal decomposition, a 84
   Ru5C(CO)15, for dehydrosulfurisation, a 133
   Ru carbonyl clusters in faujasite cages, a 41
   Ru cyclopentadiene, MOCVD precursor 157
   Ru model complexes, for nitrogen fixation 158
   [Ru(bipy))]32+, photoreactions with P450cam, a 85
   Ru(bipy)32−-KBrO3, for sulfite determination, a 85
   Ru(bpy)2(PF6)2, for solid state LEDs 104
   [Ru(bpy)3]2+ + macrocyclic Co(III), photoreactions, a 42
     for O2 reduction, a 42
     photoactive dendrimers 69
   Ru(bpy)3, in electrochemical LEDs, a 43
   Ru(bpy)3Cl2, chemiluminescence, a 42
   Ru(bpy)33− -zeolite Y with water, photoreactions, a 42
   Ru(II) bipy polyazo receptors, luminescent sensors, a 130
   Ru(II) oxazolinylferrocenylphosphine, a 88
   Ru(II) phenanthrolines, for O2 sensors, a 85
   Ru(II) polypyridyl, luminescence, a 173
   Ru(II) terpyridine containing polyimides, a 130
   Ru(III)/cryptand-coated detector, for olefins, a 85
   Ru(phen)2(PHEHAT)2+ and Ru(TAP)2(PHEHAT)2+, photoprobes for DNA, a 42
   [RuVI(Por)(NTs)2], in amidations, aziridinations, a 175
   [RuVI(Por)O2], for alkene epoxidation, a 175
Ruthenium Compounds, Bi2Ru2O7-y, O control, a 84
   RuO2, high dielectric thin films, a 45
     highly conductive thin films, on SiO2/Si, a 45
     thin films, by MOCVD 45, 157
   RuO2/Bi2O3 annealing, Bi2Ru2O7-y formation, a 84
   RuO2/glass nanocomposites, a 84
   RuO2/Na2Ti3O7, for H2O photodecomposition, a 42
   n -RuS2, photoelectrodes, a 85
   Sr2RuO4, superconductivity, a 41, 88
   SrRuO3/(Ba,Sr)TiO3/SrRuO3 epitaxial capacitor,a 45
Schottky Diodes, Pt, on n- type GaN, a 173
Semiconductors, III-V, electrical contacts to 2
Sensors, DNA, a 84, 173
   H2 detection 155, 173
   hydrocarbon, a 173
   liquid petroleum gas 165
   luminescent, a 173
   O2, a 85
   olefins, a 85
   propane,a 173
   SO2, a 85, 131
   sulfite, a 85
Shape Memory Effect, in NbRu, TaRu alloys, a 41
Silicon, Pd-SiO2/Si, for hydrogen detection 155
   Pt-enhanced oxidation, a 41
Siloxanes, cross-coupling, a 132
Silver, single monolayer on Ru(0001), nanostructures 73
Sol-Gel, O2 sensor, a 85
     Pd/γ-Al2O3, catalysts, preparation of, a 174
Sonochemistry, for Pt nanoparticles preparation 108
Sputtering, ion beam, of Pt 145
   of α-PtO2 157, 172
Steel, stainless, Ru duplex, surface composition, a 41
Stress-Rupture, properties of PGMs 18
Styrene, hydroesterification, hydroformylation, a 44
Sulfite, sensor, a 85
Sulfur Oxides, SO2, determination, a 85
     gas sensor materials for, a 131
Superconductivity, HfRhSi, TiRhSi, ZrRhSi, a 83
   Sr2RuO4, flux-line lattices, a 88
     time-reversal symmetry-breaking, a 41
Superconductors, heavy fermion, UPd2Al3, a 129
Supramolecules, with nitrogen ligands 158
Suzuki Couplings, 2- and 4-chloropyridines, a 87
Tantalum, TaRu alloy, shape memory effect, a 41
Thin Films, epitaxial, UPd2Al3, a 129
   FePd alloy, chiral magnetic domain structures, a 172
   IrO2, by reactive pulsed laser deposition, a 131
     on Si(100) substrates, a 131
   Os-O, by d.c.-glow-discharge, a 131
   Pd, by CVD, from allyl(β-ketoiminato)Pd(II), a 129
   Pd onto α - and γ-Al2O3, a 85
   Pd and Pd-Fe, for H2 separation, a 43
   Pd on ZnO, a 43
   Pd-SiO2/Si, for hydrogen detection 155
   poly(diphenylsiloxane), a 130
   poly(diphenylsilylenemethylene), a 130
   Pt, by MOCVD 157
   Ru(bpy)2(PF6)2 for solid state LEDs 104
   RuO2, by MOCVD 45, 157
     high dielectric, a 45
     highly conductive, a 45
   see also Films
Three-Way Catalysts 28, 86, 119, 131, 168
Transistors, FET, HBT, JFET 2
Ultrasound, Pt systems, ethyl pyruvate hydrogenation 29
Umpolung, of aryl-Pd species, a 174
VOCs, oxidation 86, 109
Water, decomposition, photocatalyst, a 42
   high temperature, as solvent for Heck Reactions, a 87
    photoreactions, a 42
Xylene, oxidation, a 86

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