Subject Index TO Volume 46

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Platinum Metals Rev., 2002, 46, (4), 199

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a = abstract	Page
Acetates, methyl, from MeOH, a	139
Acetylenes, phenyl-, oligomerisation, a	190
polymerisation, a	140, 190
Acid Chlorides, hydrogenation	73
Acrylic Acids, asymmetric hydrogenation	180
ACT^™, Pt, Pt-Rh coatings, for the glass industry	181
Activation, CH₄, a	87
Alcohols, allylic, arylation, a	41
C-C bond formation, with enoxysilane, a	140
aromatic, transfer dehydrogenation, a	40
2-arylcyelohexenols, to 2-arylcyclohexenes, a	139
methyl, conversion, to methyl acetate, a	139
decomposition, a	190
electrooxidation	106
DMFCs	88, 146
oxidation, a	42, 84
oxidation, a	42, 84, 191
aerobic	26
selective	24
Aldehydes, from acid chlorides	73
from alcohols	26, 191
Alfa Aesar, Fuel Cell Catalysts Brochure	14
Alkali metals, iodides, effects on Pd, Pt cathodes,
in superdry conditions	94
Alkenes, dihydroxylation	24
from alkynes	73
oxidation, a	39
Alkoxycarbonylation, chloropyridines, a	87
Alkylacrylates, copolymerisation with ethene, a	139
Alkynes, hydroalkenylation, a	139
hydroarylation, a	139
hydrogenation	73
hydrosilylation, a	138
Alloys, dental, a	88
jewellery	66
Aluminium, Al-Mg-Pd, melt oxidation, a	38
Al-Pd-Co, U-, V-phase, structures, a	38
Amination, aryl halides with an ammonia analogue	50
Hartwig-Buchwald	50
Amines, in fast living radical polymerisation, a	140
Amino Acids, L-DOPA synthesis	82
Ammonia, oxidation, over Pt	24
Aquation, cis -, trans-Pt(Ypy)₂(NO₃)₂, a	188
Arenecarboxylic Acids, synthesis, a	41
Arenes, hydrogenation, a	42, 138
iodo-. homocoupling, a	139
Aroyl Halides, microwave-assisted phenylation, a	87
Aryl Halides, arylation, of allylic alcohols, a	41
cross-coupling reactions	50
dehalogenation, a	41
Heck reactions	50, 139
Suzuki couplings, a	190, 191
Arylation, allylic alcohols, a	41
α-amino acid esters, a	87
N -AryIation, aryl indoles	50
Arylboronic Acids, coupling reactions	41, 50
autocatalysts, technologies adopted by EU	27
Biomimetic Assemblies, in photosynthesis, a	85
Book Reviews, “Catalysis of Organic Reactions”	23
Catalysts & Catalysed Reactions	65
“Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis”	73
“Modern Electrochemistry”	15
“Progress in Hydrogen Treatment of Materials”	37
Buchwald-Hartwig Couplings	50
Bushveld Complex, PGE geology, conference	177
Cancer, drugs	88, 165, 166
Capacitors, container, with Pt films, for memory Cells	107
IrO₂/PLZTVPt. Pt/PLZTm, Η-damage, o	42
Capacitors, (cont.)
memory, Pt-PtO_x thin film electrodes, a	88
MIM, Pt thin film electrodes, a	189
Pt/SrBi_2.2Ta₂O₉/Pt, annealing effects, a	88
Carbenes, Pd, N -heterocyclic nucleophilic	50
Ru, a	87, 140
Carbon Oxides, CO₂, methanation, a	86
poisoning, in PEMFC	122
reforming of propane, a	41
supercritical, solvent	139, 165, 176
CO, chemisorbed, on Pt, PtRu nanoparticles	106
copolymerisation, with ethene. a	139
effects in fuel Cells	106, 117. 146
electrooxidation	106. 106, 191
poisoning, in PEMFC	118
reaction with O₂, a	40
Carbonylation, with aryltin compounds, a	41
Carboxylic Acids, arene-, synthesis, a	41
in ketone synthesis, a	41
α,β-, β,γ-unsaturated, hydrogenation	82
Catalysis, book reviews	106, 65, 73
conferences	106, 24, 165, 167
heterogeneous, a	106–4l, 86, 138-139. 189-190
homogeneous, a	106–42, 87, 139-140, 190-191
in ionic liquids, a	191
low temperature fuel Cells	106, 64, 117, 146
in sc-CO₂	106,165,176
Catalysts, dendrimers	167, 180
in fat hardening	23
fixed bed reactors, design aspects	144
high purity gas production	144
homogeneous, supported	23
pgm/C, paste, powder, preferences	48
recycling	106, 41, 176, 180, 190, 191
three-way, see Three-Way Catalysts
Catalysts, Iridium, Ir black, NOx reduction	24, 41
RuO₂/IrO₂, to sustain H₂O electrolysis, in PEMFCs	132
Catalysts, Iridium Complexes, [(cod)IrCl]₂, a	140
[Ir(cod)(PPh₃)₂]X, for C–C: bond formation, a	140
Ir(I), for hetero-Heck type reaction, a	139
Catalysts, Osmium, Os_x(CO)_x/Vulcan C. in PEMFCs, a	106
Catalysts, Osmium Complexes,
OsO₄ + cinchona alkaloid, dihydroxylation	82, 191
OsO₄/FibreCat^™, dihydroxylation	24
Catalysts, Palladium, K₅PPdW₁₁O₃₉·12H₂O/γ-Al₂O₃,/C, hydrogenation of arenes, a	138
LaFeCoPdO, for automotive emissions control, a	190
Lindlar	73
Pd nanoparticles/Al₂O₃/NiAl, MeOH decomposition, a	106
Pd-Bi/C, glucose selective oxidation, a	138
Pd-perovskite, automotive emissions control, a	190
Pd-Pt/AIMCM-41, n -decane isomerisation, a	189
Pd/Al₂O₃, aromatic alcohol dehydrogenation, a	40
hydrodechlorination of chlorinated olefins, a	138
Pd/Al₂O₃ + Mg mesh, phenol hydrogenation, a	190
Pad/y-Al₂O₃, 4-chloro-2-nitrophenol hydrogenation, a	86
Pd/AlMCM-41, n -decane isomerisation, a	189
Pad/BaSO₄, hydrogenation of acid chlorides	73
selective poisoning, with thioquinanthrene	73
Pd/bulk MgO single crystal, particle morphology	24
Pd/C, paste, commercial	48. 92
liquid phase batch hydrogenation	92
powder, commercial	48
+ soluble Bi, glucose selective oxidation, a	138
Suzuki coupling, a	190
Pd/CeO₂/Al₂O₃, thiophene, VOC, oxidation, a	138
Pd/Fe, Pd/Mg, phenol hydrogenation, a	190
Pd/Pb-doped CaCO₃, hydrogenation of alkynes	73
modified with pyridine, quinoline	73
Pd/support, aromatic alcohol dehydrogenation, a	40
PdCl₂-CuCl₂. myrcene oxidation, a	190
transfer of oxide ions, to a catalyst substrate	165
Catalysts, Palladium Complexes, π-allyl-Pd,
asymmetric synthesis of: (-)-haemanthidine,
(-)-mesembrane, (-)-mesembrine,
(+)-crinamine, (+)-pretazettine a	139
(n³-allyl)Pd intermediate, allylsilanes cyclisation a	41
for cross-coupling reactions 50.	165
(dippf)PdCl₂, (dippf)PdCl(CH₃), polymerisation a	190
(dppe)PdCl₂, (dppe)PdCl(CH₃), oligomerisation a	190
(dppf)PdCl₂, (dppf)PdCl(CH₃), polymerisation a	190
FibreCat^™, Suzuki coupling a	190
N -heterocyclic nucleophilic carbenes, for C–C C–N	50
Pd, for poly(para -phenylene) polymer, synthesis	187
Pd(O) tricyclohexylphosphine, coupling reaction a	41
Pd-phosphino-oxazoline allyl, ‘meta-dialkyl effect'	167
Pd-polymer-bound phosphine, Suzuki coupling a	191
PdCl₂(Ph₃P₃)₂/dppb, alkoxycarbonylation a	87
Pd(dba)₂ + phosphinobenzene sulfonic acid a	139
Pd(dba)₂/(trimethylphenyl)dihydroimidazolium salt a	41
Pd₂(dba)₃/phosphine, α-amino acid ester arylation a	87
Pd(II) acetate-pyridine/hydrotaicite, aerobic oxidation	26
Pd(II) salt, carbonylation of aryltin compounds a	41
Pd(OAc)₂, arylation of allylic alcohols a	41
Pd(OAc)₂. for cross-coupling reactions	50
Pd(OAc)₂ + phosphinobenzene sulfonic acid a	139
Pd(OAc)₂ + PPh₃, synthesis of isoxazolidines a	190
Pd(OAc)₂ + P(o -tolyl)₃, for coupling reactions a	139
Pd(OAc)₂/dppf, alkoxycarbonylation a	87
Pd(OCOCF₃)₃/P(2-furyl)₃, iodoarene homocoupling a	139
Pd(PPh₃)₂Cl₂, microwave promoted phenylation a	87
Pd(PPh₃)₄, unsaturated N -chloroamine cyclisation. a	139
Catalysts, Platinum, CH₄ partial oxidation	24
electrocatalysts, anodes, for fuel Cells 117,	146
cathodes, for fuel Cells 3,	146
nanoparticles. Pt, for DMFC a	88
Pt/γ-Al₂O₃, preparation	115
NH₃ oxidation	24
Pd-Pt/AIMCM-41, n -decane isomerisation. a	189
Pt black, electrocatalysts, cathodes, for DMFCs	146
Pt-Rh/Al₂O₃, TWC, CO + O₂ reaction a	40
Pt-Sn/Al₂O₃, for cyclohexane dehydrogenation.
n -octane reforming, n -pentane isomerisation a	40
Pt/Al₂O₃, Ce addition, phenol wet oxidation a	138
for cyclohexane dehydrogenation. n -octane
reforming, n -pentane isomerisation a	40
hydrocarbon oxidation a	86
impregnated using H₂PtCl₆, Pt(NH₃)₄Cl₂, a	138
+ Rh/Al₂O₃, hydrocarbon oxidation a	86
Pt/Al₂O₃/Al monoliths. VOC oxidation a	189
Pt/AIMCM-4l, n -decane isomerisation a	189
Pt/C, 4-chloro-2-nitrophenol hydrogenation. a	86
hydrosilylation of alkynes. a	138
MeOH oxidation a	42
NO decomposition a	86
O₂ reduction reaction a	42
Pt/CeO₂-ZrO₂, in high throughput screening a	190
Pt/graphite, cinchona-modified, for hydrogenation. a	86
Pt/Ni, Pt/Ru, Pt/Ru/Ni, nanoparticles, for DMFC a	88
Pt/SPE membrane, preparation a	40
Pt/wide-pore SiO₂, polystyrene hydrogenation. a	86
PtCr, PtFe, PtMn, PtNi, PtTi, PtZr, electrocatalysts.
cathodes, for PEMFCs	3
PtMo. electrocatalysts, anodes, for PEMFCs	117
PtRu, fuel Cell electrocatalysts	14, 88, 106, 117, 146, 191
CO tolerance in fuel Cells	106, 122
PtRu/C, fuel Cell electrocatalysts	14, 117, 140. 146, 191
Pt,Sn/Mg(Al)O, propane dehydrogenation a	40
Catalysts, Platinum Complexes, Pt(bpym)Cl₂,
Pt(NH₃)Cl₂, for CH₄ activation a	87
Catalysts, Rhodium, Pt-Rh/Al₂O₃, TWC, CO + O₂ a	40
Rh aluminosilicate, laminar, zeolitic structures a	138
anchoring [Rh(Me₂CO),(2,5-norbornadiene)\|CI0₄ a	138
Rh/Al₂O₃, film, model catalyst	24
hydrocarbon oxidation a	86
+ Pt/Al₂O₃, hydrocarbon oxidation a	86
Rh/TiO₂, with propene, NOx reduction	24
Catalysts, Rhodium Complexes, alkenyl-Rh. aryl-Rh. a	87
with fluoroorganic groups, solubility in Sc-CO₂	165
in fluorous phases	165
Rh₂(OAc)₂, for 1,3-dipolar cycloaddition. a	191
Rh-polymer sc-CO₂ soluble	176
[Rh(A)CO]*/SiO₂. hydroformylation-hydrogenation a	41
[Rh-(-)-BINAP(COD)]ClO₄, in L-menthol process	82
[Rh(COd)(MeCN)₂]BF₄, conjugate additions a	87
[Rh((R,R)-DiPAMP)COD]BF₄, l-DOPA synthesis	82
Rh(I). for hetero-Heck type reaction a	139
Rh(III) salt, carbonylation of aryltin compounds a	41
[Rh(OH)(cod)]₂, for internal alkynes + silanediols. a	139
Rh(TAN₁₅DPPA)Cl, cyclohexene hydrogenation	176
Catalysts, Ruthenium,
Pt/Ru, Pt/Ru/Ni, nanoparticles. for DMFC a	88
PtRu, fuel Cell electrocatalysts	106. 88. 106. 117. 146, 191
CO tolerance in fuel Cells	106, 122
PtRu/C, fuel Cell electrocatalysts	106. 117. 140. 146. 191
Ru-Sn/Y zeolite, MeOH conversion a	139
methyl acetate formation a	139
Ru/Al₂O₃, CO₂ reforming of propane a	41
Ru/sepiolite, + Mn, Mo, Zr, for CO₂ methanation a	86
RuO₂, RuO₂,IrO₂, TiO₂, to sustain H₂O electrolysis.
in PEMFCs	132
Catalysts, Ruthenium Complexes, with fluoroorganic
groups, solubility in sc-CO2	165
in fluorous phases	165
["Pr₄N][RuO₄] + NMO or O₂. alcohol oxidation a	191
perruthenates/, ruthenates/FibreCat^™, alcohol oxidation	1 24
[(R₂P(CH₂I_nPR₂-K²P)XRu=CHR']. olefin metathesis, a	87
Ru-BINAP, dendritic, asymmetric hydrogenation
of acrylic acids	180
Ru carbenes, ring-closing enyne metathesis a	140
Ru Schiff base, Kharasch addition, CCl₄ + olefins a	87
RCM of diolefins a	87
RuCl₂(PPh₃)₃, fast living radical polymerisation a	140
RuCl₂(xylylbinap)(diamine), allyl alcohol synthesis	82
RuCl₃, chlorination, aromatic compounds, olefins a	42
RuCl₃,3H₂O + trioctylamine, lignin hydrogenation	167
[RuH₂(H₂)₂(PCy₃)₂], arene hydrogenation a	42
Ru(II) BINAP, chiral propanediol production	82
RuO₄, with NaOCl. oxidation of ethers. a	87
[Ru(OAc)₂((S)-BINAP)], (S)-(+)-naproxen synthesis	82
[RuX₂(BINAP)], for ketone hydrogenation	82
[RuX(arene)BINAP]X, for ketone hydrogenation	82
CerOx^™ Process, to treat hazardous organic wastes	18
Chemical Vapour Deposition, Pt, films	106. 189
nanoparticles a	38
precursors for	106, 107, 189
Chemiluminescence, sec Luminescence
Chiral, catalysis, in hydrogenation, oxidation	82
Cisplatin	106. 165. 166
Clusters, Rh-Pt a	38
Coatings ACT^™, Power Coatings^™, for glass industry	181
see also Deposition and Electrodeposition
Cobalt, Al-Pd-Co, U-, V-phase. structures a	38
Pt-Co. jewellery alloy	66
Colloids, Ag. Pd. for Ag:Pd powder a	84
Pt 10.5.	136
Combinatorial Chemistry, in catalysis	24
Composites, ceramic matrix, with Al-Mg-Pd. a	38
Pd-ceramic membrane a	86
see also Nanocomposites
Conferences, 8th Int. Conf. Chem. of the PGMs.
Southampton,	106 81. 165, 166, 167
9th Int. Platinum Symp., Billings, MT, U.S.A., 2002	177
18th Conf. on Catal. of Org. React., Charleston,
SC U.S.A., 2000	23
EuropaCat-V. Limerick, Ireland, 2001	24
EuropaCat-VI, 2003	24
Fuel Cells for Automotive Applications, London, 2002	64
Fuel Cells - Science and Technology 2002.
Amsterdam, 2002	64
The Dynamic Electrode Surface, Berlin, 2002	106
Copper, Pt-Cu, jewellery alloy	66
Coupling Reactions, (arylboronic + carboxylic) acids, a	41
cross-, for C-C C-N bonds	50
homo-, iodoarenes, a	139
organosilanes, as coupling agents	50
Pd catalysts 50,	165
see also Heck Reactions and Suzuki Couplings
Creep, in Ir-based refractory superalloys	74
Crystallisation, Pd₄₀Cu₃₀P_2oNi₁₀ a	136
Pd₄₃Ni₁₀Cu₂₇P₂₀ melts a	38
Cyclisation, allylsilanes, a	41
unsaturated N -chloroamines, to piperidines, a	139
Cycloadditions, 1,3-dipolar a	190, 191
Cyclohexenes, 2-aryl-, from 2-arylcyclohexenols a	139
hydrogenation	176
Decomposition, CH₄ a	189
MeOH a	190
NO, a	86
Dehalogenation, aryl halides a	41
Dehydrogenation, propane a	40
transfer, aromatic alcohols a	40
Dendrimers, as catalysts 167,	180
Os(II), Ru(II) polypyridines, photoproperties, a	85
synthesis	165
Dental, alloys a	88
Deposition, Pd, at C paste electrodes a	85
see also Coatings and Electrodeposition
DHPS^®, for the glass industry	181
Diesel, oxidation catalysts, Pt	27
particulate filters	27
selective catalytic reduction	27
Dihydroxylation, by OsO₄ 24, 82,	191
β-Diketones, Pt(II) with Al(CH₃)₃, for Pt networks	105
Pt(II) β-diketonates, photoreactions with olefins, a	39
Dimerisation, of [M(L-L)₂(eilatin)]²⁺, M = Os, Ru, a	136
2,4-Dinitrotoluene, electron transfer reduction of	94
Ductility, in Ir-based refractory superalloys	74
Electrical Conductivity, in (C₇H₁₃NH)[Pd(dmit)₂]₂, a	39
Electrical Contacts, ohmic, Pd/n^*-GaAs, a	88
Pt, with Si interlayers, on p -type SiC, a	191
Electrochemical Cells, CerOx^™ waste process	18
Electrochemistry, a	84-85,137, 188
book review	15
cathode reactivity of Pd, Pt, in dry DMF	94
destruction of hazardous organic wastes	18
doping, of Pt phthalocyanine microcrystals, a	85
in fuel cells, see Fuel Cells
Electrodeposition, Os, Os alloys, a	189
Pt, fine particles a	39
see also Coatings and Deposition
Electrodeposition and Surface Coatings, a	39, 85, 189
Electrodes, Au, anchoring of Pt(II) complex, a	137
Au-Pt black, for glucose sensor a	86
C paste, Pd deposition and dissolution a	85
conference	106
in fuel cells, see Fuel Cells
Pd, cathode reactivity in dry DMF	94
Pt(III), for CO electrochemical oxidation	106
Pt, cathode reactivity in dry DMF	94
for CO electrooxidation	106
in hydrocarbon sensor a	40
microdisk, in NO sensor a	40
nanoparticles, + nano-honeycomb diamond films, a	84
thin films, for MIM capacitors, a	189
wire, for in vivo biological sensors	72
Pt-plated Ti, in CerOx^™ electrochemical cell	18
Pt-PtO_x thin films, for memory capacitors, a	88
PtRu, for CO electrooxidation	106
Ru(001), electrooxidation	106
RuO₂/C, in supercapacitors, a	88
n -Si, with fine Pt particles, a	39
Ti₂FeRuO₂, Ti_x Fe_y RU_zO_n, in supercapacitors	105
Ti/IrO₂-TaO₅, anode ageing, in H₂SO₄ a	188
Ti/IrO₃,-Sb₂O₅-SnO₂, wastewater electroflotation a	137
Electrodes, (cont.)
Ti/RuO₂, anodes, preparation a	137
Ti/RuO₃Mn_1-3 O₂ anodes, Cl₂ + O₂ evolution a	188
Electroflotation, of wastewater a	137
ElectroIess Plating, Ag-Pd thin films, for membranes, a	86
Pt, on SPE membranes a	40
Emission Control, motor vehicles 27,	190
Erbium, Pd-Er-H. H effects on	169
Etching, Pt, by ICP, using BCl₃/Cl₂ a	140
Ethene, copolymerisation with alkylacrylates a	139
non-alternating copolymerisation with CO a	139
Ethers, cyclic enol, by ring-closing enyne metathesis, a	140
oxidation a	87
EthyI Pyruvate, hydrogenation a	86
Europe, EU adopted emission control, legislation	27
Eutectic Reactions, Pd-rare earths	108
Films, Co-Pt, sputtered on (001)-oriented Si wafer, a	140
Ir, by MOCVD a	39
Pt, by CVD, for memory capacitors	107
see also Thin Films
‘Final Analysis’	2, 48, 92, 144
Fracture, in Ir-based refractory superalloys	74
Fuel Cells a	42,88, 140, 191
automotive use	24, 64
catalysts, Pt/C, for MeOH oxidation a	42
for O₂ reduction reaction, in presence of Cl^-, a	42
PtRu, CO tolerance	106, 122
conferences	24, 64
DMFC, anodes	14, 146
cathodes	146
MEAs	146
miniaturisation	161
portable applications	161
electrocatalysts, Pt-Ru/C, by sulfito method, a	191
electrodes, Pt-Ru, nanostructured, CO oxidation, a	191
Fuel Cell Catalysts Brochure, Alfa Aesar	14
HiSPEC^™ fuel cell catalysts	14, 146
low temperature, catalysis	3, 64, 117. 146
membrane electrode assemblies	3, 117, 140. 146
nanoparticles	3, 88, 117, 146
PEFC, Pt-Ru/C electrocatalysts, XANES, a	140
MEAs a	140
PEMFC, air bleed technique	129
anodes	117
cathodes	3, 88
CO₂, CO, poisoning	117
comparison with DMFC	146
electrocatalysts, anode, PtMo, PtRu	117
cathode, Os_x (CO)_n /Vulcan C, a	88
Pt, Pt alloys	3
MEAs	3, 117
water electrolysis, effects	132
SOFC, LaSrCrRuO, anode material, a	191
see also Catalysts, Iridium, Platinum, Ruthenium
Gases, high purity H₂, O₂	144
Geology, book	17
conference	177
Glass, production technology	181
Glucose, oxidation	106, 138
sensors a	40. 86
Halogenation, of aromatic compounds, olefins a	42
Heck Reactions 50,	139. 165
High Temperature, Ir-based refractory superalloys	74
High Throughput Screening Techniques 24	, 87. 190
Hydroalkenylation, alkynes, with silanediols, a	139
Hydroarylation, alkynes, with silanediols a	139
Hydrocarbons, emission control in EU	27
oxidation a	86
sensor, a	40
Hydrocracking, n -decane, a	189
Hydrodechlorination, chlorinated olefins, a	138
Hydrofonmylation-Hydrogenation, l-octene a	41
Hydrogen,absorption. Pd	106, 169, 188
book review	37
damage of capacitors a	42
electrooxidation	117
interaction with Pd, Pd alloys	37, 169
sensors a	189
separation, using Pd-Ag membrane reactor a	189
using Pd-ceramic membranes a	86
solid solutions, in Pd	169
structural changes in Pd, Pd-Er, Pd-W	169
treatment of materials	37
Hydrogenation, acid chlorides	73
α-(acylamino)acrylic acids, esters	82
alkynes	73
arenes. a	42. 138
asymmetric, acrylic acids	180
book review	73
carboxylic acids, α.β-, β.γ-unsaturated	82
chiral-catalysed	82
cyclohexene	176
ethyl pyruvate, a	86
ketones	82, 138
lignin	167
in liquid phase batch reactors	48,92
1 -octene	176
phenols a	86, 190
polystyrenes a	86
Hydrolysis, cis-, trans-Pt(Ypy)₂(NO₃)₂, a	188
Hydrosilylation, alkynes. a	138
Hydrotalcitcs, catalyst support	26
Insulators, single-molecule, trans -Pt(II) complex a	137
Ion Source, high temperature, of Pd a	136
Ion Transfer, IrCI⁶, across liquid interface a	137
Ionic Liquids, solvents a	191
Iridium, films, by MOCVD a	39
Ir(III), surface, for electrolyte hydration	106
thin films, by DC sputtering a	42
Iridium Alloys, (Ir, Rh)₇₅,Nb₁₅Ni₁₀, specific strength	74
Ir-Nb, Ir-Zr, Ir-Nb-Ni, Ir-Nb-Ni-Al	74
Pt-Ir, jewellery alloy	66
superalloys, refractory: creep, ductility, fracture	74
Iridium Complexes, IrCl₆¹, ion transfer a	137
[Ir(DPF)₃], electrophosphorescence a	137
luminescence	137, 165
Iridium Compounds, electrodes a	137.188
IrO₂, thin films, by DC sputtering a	42
IrO₂/PLZT/Pt, capacitors a	42
Isomerisation, n -decane,	189
lsoxazolidines, synthesis a	190
Jewellery, Pt, Pt alloys, welding by laser	66
Johnson Matthey, ACT^™, Power Coatings^™	181
catalysis for fuel cells, research	106. 64, 117, 146
FibreCat^™	24, 190
PGM Conference competition winners	166, 167
“Platinum 2002”	116
Rhodium Bicentenary Competition, winner	2
Ketones, synthesis	106, 41, 191
hydrogenation	82, 138
Kumada-Tamao-Corriu Couplings	50
Lasers, to drill cavities in Pt wire electrodes	72
welding of Pt jewellery	66
Lignin, hydrogenation	167
Liquid Crystals, Rh carboxylate polymers a	188
Luminescence, electrochemi-, Ir(ppy)₃, a	137
Ru(bpy)₃^2*. a	39. 137
Ir terpyridyls	165
Os(II) polypridines, dendrimers a	85
photo-, Ir(ppy)₃ a	137
Pt(II) quaterpyridine a	39
Ru(bpy)₃²⁺. a	137
Pt octaethylporphyrin a	137
Luminescence (cont.)
Ru terpyridyls	165
Ru(II) polypridines, dendrimers. a	85
Macrocycles, Pd(lI), Pt(II) a	39
Magnesium, Al-Mg-Pd, melt oxidation a	38
Magnetism, in CoCrPt perpendicular media a	191
in CoCrPtB layers, on TiZr underlayers. a	140
in SrCuRhO, SrNiRhO a	136
Mass Spectrometry, differential electrochemical a	42
laser-activated membrane introduction, LAMIMS, a	190
Medical Uses a	88
PGM Conference	165. 166
Melting Points, Pt, Pt alloys	66. 181
MEAs, in fuel cells	106, 117. 140, 146
Membranes, Pd-Ag, for CH₄ decomposition a	189
Pd-ceramic a	86
SPE, with Pt particles a	40
Memory, capacitors for	88, 107
L.-Menthol. commercial synthesis	82
Metathesis, of olefins. RCM. ROMP a	87
ring-closing enyne. a	140
Methanation, CO₂ a	86
Methane, activation a	87
decomposition a	189
partial oxidation	24
steam reforming a	191
Microwaves, in phenylation of aroryl chlorides a	87
in synthesis of [RuCp(dppm)SR]. a	136
MOCVD, Ir films a	39
Myrcene, oxidation a	190
Nanocomposites, Pd:Ag, physical properties a	84
Pt-Ru/GCNF, for DMFC anodes	14
RuO₂/C, supercapacitors a	88
see also Composites
Nanocrystalline Powders, Pd:Ag. a	84
Ti,Fe,Ru₂O₄, in supercapacitors	105
Nanocrystals, Pt-Ru, on GCNF	14
Nanoparticles, Pd, on Al₂O₃NiAl, model catalyst a	190
embedded in ZrO₂. H₂ absorption a	188
in H₂o-in-oil microemulsions a	38
stabilised by polyfluorinated chains a	84
Pt. 3D networks. Al-organic-stabilised	105
on γ-Al₂O₃, catalysis	115
on C nanospheres, a	38
with nano diamond films, as electrodes a	84
preparation a	136
in Pt, Pt alloys, fuel cell electrocatalysts	106, 88, ! 17, 146
Pt, Pt/Ru, surface diffusion of chemisorbed CO	106
Nanostructures, PGM Conference	165
Pt-Ru electrodes, for fuel cells, 0	191
Nanowires, Pt. a	136
(S)-(+)-Naproxen, synthesis	82
Nitrogen Oxides, NO, decomposition a	86
sensor a	40
NOx, adsorbers	27
DeNOx, catalysts	27
reduction	24, 41
selective catalytic reduction of diesel emissions	27
Nitroxides, reactions with Rh porphyrin alkyls a	188
NMR, multi-, aqueous products of Pt(Ypy)₂(NO₃)₂, a	188
Nobel Prize, Chemistry, chiral-catalysed reactions.
pgm catalysts	82
Noril'sk, PGE geology, conference	177
l-Octene, reactions	41, 176
Ohmic Contacts, see Electrical Contacts
OLEDs, [Ir(DPF)₃] in PVK/PBD a	137
Olefins, dihydroxylation. asymmetric a	191
as H acceptors a	40
Kharasch addition, of CCl₄, a	87
metathesis: RCM, ROMP a	87
with Pt(II) β-diketonates, photoreactions a	39
Oligomerisation, phenylacetylene. a	190
Osmium, electrodeposition u	189
Osmium Alloys, electrodeposition, a	189
Osmium Complexes, in glucose sensors, a	40
ground and excited states	106
luminescence, a	85
Os₃(CO)₁₂, pyrolysis, a	88
Os,bipy-modified DNA, voltammetric analysis a	138
[Os(L-L)₂(eilatin)]²⁺, dimerisation a	136
Osmium Compounds, osma-aromatics, osmabenzenes	106
OsO₄, in DNA voltammetric analysis, a	138
Os(VIII), oxidation state	165
Oxidation, alcohols	106, 26, 42, 84, 191
alkenes, a	39
chiral-catalysed	82
electro-,CO	106,106,191
formaldehyde, formic acid	106
H₂	117
MeOH	106, 106, 146
ethers a	87
glucose	106, 138
hydrocarbons a	86
liquid organic waste	18
melt, Al-Mg-Pd a	38
MeOH a	42, 84
myrcene a	190
NH₃	24
partial, CH₄	24
[Pt¹¹Cl₂(H₂enda)] a	84
thiophenea	138
VOCs, a	138, 189
wet, phenol a	138
Oxygen, reaction with CO, a	40
reduction reaction, ORR, for Os_x(CO)_n/Vulcan C, a	106
on Pt/C, for fuel cells a	42
sensors a	137
Palladium, AlMgPd ceramic composites, formation, a	38
cathodic reactivity, in superdry conditions	94
circuit patterns, on polyimide a	137
interaction with H₂	37, 169
ion source a	136
nanoparticles, a	38, 84, 188, 190
Pd in poly(para -phenylene), phosphorescence	187
Pd:Ag, nanocomposite a	84
Pd-H, structural changes	169
Pd-rare earth systems, phase diagrams	108
Pd/n₊-GaAs ohmic contacts, + Ge, Sn layers a	88
[Pd_m^-, M⁺, MX], [Pd,”, Μ*,(MX)], electrogenerated	106
solid solutions of H	169
thin films a	85, 189
Palladium Alloys, Ag-Pd-Gd-Ru a	38
Al-Mg-Pd, melt oxidaton a	38
Al-Pd-Co, U-, V-phase, structures a	38
dental, Ag-Au-Pd-Cu a	88
interaction with H₂	37, 169
membranes a	86, 189
Pc₁₀Cu₃₀P₂₀Ni₁₀, a	136
Pd₁₃Ni₁₀Cu₂₇P₂₀ melts, crystallisation, a	38
Pd-Er-H, Pd-W-H, structural changes	169
Pd-Pt, interaction with H₂	37
Pd-rare earths	108
Pt-Pd, jewellery alloy	66
Ti(PdNi), shape memory a	188
Palladium Complexes, (BQA)PdCl, preparation a	38
(C₇H₁₃NH)₂[Pd(dmit)₂], air-oxidation of a	39
(C₇H₁₃NH)[Pd(dmith)₂], electrical conductivity, a	39
Pd(II) N₂S₂ macrocycles, synthesis a	39
Pd(II) with pincer-like amido ligand a	38
in poly(para -phenylene), synthesis	187
[Pd¹¹Cl_n, formation, at C paste electrode a	85
Palladium Compounds, Pd(NH₃)₄Cl₂, reduction, a	38
Na₂(Pd₂Cl₆), reduction a	84
Patents 43-7,89-91,141-143,	192-194
pH, sensors a	189
Phase Diagrams, Ag-Pd-Gd-Ru a	38
Ir-Nb-Ni, Ir-Nb-Ni-Al	74
Pd-rare earth systems	108
Phase Transformation Kinetics, Pd-H, Pd-Er-H,
Pd-W-H	169
Phenols, hydrogenation a	86, 190
wet oxidation, a	138
Phenylation, aroyl chlorides, a	87
Phosphorescence, from Ir-based OLEDs a	137
from Pd-poly(para -phenylene)	187
Photocatalysis, in Pt(II) quaterpyridine complex a	39
Photoconversion, a	106,85, 137, 189
PGM Conference	165
Photoluminescence, see Luminescence
Photoproperties, Pt-phenylene ethynylene
monomers, polymers, a	189
Ru(phen)₂(3-carbethoxy,4-hydroxy-phen)²⁺(PF₆)₂, a	189
Ru polypyridines, biomimetic assemblies, a	85
rac -[Ru(bpy)₂(PhP(OMe)₂(Cl)]Cl,a	85
Ru(II) bipyridyls. dendrimeric oligomers	165
Photoreactions, Pd(II) to Pd, by UV irradiation a	137
[(PEt₃),HPt(μ-H₂)Pt(PEt₃)₂][BPh₄], Pt-Pt homolysis	;,a 85
[(PEt₃),HPt(μ-H₂)PtH(PEt₃)₂][BPh₄], Pt homolysis, a	is,a 85
[(PEt₃₂PtH₂], [(PEt₃)₂PtH(S)][BPh₄], formation, a	85
Pt(II) β-diketonates, with olefins, a	39
Rh/Tio₂, CO₂ reduction, by H₂ a	39
Photosynthesis, Ru polypyridines, as models, a	85
Plperidines, from unsaturated N -chloroamines, a	139
“Platinum 106”	116
Platinum, ACT^™, Power Coatings^™	181
addition to, (NdEuGd)BaCuO, effects, a	42
capacitors	106, 88, 107, 189
cathodic reactivity, in superdry conditions	94
colloids	106, 136
drilling, by laser	72
electrodes, see Electrodes
etching, using BCl₃/Cl₂ gas plasma a	140
films	107
in glass making	181
laser welding, jewellery	66
melting point	66, 181
nanoparticles	106, 84, 88, 105, 106, 115, 136
nanowires, a	136
ohmic contacts, Pt/Si interlayers/p -type SiC a	191
in O sensors, a	137
particles, electroless plated, on SPE membranes, a	40
for solar cell electrodes a	39
[Pt₂, Na₊, Nal], reduction of 2,4-dinitrotoluene	94
Pt(III), surface, for electrolyte hydration	106
[Pt_n, M₊, MX], [Pt_x, M⁺, (MX)], electrogenerated	94
single crystals, for CO electrooxidation a	84
thermal diffusivity	66
thin films, a	106,88,189
welding, laser	66
Platinum Alloys, CoCrPt film, perpendicular media.
magnetic properties a	191
CoCrPtB perpendicular media on TiZr,
magnetic properties a	140
electrodes, see Electrodes and Fuel Cells
films a	140
in glass making	181
jewellery, Pt alloys	66
laser welding, jewellery	66
melting points	66, 181
nanoparticles	88, 106
Pt-Pd, interaction with H₂	37
Pt-Rh, coatings, ACT^™	181
thermal diffusivities	66
welding, laser	66
Platinum Complexes, trans -Pt(II), insulator, a	137
(BQA)PtCl, preparation a	38
(η-C₂H₄)(Cl)Pt(μ-Cl)₂Ru(Cl)(η₃:η₃-2,7-dimethyl-
octadienyl), nanocrystal precursor	14
(COD)PtCI₂ + dimethylphenyl(quinolinyl)amine, a	38
luminescence, a	39, 137
Platinum Complexes, (cont.)
photoproperties, a	189
photoreactions, a	39. 85
precursors for CVD, a	38, 107,189
[Pt,Cl₂){N (H)C(Bu')O}4], Pt(III)-Pt(III) distance a	136
[Pt₂I₂{N (H)C(Bu')0}4], a	136
Pt octaethylporphyrin, in O sensor a	137
Pt phthalocyanine, electrochemical doping of a	85
[Pt^lvCl₂(enda)], by oxidation of [Pt₁₁Cl₂(H₂enda)] a	84
[Pt(Cn)(H₂O)₂]²*, reaction with DL-penicillamine a	84
Pt(II) acetylacetonate, reaction with Al(CHi)₂.	105
Pt(U) N₂S₂ macrocycles, synthesis a	39
Pt(II) with pincer-like amido ligand a	38
Pt(III) ‘lantern-shaped’ a	136
PtR₂(COd), ligand displacement reactions a	136
PtR₂L₁, H2O-soluble diorgano-, synthesis a	136
cis-. rran.s-Pt(Ypyh(NOiK aquation, hydrolysis a	188
[RhbPMCO)i,,(dppm).,], [Rh»Pt₂(CO)₂,(dppm)₂] a	38
Platinum Compounds,antitumouragents	106, 165, 166
electrodes a	88
K;[Pt(C2O4)2], K₂PtCl₄. K₂PtCU. reduction a	136
thin films, α	88
Platinum Group Elements, geology book	17
geology conference	177
Pollution Control, organic wastes, destruction	18
wastewater, electroflotation a	137
see also Emission Control
Polymerisation, co- a	139
fast living radical a	140
ofphenylacetylene.i/	106,190
ROMP a	87
Polymers, coordination, Rh carboxylates a	188
matrix, for Pt complex thin film O sensor a	137
polyimide, with Pd circuit patterns a	137
poly(para-phenylene) + Pd, phosphorescence	187
polystyrenes, hydrogenation a	86
Pt-phenylene ethynylenes, photoproperties a	189
PVKyPBD, with [Ir(DPF),], for OLEDs. a	137
Power Coatings. ^™, for the glass industry	181
Propane, CO₂ reforming of. a	41
dehydrogenation a	40
Propene, for reduction of NOx	24,41
Pyridines, chloro-, alkoxycarbonylation a	87
Rare Earths, Pd-rare earths, eutectic phases	108
solid solublities in Pd₁ strengthening effects	108
RCM a	87. 140
Reactors, fixed bed catalyst, design aspects	144
hydrogen-permeating membrane a	189
for liquid phase batch hydrogenations	48, 92
Reduction, CO₂, by H₂ a	39
electron transfer, of 2,4-dinitrotoluene	94
Ο,,α	42
Reforming a	41, 191
Rhodium, Rhodium Bicentenary Competition	2
Rhodium Alloys, (Ir, Rh)₇₅Nb₁₅Ni₁₀. specific strength	74
Pt-Rh, coatings, ACT^™	181
jewellery alloy	66
Rhodium Complexes, [Rh₆Pt₄(CO)₁₆(dppm)₃],
[Rh»Pt₂(CO)₂,(dppm)₂] a	38
Rh porphyrin alkyls, reactions with nitroxides a	188
tetra(alkoxybenzoato)dirhodium(II), liquid crystals. a	188
pyrazine adducts, liquid crystals a	188
TpmsRh(LL) (LL = (CO)₂, cod, nbd), Rh(I) chemistry, a	84
Rhodium Compounds, Sr₁CuRhO₆, SriNiRhO, a	136
ROMP a	87
Rosenmund Reduction, acid chlorides	73
effect of H₂O	48
Russia, PGE geology, conference	177
Ruthenium, electrodes	106
Ru-doped InP, resistivities a	42
Ru(OOl), surface, for electrolyte hydration	106
Ruthenium Alloys, Ag-Pd-Gd-Ru a	38
electrodes, see Electrodes and Fuel Cells
nanoparticles	88. 106
Ruthenium Alloys {cont.)
Pt-Ru, jewellery alloy	66
Ta/Ru buffer layer, for CoCrPt perpendicular media a	191
Ruthenium Complexes, bis(rf-2.4-dimcthyl-
pentadienyl)Ru(II), for vapour-phase epitaxy a	42
cancerdrugs	106,166
(n-C₂H₄)(Cl)Pt^-Cl)₂Ru(CI)(^':n‘-2,7-dimethyl-
octadienyl), nanocrystal precursor	14
luminescence	106. 85, 137, 165
(2-MeImHHRuClj(2-McIm);],
(2-MeImH)₂[RuCl₅(2-MeIm)l, synthesis a	84
photoproperties	106. 165, 189
[RuCp(dppm)SR], microwave-assisted synthesis a	136
[RuH(arene)(Binap)]CFiSO.i, piano-stool inverted a	188
[Ru(L-L)₂(eilatin)]^:+, dimerisation a	136
Ruthenium Compounds,electrodes	106, 105, 137. 188
LaSrCrRuO, SOFC anode material a	191
RuO₂ powders, from RuCl₁ thermal decomposition a	137
Selective Catalytic Reduction, + diesel particulate filter	27
NOx	27
Sensors, glucose, a	40. 86
H₂ a	189
hydrocarbons a	40
in vivo biological	72
NO a	40
0^,o	137
pH,fl	189
Shape Memory Effect, in Ti(PdNi) u	188
Silanes	106. 50, 138, 139. 140
Single Crystals, Pt. CO electrooxidation u	84
Sol-Gel, Pt-doped SnO₂ thin films a	85
RuO₂, RuO₂Hl anodes a	137
Solar Cells, with Pt particles on /i-Si electrodes a	39
Sonogashira Couplings, of terminal alkynes	50
South Africa, PGE geology, conference	177
Sputtering, DC films. Co-Pt a	140
thin films, Ir, IrO₂. a	42
reactive r.f. magnetron, thin films. Pt-PtO, a	88
thin films. Pd-Ag. for Pd-ceramic membranes a	86
Stille Couplings, aryl halides + organostannanes	50
Sulfuric Acid, Ti/Ir0₂-Ta0₅ anodes, degradation a	188
Superalloys, Ir-based refractory	74
Supercapacitors, Ru0₂/C. nanoconiposite. a	88
Ti₂FeRuO₂. Ti,Fe,RuO,,. nanocrystalline	105
Superconductors, Pt + CeO^ additions 0	42
Suzuki Couplings, FibreCat^™. Pd/C. a	190
Pd-polymer-bound phosphine. a	191
Suzuki-Miyaura Couplings	50
Tetraalkylammonium Salts, effects on Pd. Pt cathodes.
in superdry conditions	94
Tetralins, amino-, synthesis a	191
Thermal Diffusivities, Pt, Pt alloys	66
Thin Films, Ir, IKX by DC sputtering a	42
Ni/Pd, XRD a	85
Pd. circuit patterns on polyimide a	137
Pd, for poly-Si wires, as H₂ sensors a	189
Pd-Ag. for ceramic composite membranes a	86
Pt, by chemical vapour deposition a	189
Pt octaethylporphyrin. for O sensors a	137
Pt-doped SnO₂. sol-gel preparation a	85
Pt-PtO,, for memory capacitor electrodes a	88
Ti(PdNi), shape memory behaviour. 0	188
see also Films
Thiopenes, oxidation a	138
Three-Way Catalysts	106. 40
Tungsten, Pd-W-H. H effects on	169
Pt-W. jewellery alloy	66
VOCs,oxidation.ii	106, 189
VoItammetry, (DNA-Os,bipy). microanalysis a	138
Water, waste, electrode system for electrofiotation a	137
Welding, laser, of Pt jewellery	66

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