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Platinum Metals Rev., 2002, 46, (4), 199

Subject Index TO Volume 46

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Acetates, methyl, from MeOH, a 139
Acetylenes, phenyl-, oligomerisation, a 190
polymerisation, a 140, 190
Acid Chlorides, hydrogenation 73
Acrylic Acids, asymmetric hydrogenation 180
ACT, Pt, Pt-Rh coatings, for the glass industry 181
Activation, CH4, a 87
Alcohols, allylic, arylation, a 41
C-C bond formation, with enoxysilane, a 140
aromatic, transfer dehydrogenation, a 40
2-arylcyelohexenols, to 2-arylcyclohexenes, a 139
methyl, conversion, to methyl acetate, a 139
decomposition, a 190
electrooxidation 106
DMFCs 88, 146
oxidation, a 42, 84
oxidation, a 42, 84, 191
aerobic 26
selective 24
Aldehydes, from acid chlorides 73
from alcohols 26, 191
Alfa Aesar, Fuel Cell Catalysts Brochure 14
Alkali metals, iodides, effects on Pd, Pt cathodes,
in superdry conditions 94
Alkenes, dihydroxylation 24
from alkynes 73
oxidation, a 39
Alkoxycarbonylation, chloropyridines, a 87
Alkylacrylates, copolymerisation with ethene, a 139
Alkynes, hydroalkenylation, a 139
hydroarylation, a 139
hydrogenation 73
hydrosilylation, a 138
Alloys, dental, a 88
jewellery 66
Aluminium, Al-Mg-Pd, melt oxidation, a 38
Al-Pd-Co, U-, V-phase, structures, a 38
Amination, aryl halides with an ammonia analogue 50
Hartwig-Buchwald 50
Amines, in fast living radical polymerisation, a 140
Amino Acids, L-DOPA synthesis 82
Ammonia, oxidation, over Pt 24
Aquation, cis -, trans-Pt(Ypy)2(NO3)2, a 188
Arenecarboxylic Acids, synthesis, a 41
Arenes, hydrogenation, a 42, 138
iodo-. homocoupling, a 139
Aroyl Halides, microwave-assisted phenylation, a 87
Aryl Halides, arylation, of allylic alcohols, a 41
cross-coupling reactions 50
dehalogenation, a 41
Heck reactions 50, 139
Suzuki couplings, a 190, 191
Arylation, allylic alcohols, a 41
α-amino acid esters, a 87
N -AryIation, aryl indoles 50
Arylboronic Acids, coupling reactions 41, 50
autocatalysts, technologies adopted by EU 27
Biomimetic Assemblies, in photosynthesis, a 85
Book Reviews, “Catalysis of Organic Reactions” 23
Catalysts & Catalysed Reactions 65
“Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis” 73
“Modern Electrochemistry” 15
“Progress in Hydrogen Treatment of Materials” 37
Buchwald-Hartwig Couplings 50
Bushveld Complex, PGE geology, conference 177
Cancer, drugs 88, 165, 166
Capacitors, container, with Pt films, for memory Cells 107
IrO2/PLZTVPt. Pt/PLZTm, Η-damage, o 42
Capacitors, (cont.)
memory, Pt-PtOx thin film electrodes, a 88
MIM, Pt thin film electrodes, a 189
Pt/SrBi2.2Ta2O9/Pt, annealing effects, a 88
Carbenes, Pd, N -heterocyclic nucleophilic 50
Ru, a 87, 140
Carbon Oxides, CO2, methanation, a 86
poisoning, in PEMFC 122
reforming of propane, a 41
supercritical, solvent 139, 165, 176
CO, chemisorbed, on Pt, PtRu nanoparticles 106
copolymerisation, with ethene. a 139
effects in fuel Cells 106, 117. 146
electrooxidation 106. 106, 191
poisoning, in PEMFC 118
reaction with O2, a 40
Carbonylation, with aryltin compounds, a 41
Carboxylic Acids, arene-, synthesis, a 41
in ketone synthesis, a 41
α,β-, β,γ-unsaturated, hydrogenation 82

Catalysis, book reviews
106, 65, 73

conferences
106, 24, 165, 167

heterogeneous, a
106–4l, 86, 138-139. 189-190

homogeneous, a
106–42, 87, 139-140, 190-191
in ionic liquids, a 191

low temperature fuel Cells
106, 64, 117, 146

in sc-CO2
106,165,176
Catalysts, dendrimers 167, 180
in fat hardening 23
fixed bed reactors, design aspects 144
high purity gas production 144
homogeneous, supported 23
pgm/C, paste, powder, preferences 48

recycling
106, 41, 176, 180, 190, 191
three-way, see Three-Way Catalysts
Catalysts, Iridium, Ir black, NOx reduction 24, 41
RuO2/IrO2, to sustain H2O electrolysis, in PEMFCs 132
Catalysts, Iridium Complexes, [(cod)IrCl]2, a 140
[Ir(cod)(PPh3)2]X, for C–C: bond formation, a 140
Ir(I), for hetero-Heck type reaction, a 139

Catalysts, Osmium, Osx(CO)x/Vulcan C. in PEMFCs, a
106
Catalysts, Osmium Complexes,
OsO4 + cinchona alkaloid, dihydroxylation 82, 191
OsO4/FibreCat, dihydroxylation 24
Catalysts, Palladium, K5PPdW11O39·12H2O/γ-Al2O3,/C, hydrogenation of arenes, a 138
LaFeCoPdO, for automotive emissions control, a 190
Lindlar 73

Pd nanoparticles/Al2O3/NiAl, MeOH decomposition, a
106
Pd-Bi/C, glucose selective oxidation, a 138
Pd-perovskite, automotive emissions control, a 190
Pd-Pt/AIMCM-41, n -decane isomerisation, a 189
Pd/Al2O3, aromatic alcohol dehydrogenation, a 40
hydrodechlorination of chlorinated olefins, a 138
Pd/Al2O3 + Mg mesh, phenol hydrogenation, a 190
Pad/y-Al2O3, 4-chloro-2-nitrophenol hydrogenation, a 86
Pd/AlMCM-41, n -decane isomerisation, a 189
Pad/BaSO4, hydrogenation of acid chlorides 73
selective poisoning, with thioquinanthrene 73
Pd/bulk MgO single crystal, particle morphology 24
Pd/C, paste, commercial 48. 92
liquid phase batch hydrogenation 92
powder, commercial 48
+ soluble Bi, glucose selective oxidation, a 138
Suzuki coupling, a 190
Pd/CeO2/Al2O3, thiophene, VOC, oxidation, a 138
Pd/Fe, Pd/Mg, phenol hydrogenation, a 190
Pd/Pb-doped CaCO3, hydrogenation of alkynes 73
modified with pyridine, quinoline 73
Pd/support, aromatic alcohol dehydrogenation, a 40
PdCl2-CuCl2. myrcene oxidation, a 190
transfer of oxide ions, to a catalyst substrate 165
Catalysts, Palladium Complexes, π-allyl-Pd,
asymmetric synthesis of: (-)-haemanthidine,
(-)-mesembrane, (-)-mesembrine,
(+)-crinamine, (+)-pretazettine a 139
(n3-allyl)Pd intermediate, allylsilanes cyclisation a 41
for cross-coupling reactions 50. 165
(dippf)PdCl2, (dippf)PdCl(CH3), polymerisation a 190
(dppe)PdCl2, (dppe)PdCl(CH3), oligomerisation a 190
(dppf)PdCl2, (dppf)PdCl(CH3), polymerisation a 190
FibreCat, Suzuki coupling a 190
N -heterocyclic nucleophilic carbenes, for C–C C–N 50
Pd, for poly(para -phenylene) polymer, synthesis 187
Pd(O) tricyclohexylphosphine, coupling reaction a 41
Pd-phosphino-oxazoline allyl, ‘meta-dialkyl effect' 167
Pd-polymer-bound phosphine, Suzuki coupling a 191
PdCl2(Ph3P3)2/dppb, alkoxycarbonylation a 87
Pd(dba)2 + phosphinobenzene sulfonic acid a 139
Pd(dba)2/(trimethylphenyl)dihydroimidazolium salt a 41
Pd2(dba)3/phosphine, α-amino acid ester arylation a 87
Pd(II) acetate-pyridine/hydrotaicite, aerobic oxidation 26
Pd(II) salt, carbonylation of aryltin compounds a 41
Pd(OAc)2, arylation of allylic alcohols a 41
Pd(OAc)2. for cross-coupling reactions 50
Pd(OAc)2 + phosphinobenzene sulfonic acid a 139
Pd(OAc)2 + PPh3, synthesis of isoxazolidines a 190
Pd(OAc)2 + P(o -tolyl)3, for coupling reactions a 139
Pd(OAc)2/dppf, alkoxycarbonylation a 87
Pd(OCOCF3)3/P(2-furyl)3, iodoarene homocoupling a 139
Pd(PPh3)2Cl2, microwave promoted phenylation a 87
Pd(PPh3)4, unsaturated N -chloroamine cyclisation. a 139
Catalysts, Platinum, CH4 partial oxidation 24
electrocatalysts, anodes, for fuel Cells 117, 146
cathodes, for fuel Cells 3, 146
nanoparticles. Pt, for DMFC a 88
Pt/γ-Al2O3, preparation 115
NH3 oxidation 24
Pd-Pt/AIMCM-41, n -decane isomerisation. a 189
Pt black, electrocatalysts, cathodes, for DMFCs 146
Pt-Rh/Al2O3, TWC, CO + O2 reaction a 40
Pt-Sn/Al2O3, for cyclohexane dehydrogenation.
n -octane reforming, n -pentane isomerisation a 40
Pt/Al2O3, Ce addition, phenol wet oxidation a 138
for cyclohexane dehydrogenation. n -octane
reforming, n -pentane isomerisation a 40
hydrocarbon oxidation a 86
impregnated using H2PtCl6, Pt(NH3)4Cl2, a 138
+ Rh/Al2O3, hydrocarbon oxidation a 86
Pt/Al2O3/Al monoliths. VOC oxidation a 189
Pt/AIMCM-4l, n -decane isomerisation a 189
Pt/C, 4-chloro-2-nitrophenol hydrogenation. a 86
hydrosilylation of alkynes. a 138
MeOH oxidation a 42
NO decomposition a 86
O2 reduction reaction a 42
Pt/CeO2-ZrO2, in high throughput screening a 190
Pt/graphite, cinchona-modified, for hydrogenation. a 86
Pt/Ni, Pt/Ru, Pt/Ru/Ni, nanoparticles, for DMFC a 88
Pt/SPE membrane, preparation a 40
Pt/wide-pore SiO2, polystyrene hydrogenation. a 86
PtCr, PtFe, PtMn, PtNi, PtTi, PtZr, electrocatalysts.
cathodes, for PEMFCs 3
PtMo. electrocatalysts, anodes, for PEMFCs 117
PtRu, fuel Cell electrocatalysts 14, 88, 106, 117, 146, 191
CO tolerance in fuel Cells 106, 122
PtRu/C, fuel Cell electrocatalysts 14, 117, 140. 146, 191
Pt,Sn/Mg(Al)O, propane dehydrogenation a 40
Catalysts, Platinum Complexes, Pt(bpym)Cl2,
Pt(NH3)Cl2, for CH4 activation a 87
Catalysts, Rhodium, Pt-Rh/Al2O3, TWC, CO + O2 a 40
Rh aluminosilicate, laminar, zeolitic structures a 138
anchoring [Rh(Me2CO),(2,5-norbornadiene)|CI04 a 138
Rh/Al2O3, film, model catalyst 24
hydrocarbon oxidation a 86
+ Pt/Al2O3, hydrocarbon oxidation a 86
Rh/TiO2, with propene, NOx reduction 24
Catalysts, Rhodium Complexes, alkenyl-Rh. aryl-Rh. a 87
with fluoroorganic groups, solubility in Sc-CO2 165
in fluorous phases 165
Rh2(OAc)2, for 1,3-dipolar cycloaddition. a 191
Rh-polymer sc-CO2 soluble 176
[Rh(A)CO]*/SiO2. hydroformylation-hydrogenation a 41
[Rh-(-)-BINAP(COD)]ClO4, in L-menthol process 82
[Rh(COd)(MeCN)2]BF4, conjugate additions a 87
[Rh((R,R)-DiPAMP)COD]BF4, l-DOPA synthesis 82
Rh(I). for hetero-Heck type reaction a 139
Rh(III) salt, carbonylation of aryltin compounds a 41
[Rh(OH)(cod)]2, for internal alkynes + silanediols. a 139
Rh(TAN15DPPA)Cl, cyclohexene hydrogenation 176
Catalysts, Ruthenium,
Pt/Ru, Pt/Ru/Ni, nanoparticles. for DMFC a 88

PtRu, fuel Cell electrocatalysts
106. 88. 106. 117. 146, 191

CO tolerance in fuel Cells
106, 122

PtRu/C, fuel Cell electrocatalysts
106. 117. 140. 146. 191
Ru-Sn/Y zeolite, MeOH conversion a 139
methyl acetate formation a 139
Ru/Al2O3, CO2 reforming of propane a 41
Ru/sepiolite, + Mn, Mo, Zr, for CO2 methanation a 86
RuO2, RuO2,IrO2, TiO2, to sustain H2O electrolysis.
in PEMFCs 132
Catalysts, Ruthenium Complexes, with fluoroorganic
groups, solubility in sc-CO2 165
in fluorous phases 165
["Pr4N][RuO4] + NMO or O2. alcohol oxidation a 191
perruthenates/, ruthenates/FibreCat, alcohol oxidation 1 24
[(R2P(CH2InPR2-K2P)XRu=CHR']. olefin metathesis, a 87
Ru-BINAP, dendritic, asymmetric hydrogenation
of acrylic acids 180
Ru carbenes, ring-closing enyne metathesis a 140
Ru Schiff base, Kharasch addition, CCl4 + olefins a 87
RCM of diolefins a 87
RuCl2(PPh3)3, fast living radical polymerisation a 140
RuCl2(xylylbinap)(diamine), allyl alcohol synthesis 82
RuCl3, chlorination, aromatic compounds, olefins a 42
RuCl3,3H2O + trioctylamine, lignin hydrogenation 167
[RuH2(H2)2(PCy3)2], arene hydrogenation a 42
Ru(II) BINAP, chiral propanediol production 82
RuO4, with NaOCl. oxidation of ethers. a 87
[Ru(OAc)2((S)-BINAP)], (S)-(+)-naproxen synthesis 82
[RuX2(BINAP)], for ketone hydrogenation 82
[RuX(arene)BINAP]X, for ketone hydrogenation 82
CerOx Process, to treat hazardous organic wastes 18

Chemical Vapour Deposition, Pt, films
106. 189
nanoparticles a 38

precursors for
106, 107, 189
Chemiluminescence, sec Luminescence
Chiral, catalysis, in hydrogenation, oxidation 82

Cisplatin
106. 165. 166
Clusters, Rh-Pt a 38
Coatings ACT, Power Coatings, for glass industry 181
see also Deposition and Electrodeposition
Cobalt, Al-Pd-Co, U-, V-phase. structures a 38
Pt-Co. jewellery alloy 66
Colloids, Ag. Pd. for Ag:Pd powder a 84
Pt 10.5. 136
Combinatorial Chemistry, in catalysis 24
Composites, ceramic matrix, with Al-Mg-Pd. a 38
Pd-ceramic membrane a 86
see also Nanocomposites
Conferences, 8th Int. Conf. Chem. of the PGMs.

Southampton,
106 81. 165, 166, 167
9th Int. Platinum Symp., Billings, MT, U.S.A., 2002 177
18th Conf. on Catal. of Org. React., Charleston,
SC U.S.A., 2000 23
EuropaCat-V. Limerick, Ireland, 2001 24
EuropaCat-VI, 2003 24
Fuel Cells for Automotive Applications, London, 2002 64
Fuel Cells - Science and Technology 2002.
Amsterdam, 2002 64
The Dynamic Electrode Surface, Berlin, 2002 106
Copper, Pt-Cu, jewellery alloy 66
Coupling Reactions, (arylboronic + carboxylic) acids, a 41
cross-, for C-C C-N bonds 50
homo-, iodoarenes, a 139
organosilanes, as coupling agents 50
Pd catalysts 50, 165
see also Heck Reactions and Suzuki Couplings
Creep, in Ir-based refractory superalloys 74
Crystallisation, Pd40Cu30P2oNi10 a 136
Pd43Ni10Cu27P20 melts a 38
Cyclisation, allylsilanes, a 41
unsaturated N -chloroamines, to piperidines, a 139
Cycloadditions, 1,3-dipolar a 190, 191
Cyclohexenes, 2-aryl-, from 2-arylcyclohexenols a 139
hydrogenation 176
Decomposition, CH4 a 189
MeOH a 190
NO, a 86
Dehalogenation, aryl halides a 41
Dehydrogenation, propane a 40
transfer, aromatic alcohols a 40
Dendrimers, as catalysts 167, 180
Os(II), Ru(II) polypyridines, photoproperties, a 85
synthesis 165
Dental, alloys a 88
Deposition, Pd, at C paste electrodes a 85
see also Coatings and Electrodeposition
DHPS®, for the glass industry 181
Diesel, oxidation catalysts, Pt 27
particulate filters 27
selective catalytic reduction 27
Dihydroxylation, by OsO4 24, 82, 191
β-Diketones, Pt(II) with Al(CH3)3, for Pt networks 105
Pt(II) β-diketonates, photoreactions with olefins, a 39
Dimerisation, of [M(L-L)2(eilatin)]2+, M = Os, Ru, a 136
2,4-Dinitrotoluene, electron transfer reduction of 94
Ductility, in Ir-based refractory superalloys 74
Electrical Conductivity, in (C7H13NH)[Pd(dmit)2]2, a 39
Electrical Contacts, ohmic, Pd/n*-GaAs, a 88
Pt, with Si interlayers, on p -type SiC, a 191
Electrochemical Cells, CerOx waste process 18
Electrochemistry, a 84-85,137, 188
book review 15
cathode reactivity of Pd, Pt, in dry DMF 94
destruction of hazardous organic wastes 18
doping, of Pt phthalocyanine microcrystals, a 85
in fuel cells, see Fuel Cells
Electrodeposition, Os, Os alloys, a 189
Pt, fine particles a 39
see also Coatings and Deposition
Electrodeposition and Surface Coatings, a 39, 85, 189
Electrodes, Au, anchoring of Pt(II) complex, a 137
Au-Pt black, for glucose sensor a 86
C paste, Pd deposition and dissolution a 85
conference 106
in fuel cells, see Fuel Cells
Pd, cathode reactivity in dry DMF 94
Pt(III), for CO electrochemical oxidation 106
Pt, cathode reactivity in dry DMF 94
for CO electrooxidation 106
in hydrocarbon sensor a 40
microdisk, in NO sensor a 40
nanoparticles, + nano-honeycomb diamond films, a 84
thin films, for MIM capacitors, a 189
wire, for in vivo biological sensors 72
Pt-plated Ti, in CerOx electrochemical cell 18
Pt-PtOx thin films, for memory capacitors, a 88
PtRu, for CO electrooxidation 106
Ru(001), electrooxidation 106
RuO2/C, in supercapacitors, a 88
n -Si, with fine Pt particles, a 39
Ti2FeRuO2, Tix Fey RUzOn, in supercapacitors 105
Ti/IrO2-TaO5, anode ageing, in H2SO4 a 188
Ti/IrO3,-Sb2O5-SnO2, wastewater electroflotation a 137
Electrodes, (cont.)
Ti/RuO2, anodes, preparation a 137
Ti/RuO3Mn1-3 O2 anodes, Cl2 + O2 evolution a 188
Electroflotation, of wastewater a 137
ElectroIess Plating, Ag-Pd thin films, for membranes, a 86
Pt, on SPE membranes a 40
Emission Control, motor vehicles 27, 190
Erbium, Pd-Er-H. H effects on 169
Etching, Pt, by ICP, using BCl3/Cl2 a 140
Ethene, copolymerisation with alkylacrylates a 139
non-alternating copolymerisation with CO a 139
Ethers, cyclic enol, by ring-closing enyne metathesis, a 140
oxidation a 87
EthyI Pyruvate, hydrogenation a 86
Europe, EU adopted emission control, legislation 27
Eutectic Reactions, Pd-rare earths 108
Films, Co-Pt, sputtered on (001)-oriented Si wafer, a 140
Ir, by MOCVD a 39
Pt, by CVD, for memory capacitors 107
see also Thin Films
‘Final Analysis’ 2, 48, 92, 144
Fracture, in Ir-based refractory superalloys 74
Fuel Cells a 42,88, 140, 191
automotive use 24, 64
catalysts, Pt/C, for MeOH oxidation a 42
for O2 reduction reaction, in presence of Cl-, a 42
PtRu, CO tolerance 106, 122
conferences 24, 64
DMFC, anodes 14, 146
cathodes 146
MEAs 146
miniaturisation 161
portable applications 161

electrocatalysts, Pt-Ru/C, by sulfito method, a
191
electrodes, Pt-Ru, nanostructured, CO oxidation, a 191
Fuel Cell Catalysts Brochure, Alfa Aesar 14
HiSPEC fuel cell catalysts 14, 146
low temperature, catalysis 3, 64, 117. 146
membrane electrode assemblies 3, 117, 140. 146
nanoparticles 3, 88, 117, 146
PEFC, Pt-Ru/C electrocatalysts, XANES, a 140
MEAs a 140
PEMFC, air bleed technique 129
anodes 117
cathodes 3, 88
CO2, CO, poisoning 117
comparison with DMFC 146
electrocatalysts, anode, PtMo, PtRu 117
cathode, Osx (CO)n /Vulcan C, a 88
Pt, Pt alloys 3
MEAs 3, 117
water electrolysis, effects 132
SOFC, LaSrCrRuO, anode material, a 191
see also Catalysts, Iridium, Platinum, Ruthenium
Gases, high purity H2, O2 144
Geology, book 17
conference 177
Glass, production technology 181
Glucose, oxidation 106, 138
sensors a 40. 86
Halogenation, of aromatic compounds, olefins a 42
Heck Reactions 50, 139. 165
High Temperature, Ir-based refractory superalloys 74
High Throughput Screening Techniques 24 , 87. 190
Hydroalkenylation, alkynes, with silanediols, a 139
Hydroarylation, alkynes, with silanediols a 139
Hydrocarbons, emission control in EU 27
oxidation a 86
sensor, a 40
Hydrocracking, n -decane, a 189
Hydrodechlorination, chlorinated olefins, a 138
Hydrofonmylation-Hydrogenation, l-octene a 41

Hydrogen,absorption. Pd
106, 169, 188
book review 37
damage of capacitors a 42
electrooxidation 117
interaction with Pd, Pd alloys 37, 169
sensors a 189
separation, using Pd-Ag membrane reactor a 189
using Pd-ceramic membranes a 86
solid solutions, in Pd 169
structural changes in Pd, Pd-Er, Pd-W 169
treatment of materials 37
Hydrogenation, acid chlorides 73
α-(acylamino)acrylic acids, esters 82
alkynes 73
arenes. a 42. 138
asymmetric, acrylic acids 180
book review 73
carboxylic acids, α.β-, β.γ-unsaturated 82
chiral-catalysed 82
cyclohexene 176
ethyl pyruvate, a 86
ketones 82, 138
lignin 167
in liquid phase batch reactors 48,92
1 -octene 176
phenols a 86, 190
polystyrenes a 86
Hydrolysis, cis-, trans-Pt(Ypy)2(NO3)2, a 188
Hydrosilylation, alkynes. a 138
Hydrotalcitcs, catalyst support 26
Insulators, single-molecule, trans -Pt(II) complex a 137
Ion Source, high temperature, of Pd a 136
Ion Transfer, IrCI6, across liquid interface a 137
Ionic Liquids, solvents a 191
Iridium, films, by MOCVD a 39
Ir(III), surface, for electrolyte hydration 106
thin films, by DC sputtering a 42
Iridium Alloys, (Ir, Rh)75,Nb15Ni10, specific strength 74
Ir-Nb, Ir-Zr, Ir-Nb-Ni, Ir-Nb-Ni-Al 74
Pt-Ir, jewellery alloy 66
superalloys, refractory: creep, ductility, fracture 74
Iridium Complexes, IrCl61, ion transfer a 137
[Ir(DPF)3], electrophosphorescence a 137
luminescence 137, 165
Iridium Compounds, electrodes a 137.188
IrO2, thin films, by DC sputtering a 42
IrO2/PLZT/Pt, capacitors a 42
Isomerisation, n -decane, 189
lsoxazolidines, synthesis a 190
Jewellery, Pt, Pt alloys, welding by laser 66
Johnson Matthey, ACT, Power Coatings 181

catalysis for fuel cells, research
106. 64, 117, 146
FibreCat 24, 190
PGM Conference competition winners 166, 167
“Platinum 2002” 116
Rhodium Bicentenary Competition, winner 2

Ketones, synthesis
106, 41, 191
hydrogenation 82, 138
Kumada-Tamao-Corriu Couplings 50
Lasers, to drill cavities in Pt wire electrodes 72
welding of Pt jewellery 66
Lignin, hydrogenation 167
Liquid Crystals, Rh carboxylate polymers a 188
Luminescence, electrochemi-, Ir(ppy)3, a 137
Ru(bpy)32*. a 39. 137
Ir terpyridyls 165
Os(II) polypridines, dendrimers a 85
photo-, Ir(ppy)3 a 137
Pt(II) quaterpyridine a 39
Ru(bpy)32+. a 137
Pt octaethylporphyrin a 137
Luminescence (cont.)
Ru terpyridyls 165
Ru(II) polypridines, dendrimers. a 85
Macrocycles, Pd(lI), Pt(II) a 39
Magnesium, Al-Mg-Pd, melt oxidation a 38
Magnetism, in CoCrPt perpendicular media a 191
in CoCrPtB layers, on TiZr underlayers. a 140
in SrCuRhO, SrNiRhO a 136
Mass Spectrometry, differential electrochemical a 42
laser-activated membrane introduction, LAMIMS, a 190
Medical Uses a 88
PGM Conference 165. 166
Melting Points, Pt, Pt alloys 66. 181

MEAs, in fuel cells
106, 117. 140, 146
Membranes, Pd-Ag, for CH4 decomposition a 189
Pd-ceramic a 86
SPE, with Pt particles a 40
Memory, capacitors for 88, 107
L.-Menthol. commercial synthesis 82
Metathesis, of olefins. RCM. ROMP a 87
ring-closing enyne. a 140
Methanation, CO2 a 86
Methane, activation a 87
decomposition a 189
partial oxidation 24
steam reforming a 191
Microwaves, in phenylation of aroryl chlorides a 87
in synthesis of [RuCp(dppm)SR]. a 136
MOCVD, Ir films a 39
Myrcene, oxidation a 190
Nanocomposites, Pd:Ag, physical properties a 84
Pt-Ru/GCNF, for DMFC anodes 14
RuO2/C, supercapacitors a 88
see also Composites
Nanocrystalline Powders, Pd:Ag. a 84
Ti,Fe,Ru2O4, in supercapacitors 105
Nanocrystals, Pt-Ru, on GCNF 14
Nanoparticles, Pd, on Al2O3NiAl, model catalyst a 190
embedded in ZrO2. H2 absorption a 188
in H2o-in-oil microemulsions a 38
stabilised by polyfluorinated chains a 84
Pt. 3D networks. Al-organic-stabilised 105
on γ-Al2O3, catalysis 115
on C nanospheres, a 38
with nano diamond films, as electrodes a 84
preparation a 136

in Pt, Pt alloys, fuel cell electrocatalysts
106, 88, ! 17, 146
Pt, Pt/Ru, surface diffusion of chemisorbed CO 106
Nanostructures, PGM Conference 165
Pt-Ru electrodes, for fuel cells, 0 191
Nanowires, Pt. a 136
(S)-(+)-Naproxen, synthesis 82
Nitrogen Oxides, NO, decomposition a 86
sensor a 40
NOx, adsorbers 27
DeNOx, catalysts 27
reduction 24, 41
selective catalytic reduction of diesel emissions 27
Nitroxides, reactions with Rh porphyrin alkyls a 188
NMR, multi-, aqueous products of Pt(Ypy)2(NO3)2, a 188
Nobel Prize, Chemistry, chiral-catalysed reactions.
pgm catalysts 82
Noril'sk, PGE geology, conference 177
l-Octene, reactions 41, 176
Ohmic Contacts, see Electrical Contacts
OLEDs, [Ir(DPF)3] in PVK/PBD a 137
Olefins, dihydroxylation. asymmetric a 191
as H acceptors a 40
Kharasch addition, of CCl4, a 87
metathesis: RCM, ROMP a 87
with Pt(II) β-diketonates, photoreactions a 39
Oligomerisation, phenylacetylene. a 190
Osmium, electrodeposition u 189
Osmium Alloys, electrodeposition, a 189
Osmium Complexes, in glucose sensors, a 40
ground and excited states 106
luminescence, a 85
Os3(CO)12, pyrolysis, a 88
Os,bipy-modified DNA, voltammetric analysis a 138
[Os(L-L)2(eilatin)]2+, dimerisation a 136

Osmium Compounds, osma-aromatics, osmabenzenes
106
OsO4, in DNA voltammetric analysis, a 138
Os(VIII), oxidation state 165

Oxidation, alcohols
106, 26, 42, 84, 191
alkenes, a 39
chiral-catalysed 82

electro-,CO
106,106,191
formaldehyde, formic acid 106
H2 117
MeOH 106, 106, 146
ethers a 87
glucose 106, 138
hydrocarbons a 86
liquid organic waste 18
melt, Al-Mg-Pd a 38
MeOH a 42, 84
myrcene a 190
NH3 24
partial, CH4 24
[Pt11Cl2(H2enda)] a 84
thiophenea 138
VOCs, a 138, 189
wet, phenol a 138
Oxygen, reaction with CO, a 40
reduction reaction, ORR, for Osx(CO)n/Vulcan C, a 106
on Pt/C, for fuel cells a 42
sensors a 137
Palladium, AlMgPd ceramic composites, formation, a 38
cathodic reactivity, in superdry conditions 94
circuit patterns, on polyimide a 137
interaction with H2 37, 169
ion source a 136
nanoparticles, a 38, 84, 188, 190
Pd in poly(para -phenylene), phosphorescence 187
Pd:Ag, nanocomposite a 84
Pd-H, structural changes 169
Pd-rare earth systems, phase diagrams 108
Pd/n+-GaAs ohmic contacts, + Ge, Sn layers a 88
[Pdm-, M+, MX], [Pd,”, Μ*,(MX)], electrogenerated 106
solid solutions of H 169
thin films a 85, 189
Palladium Alloys, Ag-Pd-Gd-Ru a 38
Al-Mg-Pd, melt oxidaton a 38
Al-Pd-Co, U-, V-phase, structures a 38
dental, Ag-Au-Pd-Cu a 88
interaction with H2 37, 169
membranes a 86, 189
Pc10Cu30P20Ni10, a 136
Pd13Ni10Cu27P20 melts, crystallisation, a 38
Pd-Er-H, Pd-W-H, structural changes 169
Pd-Pt, interaction with H2 37
Pd-rare earths 108
Pt-Pd, jewellery alloy 66
Ti(PdNi), shape memory a 188
Palladium Complexes, (BQA)PdCl, preparation a 38
(C7H13NH)2[Pd(dmit)2], air-oxidation of a 39
(C7H13NH)[Pd(dmith)2], electrical conductivity, a 39
Pd(II) N2S2 macrocycles, synthesis a 39
Pd(II) with pincer-like amido ligand a 38
in poly(para -phenylene), synthesis 187
[Pd11Cln, formation, at C paste electrode a 85
Palladium Compounds, Pd(NH3)4Cl2, reduction, a 38
Na2(Pd2Cl6), reduction a 84
Patents 43-7,89-91,141-143, 192-194
pH, sensors a 189
Phase Diagrams, Ag-Pd-Gd-Ru a 38
Ir-Nb-Ni, Ir-Nb-Ni-Al 74
Pd-rare earth systems 108
Phase Transformation Kinetics, Pd-H, Pd-Er-H,
Pd-W-H 169
Phenols, hydrogenation a 86, 190
wet oxidation, a 138
Phenylation, aroyl chlorides, a 87
Phosphorescence, from Ir-based OLEDs a 137
from Pd-poly(para -phenylene) 187
Photocatalysis, in Pt(II) quaterpyridine complex a 39

Photoconversion, a
106,85, 137, 189
PGM Conference 165
Photoluminescence, see Luminescence
Photoproperties, Pt-phenylene ethynylene
monomers, polymers, a 189
Ru(phen)2(3-carbethoxy,4-hydroxy-phen)2+(PF6)2, a 189
Ru polypyridines, biomimetic assemblies, a 85
rac -[Ru(bpy)2(PhP(OMe)2(Cl)]Cl,a 85
Ru(II) bipyridyls. dendrimeric oligomers 165
Photoreactions, Pd(II) to Pd, by UV irradiation a 137
[(PEt3),HPt(μ-H2)Pt(PEt3)2][BPh4], Pt-Pt homolysis ;,a 85
[(PEt3),HPt(μ-H2)PtH(PEt3)2][BPh4], Pt homolysis, a is,a 85
[(PEt32PtH2], [(PEt3)2PtH(S)][BPh4], formation, a 85
Pt(II) β-diketonates, with olefins, a 39
Rh/Tio2, CO2 reduction, by H2 a 39
Photosynthesis, Ru polypyridines, as models, a 85
Plperidines, from unsaturated N -chloroamines, a 139
“Platinum 106” 116
Platinum, ACT, Power Coatings 181
addition to, (NdEuGd)BaCuO, effects, a 42

capacitors
106, 88, 107, 189
cathodic reactivity, in superdry conditions 94

colloids
106, 136
drilling, by laser 72
electrodes, see Electrodes
etching, using BCl3/Cl2 gas plasma a 140
films 107
in glass making 181
laser welding, jewellery 66
melting point 66, 181

nanoparticles
106, 84, 88, 105, 106, 115, 136
nanowires, a 136
ohmic contacts, Pt/Si interlayers/p -type SiC a 191
in O sensors, a 137
particles, electroless plated, on SPE membranes, a 40
for solar cell electrodes a 39
[Pt2, Na+, Nal], reduction of 2,4-dinitrotoluene 94
Pt(III), surface, for electrolyte hydration 106
[Ptn, M+, MX], [Ptx, M+, (MX)], electrogenerated 94
single crystals, for CO electrooxidation a 84
thermal diffusivity 66
thin films, a 106,88,189
welding, laser 66
Platinum Alloys, CoCrPt film, perpendicular media.
magnetic properties a 191
CoCrPtB perpendicular media on TiZr,
magnetic properties a 140
electrodes, see Electrodes and Fuel Cells
films a 140
in glass making 181
jewellery, Pt alloys 66
laser welding, jewellery 66
melting points 66, 181
nanoparticles 88, 106
Pt-Pd, interaction with H2 37
Pt-Rh, coatings, ACT 181
thermal diffusivities 66
welding, laser 66
Platinum Complexes, trans -Pt(II), insulator, a 137
(BQA)PtCl, preparation a 38
(η-C2H4)(Cl)Pt(μ-Cl)2Ru(Cl)(η33-2,7-dimethyl-
octadienyl), nanocrystal precursor 14
(COD)PtCI2 + dimethylphenyl(quinolinyl)amine, a 38
luminescence, a 39, 137
Platinum Complexes, (cont.)
photoproperties, a 189
photoreactions, a 39. 85
precursors for CVD, a 38, 107,189
[Pt,Cl2){N (H)C(Bu')O}4], Pt(III)-Pt(III) distance a 136
[Pt2I2{N (H)C(Bu')0}4], a 136
Pt octaethylporphyrin, in O sensor a 137
Pt phthalocyanine, electrochemical doping of a 85
[PtlvCl2(enda)], by oxidation of [Pt11Cl2(H2enda)] a 84
[Pt(Cn)(H2O)2]2*, reaction with DL-penicillamine a 84
Pt(II) acetylacetonate, reaction with Al(CHi)2. 105
Pt(U) N2S2 macrocycles, synthesis a 39
Pt(II) with pincer-like amido ligand a 38
Pt(III) ‘lantern-shaped’ a 136
PtR2(COd), ligand displacement reactions a 136
PtR2L1, H2O-soluble diorgano-, synthesis a 136
cis-. rran.s-Pt(Ypyh(NOiK aquation, hydrolysis a 188
[RhbPMCO)i,,(dppm).,], [Rh»Pt2(CO)2,(dppm)2] a 38

Platinum Compounds,antitumouragents
106, 165, 166
electrodes a 88
K;[Pt(C2O4)2], K2PtCl4. K2PtCU. reduction a 136
thin films, α 88
Platinum Group Elements, geology book 17
geology conference 177
Pollution Control, organic wastes, destruction 18
wastewater, electroflotation a 137
see also Emission Control
Polymerisation, co- a 139
fast living radical a 140

ofphenylacetylene.i/
106,190
ROMP a 87
Polymers, coordination, Rh carboxylates a 188
matrix, for Pt complex thin film O sensor a 137
polyimide, with Pd circuit patterns a 137
poly(para-phenylene) + Pd, phosphorescence 187
polystyrenes, hydrogenation a 86
Pt-phenylene ethynylenes, photoproperties a 189
PVKyPBD, with [Ir(DPF),], for OLEDs. a 137
Power Coatings.
, for the glass industry
181
Propane, CO2 reforming of. a 41
dehydrogenation a 40
Propene, for reduction of NOx 24,41
Pyridines, chloro-, alkoxycarbonylation a 87
Rare Earths, Pd-rare earths, eutectic phases 108
solid solublities in Pd1 strengthening effects 108
RCM a 87. 140
Reactors, fixed bed catalyst, design aspects 144
hydrogen-permeating membrane a 189
for liquid phase batch hydrogenations 48, 92
Reduction, CO2, by H2 a 39
electron transfer, of 2,4-dinitrotoluene 94
Ο,,α 42
Reforming a 41, 191
Rhodium, Rhodium Bicentenary Competition 2
Rhodium Alloys, (Ir, Rh)75Nb15Ni10. specific strength 74
Pt-Rh, coatings, ACT 181
jewellery alloy 66
Rhodium Complexes, [Rh6Pt4(CO)16(dppm)3],
[Rh»Pt2(CO)2,(dppm)2] a 38
Rh porphyrin alkyls, reactions with nitroxides a 188
tetra(alkoxybenzoato)dirhodium(II), liquid crystals. a 188
pyrazine adducts, liquid crystals a 188
TpmsRh(LL) (LL = (CO)2, cod, nbd), Rh(I) chemistry, a 84
Rhodium Compounds, Sr1CuRhO6, SriNiRhO, a 136
ROMP a 87
Rosenmund Reduction, acid chlorides 73
effect of H2O 48
Russia, PGE geology, conference 177
Ruthenium, electrodes 106
Ru-doped InP, resistivities a 42
Ru(OOl), surface, for electrolyte hydration 106
Ruthenium Alloys, Ag-Pd-Gd-Ru a 38
electrodes, see Electrodes and Fuel Cells
nanoparticles 88. 106
Ruthenium Alloys {cont.)
Pt-Ru, jewellery alloy 66
Ta/Ru buffer layer, for CoCrPt perpendicular media a 191
Ruthenium Complexes, bis(rf-2.4-dimcthyl-
pentadienyl)Ru(II), for vapour-phase epitaxy a 42

cancerdrugs
106,166
(n-C2H4)(Cl)Pt^-Cl)2Ru(CI)(^':n‘-2,7-dimethyl-
octadienyl), nanocrystal precursor 14

luminescence
106. 85, 137, 165
(2-MeImHHRuClj(2-McIm);],
(2-MeImH)2[RuCl5(2-MeIm)l, synthesis a 84

photoproperties
106. 165, 189
[RuCp(dppm)SR], microwave-assisted synthesis a 136
[RuH(arene)(Binap)]CFiSO.i, piano-stool inverted a 188
[Ru(L-L)2(eilatin)]:+, dimerisation a 136

Ruthenium Compounds,electrodes
106, 105, 137. 188
LaSrCrRuO, SOFC anode material a 191
RuO2 powders, from RuCl1 thermal decomposition a 137
Selective Catalytic Reduction, + diesel particulate filter 27
NOx 27

Sensors, glucose, a
40. 86
H2 a 189
hydrocarbons a 40
in vivo biological 72
NO a 40
0^,o 137
pH,fl 189
Shape Memory Effect, in Ti(PdNi) u 188

Silanes
106. 50, 138, 139. 140
Single Crystals, Pt. CO electrooxidation u 84
Sol-Gel, Pt-doped SnO2 thin films a 85
RuO2, RuO2Hl anodes a 137
Solar Cells, with Pt particles on /i-Si electrodes a 39
Sonogashira Couplings, of terminal alkynes 50
South Africa, PGE geology, conference 177
Sputtering, DC films. Co-Pt a 140
thin films, Ir, IrO2. a 42
reactive r.f. magnetron, thin films. Pt-PtO, a 88
thin films. Pd-Ag. for Pd-ceramic membranes a 86
Stille Couplings, aryl halides + organostannanes 50
Sulfuric Acid, Ti/Ir02-Ta05 anodes, degradation a 188
Superalloys, Ir-based refractory 74
Supercapacitors, Ru02/C. nanoconiposite. a 88
Ti2FeRuO2. Ti,Fe,RuO,,. nanocrystalline 105
Superconductors, Pt + CeO^ additions 0 42
Suzuki Couplings, FibreCat. Pd/C. a 190
Pd-polymer-bound phosphine. a 191
Suzuki-Miyaura Couplings 50
Tetraalkylammonium Salts, effects on Pd. Pt cathodes.
in superdry conditions 94
Tetralins, amino-, synthesis a 191
Thermal Diffusivities, Pt, Pt alloys 66
Thin Films, Ir, IKX by DC sputtering a 42
Ni/Pd, XRD a 85
Pd. circuit patterns on polyimide a 137
Pd, for poly-Si wires, as H2 sensors a 189
Pd-Ag. for ceramic composite membranes a 86
Pt, by chemical vapour deposition a 189
Pt octaethylporphyrin. for O sensors a 137
Pt-doped SnO2. sol-gel preparation a 85
Pt-PtO,, for memory capacitor electrodes a 88
Ti(PdNi), shape memory behaviour. 0 188
see also Films
Thiopenes, oxidation a 138

Three-Way Catalysts
106. 40
Tungsten, Pd-W-H. H effects on 169
Pt-W. jewellery alloy 66

VOCs,oxidation.ii
106, 189
VoItammetry, (DNA-Os,bipy). microanalysis a 138
Water, waste, electrode system for electrofiotation a 137
Welding, laser, of Pt jewellery 66

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