Acetoxylation, oxidative, of alkenes | 20 |
Acetylcholine, sensor, a | 185 |
Acetylenes, phenyl-, living polymerisation, a | 135 |
terminal, Sonogashira couplings, a | 91 |
Actuators, shape memory alloys | 58 |
Air, photocatalytic purification | 61 |
Alcohols, dehydration | 20 |
ethyl, electrooxidation, a | 40 |
in fuel cells | 28 |
methyl, adsorption, desorption, a | 132 |
electrooxidation, a | 40, 92, 136, 187 |
oxidation | 27, 134, 135 |
selective | 20, 185 |
Aldehydes, from alcohols, a | 134, 185 |
oxidation, a | 135 |
Alkanes, dehydrogenation | 13, 39 |
oxidation | 20 |
Alkenes, acetoxylation, alkoxylation, oxidative | 20 |
from alkanes, a | 39 |
from alkynes | 44 |
hydroformylation | 14, 91, 135 |
hydrogenation, a | 90, 134, 135 |
oxidation | 20, 135 |
Alkoxylation, oxidative, of alkenes | 20 |
Alkylation, asymmetric, 1,3-diphenylallylic systems, a | 135 |
Alkynes, intramolecular couplings, a | 40 |
oxidation, a | 135 |
reduction | 44 |
Alloys, dental, a | 187 |
mechanical properties | 46, 111 |
Amination, amino ester + aryl bromides, a | 186 |
Amines, carbonylation, oxidative, a | 91 |
Amino Acids, aromatic, reduction, a | 134 |
Pt clusters, growth | 98 |
Ammonia, oxidation | 36, 111 |
reaction with NO, a | 39 |
Antibacterial Agents, Ag/Pt coated polymers | 131 |
Antimicrobial Agents, Ru(II)-arenes, a | 136 |
Antisense Drugs, trans-PtII-modified PNA oligomers, a | AquaCat®, pgm recovery, from spent catalysts | 163 |
Arenes, iodo-, carbonylation, a | 40 |
oxidation, a | 135 |
Aryl Halides, coupling reactions, a | 39, 90, 91, 134, 135, 186 |
Aryl Triflates, Suzuki-Miyaura couplings, a | 90 |
Arylation, intramolecular, of pyrimidines, a | 40 |
Aryldiazonium Salts, cross-coupling reactions, a | 39 |
Autocatalysts | 13, 15, 20, 96, 140, 157 |
Benzene, photodegradation | 183 |
Biomass, gasification, a | 39 |
Biphenyls, by coupling, of substituted halobenzenes, a | 39 |
Book Reviews, “Electron Microscopy in Heterogeneous Catalysis” | 110 |
‘Polymeric platinum-containing drugs in the treatment of cancer’ | 109 |
“Surface Chemistry and Catalysis” | 120 |
“The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of Platinum-Group Elements” | 59 |
Cancer, anti-, pgm complexes | 92, 109, 136 |
Capacitors, HD memory, RuTiN diffusion barrier, a | 187 |
microsuper-, RuO2 electrode, W-RuO2 electrode, a | 187 |
Pd alloy powders | 36 |
Carbenes | 37, 39, 73, 88, 184 |
Carbon Oxides, CO, adsorption energy, a | 184 |
CO/H2 mixtures, oxidation, a | 90 |
for intramolecular alkyne–alkyne couplings, a | 40 |
oxidation | 20 |
poisoning, in PEMFC | 107 |
sensors, a | 89, 185 |
tolerance, in PEMFC, a | 91 |
CO2, production, in benzene photodegradation | 183 |
solvent, a | 91, 34 |
Carbonylation, iodoarenes, a | 40 |
oxidative, amines, a | 91 |
RuCl3·3H2O, to Ru carbonyls, a | 37 |
5-vinyloxazolidin-2-ones, a | 90 |
Carbonyls, Pd(+1) clusters, as catalysts | 20 |
[Rh(CO)4]+, luminescence, a | 89 |
Ru, from RuCl3·3H2O, a | 37 |
Carboxylic Acids, aryl, thermolysis of Pd4(CO)4(OAc)4 | 20 |
from alcohols, a | 185 |
hydrogenation, a | 90 |
Catalysis, book reviews | 110, 120 |
in CO2 solvent, a | 91, 34 |
conferences | 13, 28 |
electron microscopy, use of | 110 |
in H2O solvent | 60, 174 |
heterogeneous, a | 39, 90, 134, 185–86 |
history | 175 |
homogeneous, a | 39–40, 90–91, 134–135, 186 |
surface chemistry | 120 |
Catalysts, agglomeration | 44 |
deactivation | 13, 44 |
metal loss | 44 |
model | 120 |
pgm, supported single crystals | 120 |
poisoning, chemical, physical | 44 |
recycling | 13, 39, 134, 186 |
Selectra™ Shift, for reformer | 28 |
spent, precious metal recovery | 163 |
three-way, see Three-Way Catalysts | |
Catalysts, Iridium, Ir, in lean-burn gasoline engine | 157 |
Ir/SrTiO3, H2O photocleavage | 2 |
Ir/TiO2, H2O photooxidation | 2 |
Ir(0) nanoclusters, cyclohexene hydrogenation, a | 135 |
Catalysts, Iridium Complexes, cyclooctadienylIr(I) hexafluoropentanedionate, D labelling, a | 186 |
Ir-HetPHOX, asymmetric hydrogenations, a | 186 |
IrCl(CO)(PPh3)2, alkyne–alkyne couplings, a | 40 |
Vaska’s complex, alkyne–alkyne couplings, a | 40 |
Catalysts, Osmium, Os/SrTiO3, H2O photocleavage | 2 |
Catalysts, Osmium Complexes, OsO4/polymer | 174 |
PVI-Os(dpa)2Cl, with diaphorase, a | 92 |
Catalysts, Palladium, APK-2/α-Al2O3, NOx conversion | 20 |
electrocatalysts, PtPd/C | 28, 91 |
Lindlar’s catalyst, reduction of alkynes | 44 |
palladised metal(IV) phosphates, hydrogenations, a | 90 |
Pd, HC emission oxidation | 157 |
nanostructured, in pellistor sensors | 72 |
supported, CH4 combustion, a | 90 |
Pd clusters/Sibunit, hydrocarbon oxidation | 20 |
Pd clusters/spherical SiO2 particles, CO, HC, oxidation | 20 |
Pd nanoparticles, hydrogenation of olefins, a | 134, 186 |
phen protected, a | 186 |
Pd powder, + KF/Al2O3, solventless Suzuki coupling, a | 134 |
Pd-Cu/C, thermal treatments | 110 |
Pd-Fe, dehalogenation of trihalomethanes, a | 186 |
Pd-zeolite beta spheres, preparation, a | 90 |
Pd/Al2O3, CH4 combustion, S poisoning | 13 |
sintering mechanisms | 110 |
Pd/C, + NaCl, for debenzylation, a | 186 |
spent, Pd recovery | 163 |
+ tetrabutylammonium bromide, biphenyl synthesis, a | 39 |
Pd/CaCO3 + Pb, reduction of alkynes | 44 |
Pd/Rh, TWC, high thermal durability | 15 |
Pd/SrTiO3, H2O photocleavage | 2 |
Pd/Ti silicalite, synthesis of propylene oxide, a | 134 |
Pd/TiO2, H2O photoreduction | 2 |
H2O purification | 61 |
STM studies | 13 |
Pd4(CO)4(OCOR)4 + bipy/oxide carrier, oxidations | 20 |
NOx reduction, by CH4 | 20 |
Pd4(CO)4(OCOR)4 + phen/α-Al2O3, NOx conversion | 20 |
Pd4(CO)4(OCOR)4 + phen/oxide carrier, oxidations | 20 |
NOx reduction, by CH4 | 20 |
Pt/Pd/Rh, TWC, pgm loading | 157 |
TiO2-Pd(II) chloride | 61 |
Catalysts, Palladium Complexes, (η3-allyl)Pd, addition | |
polymerisation of norbornene-type monomers, a | 40 |
monocarbenepalladium(0), coupling reactions, a | 39 |
Na{Pd4[CpMo(CO)3]4}, dehydration of alcohols | 20 |
PAMAM dendrimer-Pd(RcN)2Cl2/SiO2, -Pd(tetra-methylethylenediamine)Me2/SiO2, a | 40 |
Pd(+1) carbonyl clusters, oxidations | 20 |
Pd with P,N -ferrocenyl ligands, allylic alkylation, a | 135 |
Pd-dendrimer nanocomposites, olefin hydrogenation, a | 40 |
Pd-phosphine-PS-PEG resin, reactions in H2O | 60 |
Pd/C + PPh3, Sonogashira coupling, a | 91 |
Pd2(dba)3/BINAP/NaOt Bu, coupling amination, a | 186 |
Pd4(CO)4(OCOR)4/bipy, /phen, olefin oxidation | 20 |
PdCl2/HP(adamantyl)2, /HP(t -butyl)2, Heck reactions, a | 39 |
PdCl2(dppf), Suzuki coupling, solid phase, a | 135 |
PdCl2(dppf)·CH2Cl2/Cs2CO3, S.-M. coupling, a | 90 |
PdCl2(PPh3)2, preparation of δ-lactam, a | 90 |
Suzuki-Miyaura coupling, a | 135 |
PdI2 + KI, oxidative carbonylation of amines, a | 91 |
Pd(OAc)2, in TBAB-H2O, Suzuki coupling, a | 91 |
Pd(OAc)2 + NBu3/P(o -tolyl)3, Heck reaction, a | 91 |
Pd(OAc)2/PPh3, Sonogashira coupling, a | 91 |
Pd(OAc)2/PPh3/NEt4Cl/K2CO3, cyclisations, a | 186 |
Pd(OAc)2/PPh3/TlOAc, cyclisations, a | 186 |
Pd(OAc)2(PPh3)2 + base, arylation, intramolecular, a | 40 |
Pd(PPh3)4, Sonogashira coupling, a | 91 |
removal, by polymer-bound ethylenediamines, a | 135 |
Catalysts, Platinum, electrocatalysts, nanoparticles, Pt, on C, for DMFC, a | 40 |
Pt, on C, Ru deposition, MeOH oxidation, a | 136 |
Pt, on polypyrrole nanotubules, for fuel cells a | 187 |
Pt, Pt-Ru, spheres, on C | 28 |
Pt, for fuel cells | 28, 40, 135, 136, 187 |
Pt/carbon-CH2CH2PO3H2, for PEMFCs, a | 135 |
Pt, + Cr, Fe, Mn, Mo, Pd, for fuel cells | 28 |
Pt/Ni, for DMFCs, a | 187 |
PtPd4/C, for PEMFCs, a | 91 |
PtRh, EtOH electrooxidation, a | 40 |
PtRu, for fuel cells | 28, 92, 107, 136, 187 |
PtRuMo, for PEMFCs, reactivity imaging | 107 |
Pt-Ru-P/C nanocomposites, anodes, for DMFCs, a | 187 |
HPS-Pt-THF, direct L-sorbose oxidation, a | 185 |
platinised metal(IV) phosphates, hydrogenations, a | 90 |
Pt, addition, Ru-Sn/active C, hydrogenations, a | 90 |
in autocatalysts, emission control: diesel, gasoline, lean-burn gasoline | 15, 157 |
filter, aldehydes, CO, HC conversion, from diesel | 157 |
ceramic foam, PM removal, from diesel emissions | 157 |
PM, from diesel emissions | 15, 157 |
HC + NOx | 157 |
oxidation, CO, HC, NO | 157 |
MeOH, a | 136 |
NOx-traps | 15, 157 |
with Ru/C, hydrogenation of glucose to sorbitol | 13 |
Pt, Bi/C, N2O decomposition, a | 39 |
Pt, Bi/C, 1-octanol to octanoic acid, a | 185 |
2-octanol to 2-octanone, a | 185 |
Pt-Rh/SiO2, heat treatment; under N2 | 110 |
Pt-Ru-Sn/active C, hydrogenations, a | 90 |
Pt-Sn-K/, Pt-Sn-K-Fe/Al2O3, dehydrogenations, a | 39 |
Pt–WOx, MeOH oxidation, a | 136 |
Pt/Al2O3, butane dehydrogenation | 13 |
CCl4 hydrodechlorination, a | 90 |
CH4 combustion, S poisoning | 13 |
sintering mechanisms | 110 |
Pt/Al2O3-coated monolith, oxidation of CO/H2, a | 90 |
Pt/B/TiO2, H2O photocleavage | 2 |
Pt/Ba + Rh, NOx storage/reduction | 13 |
Pt/C, N2O decomposition, a | 39 |
spent, Pt recovery | 163 |
Pt/fluorinated C, NO + NH3, a | 39 |
Pt/Pd/Rh, TWC, pgm loading | 157 |
Pt/polypyrrole, electrooxidation of MeOH, a | 187 |
Pt/Rh, TWC, high thermal durability | 15 |
Pt/’RuO2’/TiO2, H2O photocleavage | 2 |
Pt/’RuO2’/TiO2 doped with Cr, H2O photocleavage | 2 |
Pt/SiO2, hydrogenation, of ethene, ethyne, a | 134 |
Pt/Sn/Al2O3 filaments, a | 39 |
Pt/SrTiO3, H2O photocleavage | 2 |
Pt/TiO2, air purification | 61 |
benzene photodegradation, magnetic field effects | 183 |
H2O, photocleavage, photoreduction, purification | 2, 61 |
Pt/TiO2/SiO2, H2O photoreduction | 2 |
Pt/WO3, H2O photooxidation | 2 |
Ru, Pt/C, oxidation of alcohols, a | 185 |
TiO2-Pt(IV) chloride, H2O purification | 61 |
Catalysts, Rhodium, autocatalysts, NOx reduction | 13, 157 |
Pd/Rh, TWC, high thermal durability | 15 |
Pt-Rh/SiO2, heat treatment; under N2 | 110 |
Pt/Pd/Rh, TWC, pgm loading | 157 |
Pt/Rh, TWC, high thermal durability | 15 |
PtRh, EtOH electrooxidation, a | 40 |
Rh, EtOH electrooxidation, a | 40 |
Rh/Al2O3, CH4 combustion, S poisoning | 13 |
reduction of aromatic amino acid derivatives, a | 134 |
Rh/C, reduction of aromatic amino acid derivatives, a | 134 |
Rh/CeO2/SiO2, biomass gasification, a | 39 |
Rh/TiO2, H2O, photooxidation, photoreduction | 2 |
STM studies | 13 |
Rh/WO3, H2O photooxidation | 2 |
TiO2-Rh(III) chloride | 61 |
Catalysts, Rhodium Complexes, [(cod)RhL’Cl] | 73 |
[(nbd)RhCl]2/PH2C=C(Ph)Li/Ph3P, polymerisation, a | 135 |
Rh with P,N -ferrocenyl ligands, hydroboration, a | 135 |
Rh POSS dendrimers, oct-1-ene hydroformylation | 14 |
[RH2(OAc)4]/phosphines, hydroformylation in sc-CO2, a | 91 |
RH2[(R)-DDBNP]4, RH2[(S )-DOSP]4, a | 91 |
Rh(bpy)33+/TiO2, H2O photoreduction | 2 |
[RhCl(cod)]2, alkyne-alkyne couplings, a | 40 |
[Rh(L-L)NBD]BF4/Nafion, hydroformylation, a | 135 |
[Rh(L)2NBD]BF4/Nafion, hydroformylation, a | 135 |
Catalysts, Ruthenium, Cu-Ru/C, CO, H2 treatments | 110 |
electrocatalysts, PtRu, for fuel cells | 28, 92, 107, 136, 187 |
PtRuMo, for PEMFCs, reactivity imaging | 107 |
Ru-Se, for fuel cells | 28 |
Pt-Ru-Sn/active C, hydrogenation of carboxylic acids, a | 90 |
Pt/’RuO2’/TiO2, H2O photocleavage | 2 |
Pt/’RuO2’/TiO2 doped with Cr, H2O photocleavage | 2 |
Ru, Pt/C, oxidation of alcohols, a | 185 |
RuIV-CoIII oxide, oxidation of alcohols, a | 134 |
Ru-Sn/active C, hydrogenation of carboxylic acids, a | 90 |
Ru/Al2O3, oxidation of alcohols | 27 |
Ru/C cathode, electroreduction of N2, a | 184 |
with Pt, hydrogenation of glucose to sorbitol | 13 |
Ru/SrTiO3, H2O photocleavage | 2 |
Ru/TiO2, H2O photooxidation | 2 |
oxidation of organic pollutants, in H2O | 13 |
Ru/WO3, H2O photooxidation | 2 |
‘RuO2’/BaTi4O9, H2O photocleavage | 2 |
‘RuO27In1-xNixTaO4, H2O photocleavage | 2 |
RuO2/WO3, H2O photooxidation | 2 |
RuO2·xH2O/WO3, H2O photooxidation | 2 |
Catalysts, Ruthenium Complexes, Grubbs catalysts, a | 186 |
Ru benzylidenes, ROMP, a | 186 |
Ru bipy, Ru phen, WGSR, a | 40 |
RuO4, oxidations, in dimethyl carbonate-H2O, a | 135 |
CCRT™, for diesel emission control | 15, 157 |
Cerium, addition to, Pt-Pd-Rh, mechanical properties | 111 |
Chagas’ Disease, Ru complexes | 87 |
Chemical Vapour Deposition, macroporous films, a | 185 |
Chemiluminescence, see Luminescence | |
Chlorate, electrolysis, a | 133 |
Choline, sensor, a | 185 |
Chromatography, Pd, Rh, Ru | 123 |
CHT™, for gasoline emission control | 15, 157 |
Clusters, Pd(+1) carbonyls, as catalysts | 20 |
Pd, nucleation and growth, on biopolymers | 98 |
[PdBi10]4+, a | 184 |
Pt, nucleation and growth, on biopolymers | 98 |
in solution | 98 |
[Ru5C(CO)15], gas sensor activity, a | 89 |
Coatings, Ag/Pt, on polymers, antibacterial activity | 131 |
Ir-Re, by plasma-based ion implantation, a | 38 |
Pd-Ni, for microcantilevers, in H2 sensor, a | 89 |
Pt, for cantilevers, in scanning microscopy probes, a | 38 |
see also Deposition and Electrodeposition | |
Combinatorial Chemistry, fuel cell cataysts | 107 |
Suzuki couplings, a | 135 |
use of K alkenyltrifluoroborates, a | 90 |
Combustion, CH4 | 13, 90 |
Conferences, 4th Noble and Rare Metals: NRM-2003, Donetsk, Ukraine, 2003 | 36 |
8th Grove Fuel Cell Symposium, London, 2003 | 31 |
Catalyst Life Cycle, University of Bath, U.K., 2002 | 13 |
Fuel Cells – Science and Technology 2002, Amsterdam, 2002 | 28 |
Hannover Messe, Hydrogen + Fuel Cells, 2003 | 108 |
IFSSEHT-2003, Sarov, Russia, 2003 | 166 |
SAE, Detroit, U.S.A. | 15, 157 |
Coupling Reactions | 39, 40, 73, 186 |
see also Heck Reactions and Suzuki Couplings | |
Creep, -rupture curves, Pt-Pd-Rh, + Ce, + Ru | 111 |
CRT™, for diesel emission control | 15, 96, 157 |
Cyclisation, to pyrazolidines, a | 186 |
Cyclometallates, Pd phenylbipyridines, luminescence, a | 38 |
L-Cysteine, determination of, a | 89 |
L-Cystine, determination of, a | 89 |
Debenzylation, in synthesis of quinolinones, a | 186 |
Decomposition, N2O, a | 39 |
Dehalogenation, trihalomethanes, a | 186 |
Dehydration, alcohols | 20 |
Dehydrogenation, alkanes | 13, 39 |
Dendrimers, as catalysts | 14, 40 |
Dental, alloys, a | 187 |
Deoxymannojirimycin, synthesis, a | 90 |
Deposition, Pd, on dielectric surfaces, a | 185 |
see also Coatings and Electrodeposition | |
Deuterium, interaction with Pd, Pd alloys | 166 |
labelling, a nilines, benzylamines, N heterocycles, a | 186 |
Diacyls, from thermolysis of Pd4(CO)4(OCOR)4 | 20 |
Diesel, particulate filters, for emissions control | 15, 96, 157 |
PM, control, by CCRT™ | 15, 157 |
by CRT™ |
15, 96, 157 |
by EGR-CRT™ | 157 |
by SCRT™ | 157 |
S content | 96 |
Dihydroxylation, asymmetric, olefins | 174 |
Dispersion Hardening, of alloys, for glass production | 36 |
Displacive Transformations, Pt alloys | 142 |
DNA, Pt clusters, growth | 98 |
EGR-CRT™, for diesel emission control | 157 |
Electrical Contacts, ohmic, Pd/Ru/p-GaN, a | 92 |
Pt, on p-GaN, a | 136 |
Electrochemistry, a | 88, 133, 184 |
oximes, on Pt(100) surfaces, on Pt(111) surfaces, a | 88 |
[SiW11O39RuIII(H2O)]5–, a | 88 |
[SiW11O39RuIVORuIIISiW11O39]11–, a | 88 |
Electrodeposition, Pd, codeposition of H, a | 89 |
films, nanostructured, on Si | 72 |
on Ni, a | 89 |
Rh, on Ti substrates, a | 38 |
see also Coatings and Deposition | |
Electrodeposition and Surface Coatings, a | 38, 89, 133, 185 |
Electrodes, C paste, Ir, + Cu, Pd, Ru, in glucose sensor, a | 38 |
FePO4, + RuO2, for Li cells, a | 184 |
in fuel cells, see Fuel Cells | |
[Os(bpy)2(bpy-(CH2)13SH)]2+/Au, with ascorbic acid, a | 88 |
with dopamine, a | 88 |
Pd/C, anode, in electroreduction of N2, a | 184 |
Pt nanoparticles, embedded, in C film, a | 185 |
Ru-based DSA®, chlorate electrolysis, a | 133 |
Ru/C, cathode, in electroreduction of N2, a | 184 |
RuO2, W-RuO2, in microsupercapacitors, a | 187 |
Ti/IrO2-TaO5, microstructure, a | 88 |
Electroless Plating, Pd, on α-Al2O3, a | 134 |
on TiN barrier films, for electroless Cu, a | 133 |
Electrolysis, chlorate, a | 133 |
Emission Control, motor vehicles | 13, 15, 96, 140, 157 |
Etching, Pt ultrathin films, a | 89 |
Ethers, oxidation, a | 135 |
Films, Pd, on Au single crystals, a | 184 |
nanostructured | 72 |
Pt, Pt-Pd, macroporous, by CVD, a | 185 |
Ru β-diketonato polypyridyls on TiO2, a | 38 |
see also Thin Films | |
‘Final Analysis’ | 44, 96, 140 |
Foils, Fe/Pt, a | 132 |
Fracture, brittle, in Ir, Ir alloys | 36 |
in Pt-Pd-Rh alloys, Ce addition, Ru addition | 111 |
Fuel Cells, a | 40, 91–92, 135–136, 187 |
bio-, anodes, a | 92 |
catalysts, Pt nanoparticles/C, + Ru deposition, a | 136 |
Pt/C, PtRu/C, MeOH electrochemical oxidation, a | 136 |
conferences | 28, 31, 108 |
direct 2-propanol fuel cell | 28 |
DMFC, anodes, Pt-Ru/, Pt-Ru-P/C, nanocomposites, a | 187 |
cathode, Ru-Se | 28 |
electrocatalysts, high throughput screening, a | 91 |
Pt/polypyrrole, a | 187 |
Pt nanoparticles/polypyrrole nanotubules, a | 187 |
Pt/Ni, a | 187 |
Pt-Ru/mesocarbon microbead support, a | 92 |
electrodes, a | 40 |
MEAs, a | 91 |
electrodes, Pt, Pt–WOx, MeOH oxidation, a | 136 |
fuel, H2 | 28, 108, 119, 166 |
low temperature, electrocatalysts, Pt/C, a | 187 |
MCFC, with gas turbines | 28 |
membrane electrode assemblies | 28, 91 |
nanoparticles | 28, 40, 136, 187 |
PEMFC, CO poisoning | 107 |
CO tolerance, a | 91 |
electrocatalysts, Pt, Pt alloys | 28, 135 |
Pt nanoparticles/polypyrrole nanotubules, a | 187 |
Pt/carbon-CH2CH2PO3H2, a | 135 |
PtPd4/C, a | 91 |
PtRu, PtRuMo, reactivity imaging | 107 |
Pt-Ru/C, a | 92 |
electrodes, Pt | 107, 108 |
MEAs | 28 |
as power sources, for camcorder | 108 |
for fork-lift truck | 108 |
for public transport | 108 |
for video camera | 108 |
SOFC, with gas turbines | 28 |
Gasification, biomass, a | 39 |
Gasoline, S content | 96 |
Gauzes, NH3 oxidation | 36, 111 |
Geology, book | 59 |
Glass, production, using dispersion hardened alloys | 36 |
Glucose, hydrogenation | 13 |
sensors, a | 38, 185 |
Gorsky Effect, on H diffusion coefficients, in Pd77Ag23 | 32 |
Heck Reactions, a | 39, 91 |
Heterocycles, synthesis, a | 40 |
High Throughput Screening, fuel cell catalysts | 91, 107 |
History, Enrico Fermi | 167 |
Ir isotopes, discoverers | 167 |
Pd discovery, uses | 175 |
Rh discovery, uses | 175 |
Smithson Tennant | 175 |
William Hyde Wollaston, Wollaston Medal | 175 |
Hydroboration, styrene, with catechol borane, a | 135 |
Hydrocarbons, emission control | 15, 96, 157 |
hydrogenation, a | 134 |
oxidation | 20 |
reforming | 28, 108 |
Hydrodechlorination, CCl4, a | 90 |
Hydroformylation, alkenes | 14, 91, 135 |
Hydrogen, atomic, adsorption energy, a | 184 |
by photocleavage, photoreduction, of H2O | 2 |
CO/H2 mixtures, oxidation, a | 90 |
codeposited, in Pd electrodeposition, a | 89 |
diffusion coefficents, in Pd77Ag23 membranes | 32 |
economy | 166 |
electrooxidation, a | 187 |
extraction | 166 |
fuel, for fuel cells | 28, 108, 119, 166 |
interaction, with Pd, Pd alloys, Pt, Pt alloys, Rh | 166 |
with Pd, hydride phases, video studies | 119 |
purification | 32 |
safety | 166 |
sensors | 89, 166 |
separation, from gases | 134, 166 |
transport | 166 |
Hydrogen Peroxide, electrooxidation, a | 185 |
sensor, a | 185 |
Hydrogen Sulfide, sensor, a | 89 |
Hydrogenation, alkenes, a | 90, 134, 135 |
asymmetric, imines, olefins, a | 186 |
carboxylic acids, a | 90 |
ethyne, a | 134 |
glucose | 13 |
hydrocarbons, a | 134 |
olefins, a | 40, 134, 186 |
Imines, hydrogenation, asymmetric, a | 186 |
Ion Exchange, Pd ions, Rh ions, Ru ions | 74, 123 |
Ionic Liquids, solvents, a | 186 |
Iridium, brittle fracture | 36 |
for C paste electrodes, a | 38 |
Ir(110), N2O dissociation, a | 37 |
isotopes, history of the discoveries | 167 |
thin films, by MOCVD, a | 133 |
Iridium Alloys, brittle fracture | 36 |
Ir-Re coatings, by plasma-based ion implantation, a | 38 |
Iridium Complexes, cyclometallation-induced formation of M–C bonds to sp2 C of aryl and vinyl groups | 73 |
Ir carbenes | 73, 184 |
Ir(COD)(MeCp), for MOCVD, a | 133 |
[Ir(pik)(phen)Cl2]+, luminescence, a | 185 |
K[Ir(pik)Cl4], spectral properties, a | 185 |
phosphorescence | 6, 89 |
Iridium Compounds, electrodes, a | 88 |
Isocyanides, for alkyne–alkyne couplings, a | 40 |
Isomerism, coordination, M(II) salicylhydroxamates, a | 184 |
Isotopes, detector, double-sided silicon strip | 167 |
Ir, discoveries | 167 |
Jewellery, Pt, Pt alloys | 36 |
Johnson Matthey, AquaCat® | 163 |
Catalysts division, ECT, PCT | 121 |
emission control, motor vehicles | 15, 96, 157 |
FP05 prototype reformer | 28 |
“Platinum 2003” | 122 |
‘Platinum Today’ website | 121 |
Johnson, Percival Norton | 175 |
Ketones, synthesis, a | 91, 185 |
Labelling, D2, anilines, benzylamines, N heterocycles, a | 186 |
Langmuir-Bodgett Films, conducting polymer/Ru3+, a | 134 |
Lasers, welding, of dental alloys, a | 187 |
LEDs, Os bpy, Ru bpy, Ru phen, a | 38 |
Luminescence, chemi-, Ru(bipy)32+, a | 89 |
cyclometallated Pd(II) complexes, a | 38 |
[Ir(pik)(phen)Cl2]+, a | 185 |
Pt(II) terpyridyl-capped C-rich molecular rods, a | 185 |
[Rh(CO)4]+, [Rh(CO)4](1-Et-CB11F11), a | 89 |
Ru(II) poly(pyridine)s, a | 133 |
Magnetism, Co/Pt nanomultilayers, properties, a | 37 |
effects, on benzene photodegradation | 183 |
D-Mannolactam, synthesis, a | 90 |
Mass Spectrometry, Ru complexes, + PS, + PP, a | 88 |
MEAs, array, high throughput screening, a | 91 |
in fuel cells | 28 |
Mechanical Properties, CoPt, FePd, NiPt, Pd3Fe, Pt3Co | 46 |
Pt-Pd-Rh, + Ce, + Ru | 111 |
Medical Uses | 87, 92, 109, 136, 187 |
Membranes, Pd, H2 permeation | 32 |
Pd alloys, H2 permeation | 32, 166 |
Pd-Cu, Pd-Y, Pd-In-Ru, H extraction | 166 |
Pd/Ag, reactor, microstructured filament catalyst, a | 39 |
Pd/Ag on α-Al2O3, for H separation, a | 134 |
Pd77Ag23, hydrogen diffusion coefficients | 32 |
Pd/Si, Pt/Si, for H separation | 166 |
Memory, capacitors, a | 187 |
Metallabenzenes, platinabenzene, synthesis, a | 37 |
Methane, combustion | 13, 90 |
in NOx reduction | 20 |
sensor | 72 |
Microscopy, electron, in heterogeneous catalysis | 110 |
Microwaves, to prepare, aryl isonipecotic acids, a | 186 |
Pt nanoparticles/C, a | 40 |
in solventless Suzuki couplings, a | 134 |
MOCVD, Ir thin films, a | 133 |
NADH, electrochemical oxidation, a | 92 |
Nanocomposites, Pt-Ru/, Pt-Ru-P/C, electrocatalysts, a | 187 |
Nanomultilayers, Co/Pt, magnetic anisotropy, a | 37 |
Nanoparticles, Pd, phen protected, a | 186 |
Pt, embedded, in C film electrode, a | 185 |
Pt, fuel cell electrocatalysts | 28, 40, 136, 187 |
Nanostructures, LB film, conducting polymer + Ru3+, a | 134 |
Pd films | 72 |
Pd30-, Pd54-core, nanosized, synthesis, a | 132 |
Nitric Acid, manufacture | 111 |
Nitrogen, adsorption, Rh(II) benzoate pyrazine, a | 88 |
desorption, from Ir(110), Pd(110), Rh(110), a | 37 |
electroreduction, a | 184 |
Nitrogen Oxides, NO, reaction with NH3, a | 39 |
scavengers, Ru(III) polyaminocarboxylates, a | 136 |
NOx, catalytic control systems | 15, 157 |
in PM combustion | 15, 157 |
reduction, by CH4 | 20 |
selective catalytic reduction of diesel emissions | 157 |
storage/reduction | 13 |
-traps | 15, 96, 157 |
N2O, decomposition, a | 39 |
dissociation, on Ir(110), Pd(110), Rh(110), a | 37 |
Nitrosoarenes, reaction with Pd4(CO)4(OCOR)4 | 20 |
Nuclear Waste, HLLWs, recovery, of Pd, Rh, Ru | 74, 123 |
Ohmic Contacts, see Electrical Contacts | |
Oils, engine, additives | 140 |
OLEDs, red, Os(II)(N–N)2L–L in PVK/PBD, a | 38 |
Olefins, asymmetric dihydroxylation | 174 |
coupling reactions, a | 39, 135 |
hydrogenation, a | 40, 134, 186 |
asymmetric, a | 186 |
oxidation | 20 |
Osmium, recovery and separation | 36 |
Osmium Complexes, electrodes, a | 88 |
Os bpy, in LEDs, a | 38 |
Os(II)(N–N)2L–L, phosphorescence, a | 38 |
Osmium Compounds, Ba3LiOs2O9, Ba3NaOs2O9, a | 132 |
Oxidation, alcohols | 27, 134, 135 |
aldehydes, a | 135 |
alkanes | 20 |
alkenes | 20, 135 |
alkynes, a | 135 |
arenes, a | 135 |
CO | 20 |
CO/H2 mixtures, a | 90 |
electro-, EtOH, a | 40 |
H2, a | 187 |
H2O2, a | 185 |
MeOH, a | 40, 92, 136, 187 |
electrochemical, NADH, a | 92 |
ethers, a | 135 |
hydrocarbons | 20 |
NH3 | 36, 111 |
olefins | 20 |
organic pollutants, in H2O | 13 |
selective, alcohols | 20, 185 |
L-sorbose, a | 185 |
unsaturated compounds | 20 |
using supercritical H2O, of spent catalysts | 163 |
Oxygen, by photocleavage, photooxidation, of H2O | 2 |
sensors, a | 133 |
Palladium, addition to, Mg-Ni, for H storage | 28 |
deposition, on dielectric surfaces, a | 185 |
discovery, history | 175 |
electrodeposition | 72, 89 |
electrodes, a | 38, 184 |
in fuel cells, see Fuel Cells | |
electroless plating, a | 133, 134 |
films, for CH4 detection | 72 |
hydride phases, video studies | 119 |
interaction with D2, interaction with H2 | 166 |
membranes | 32 |
overlayers, on Au single crystals, a | 184 |
palladised, Co oxide, Mn oxide, interaction with H2 | 166 |
Pd/Ru/p-GaN ohmic contacts, a | 92 |
Pd(110), N2O dissociation, a | 37 |
Pd(111), MeOH adsorption, MeOH desorption, a | 132 |
recovery, from nuclear waste | 74, 123 |
from spent catalysts | 163 |
Palladium Alloys, Au-Cu-Pd, phase diagrams | 36 |
Bi2Pd, intermetallic phase, a | 184 |
capacitors | 36 |
dental, Pd-Ag-Cu-Au, a | 187 |
interaction with D2, interaction with H2 | 166 |
mechanical properties, FePd, Pd3Fe | 46 |
Pt-Pd-Rh, + Ce, + Ru | 111 |
membranes | 32, 39, 134, 166 |
Pd-Ni, coatings, for microcantilevers, in H2 sensor, a | 89 |
Pd/V, MeOH adsorption, MeOH desorption, a | 132 |
Pt-Pd films, macroporous, by CVD, a | 185 |
shape memory effect, Fe-Pd | 37, 58 |
Fe-Pd-Pt, a | 37 |
TiPdNi, a | 184 |
Palladium Complexes, BINAP(O) Pd, synthesis, a | 132 |
clusters, nucleation and growth, on biopolymers | 98 |
[(COD)PdMe(L)]n+, synthesis, a | 88 |
[(COD)PdMe(OH)], hydrolysis reactions, a | 88 |
Me-PdII N -heterocyclic, germylenes, silylenes, a | 88 |
Na2{Pd4[CpMo(CO)3]4}, synthesis | 20 |
[(μ-OH){(COD)PdMe}2]+, hydrolysis reactions, a | 88 |
Pd carbenes, a | 39, 88, 184 |
[Pd4(CO)2L4]X4, L = bipy, phen, synthesis | 20 |
Pd4(CO)4(OAc)4, Pd4(CO)4(OCOR)4, synthesis | 20 |
[Pd30(CO)26(PEt3)10], [Pd54(CO)40(PEt3)14], nano core, a | 132 |
[Pd(C4H7)(hfac)], [Pd(hfac)2], in CVD, a | 185 |
PdII(hfac)2, + reduced S-terminated silanes, a | 185 |
[Pd(HL)Cl2], HL = thiohydrazone derivatives, a | 92 |
Pd(II), with reducing sugars, a | 184 |
Pd(II) salicylhydroxamates, coordination isomerism, a | 184 |
[Pd(Ln)Cl], Ln = bipy derivatives, luminescence, a | 38 |
Palladium Compounds, Bi14PdBr16, [pdBi10]4+, a | 184 |
PdO/SnO2, CO sensitivity, a | 185 |
Patents | 41-43, 93-95, 137-139, 188-190 |
searching of | 156 |
Phase Diagrams, Au-Cu-Pd | 36 |
Pt-Al-Ni, -Al-Ru, -Ti-Ni, -Ti-Ru | 142 |
Phosphorescence, btp2Ir(acac) | 60 |
electro-, Ir p -substituted 2-phenylpyridines, a | 89 |
Ir(ppy)3 | 60 |
Os(II)(N-N)2L-L, a | 38 |
Pt(II) diimine bis(pyrenylacetylide), a | 133 |
Photocatalysis, benzene degradation | 183 |
by semiconductors | 2, 61 |
Photocleavage, semiconductor-sensitised, H2O | 2 |
Photoconversion, a | 38, 89, 133, 185 |
Os bpy, a | 38 |
[Rh(NH3)5L]4+, a | 92 |
Ru bpy, Ru phen, a | 38 |
[Ru(bpy)2dppz]2+, light-switch effect | 19 |
Ru β-diketonato polypyridyls on TiO2, a | 38 |
Photoluminescence, see Luminescence | |
Photolysis, laser, Rh(III) porphyrins, a | 133 |
Photomineralisation, organic pollutants, a | 61 |
Photooxidation, semiconductor-sensitised, of H2O | 2 |
Pholeftroperties, chloro-pgm-, chloro-Pt(IV)-titania | 61 |
[Ir(pik)(phen)Cl2]+, K[Ir(pik)Cl4], a | 185 |
pgm/TiO2, pgm oxide/TiO2 | 2, 61 |
trans-[RuII(NH3)4(SO2)X]Y, isomerisation of SO2, a | 89 |
Photoreactions, semiconductor-sensitised | 2 |
Photoreduction, semiconductor-sensitised, of H2O | 2 |
Photosensitisation, semiconductors | 2 |
Photovoltaic Cell, Pt/C60/In/Al, a | 92 |
Plasma, ion implantation, of Ir-Re coatings, a | 38 |
Plasma Technology, ‘PM-plasmoceramic’ system | 36 |
“Platinum 2003” | 122 |
Platinum, Ag/Pt coated polymers, antibacterial activity | 131 |
in CeO2 O2 sensors, a | 133 |
coatings, for scanning microscopy probes, a | 38 |
electrical contacts, Pt, on p -GaN, a | 136 |
electrodes, in fuel cells, see Fuel Cells | |
films, macroporous, by CVD, a | 185 |
interaction with H2 | 166 |
isoleftes | 174 |
jewellery | 36 |
membranes | 166 |
nanoparticles | 28, 40, 136, 185, 187 |
photovoltaic cell, a | 92 |
Pt(100), Pt(111), reactivity of oximes, a | 88 |
recovery, from spent catalysts | 163 |
ultrathin films, a | 89 |
Platinum Alloys, Co/Pt nanomultilayers, magnetism, a | 37 |
Fe/Pt foils, a | 132 |
interaction with H2 | 166 |
jewellery | 36 |
mechanical properties, CoPt, NiPt, Pt3Co | 46 |
Pt-Pd-Rh, + Ce, + Ru | 111 |
nanoparticles | 28 |
Pt-Al, -Al-Ni, -Al-Ru, -Cr, -Cu, -Fe, -Ga, -Mn, -Ti, -Ti-Ni, -Ti-Ru, -V | 142 |
Pt-Pd films, macroporous, by CVD, a | 185 |
shape memory effect, Fe-Pd-Pt, a | 37 |
Pt3Al, PtFe3, PtTi, (Pt, Ni)Ti | 142 |
Platinum Complexes, cationic porphyrin-Pt, cancer, a | 136 |
clusters, nucleation, growth, on biopolymers, in solution | 98 |
dimers, trimers, formation | 98 |
platinabenzene, synthesis, from [Pt(cod)Cb], a | 37 |
polymeric, a nticancer drugs, a nticancer prodrugs | 109 |
Pt amine hydroxamates, biological activity, a | 136 |
trans-PtII-modified PNA oligomers, a ntisense drugs, a | 92 |
Pt(II) diimine pyrenylacetylide, phosphorescence, a | 133 |
Pt(II) salicylhydroxamates, coordination isomerism, a | 184 |
Pt(II) terpyridyl-capped C-rich molecular rods, a | 185 |
[Pt(L)2Cl2], HL = thiohydrazone derivatives, a | 92 |
[PtMe2(COD)], precusor for CVD, a | 185 |
Platinum Compounds, K2PtCl4, reduction | 98 |
Pt6Cl12, structure and bonding, a | 132 |
PtO/SnO2, CO sensitivity, a | 185 |
Platinum Group Elements,geology book | 59 |
PLEDs, Ir phenylpyridines | 60, 89 |
Pollution Control, in AquaCat® process | 163 |
dehalogenation of trihalomethanes, a | 186 |
off-gas, from metallurgical, petrochemical plants | 20 |
organics, oxidative degradation, a | 135 |
semiconductor photocatalysis, of air, H2O | 13, 61 |
see also Emission Control | |
Polymerisation, living, of phenylacetylenes, a | 135 |
ROMP, a | 186 |
vinyl addition, of norbornene-type monomers, a | 40 |
Polymers, with Ag/Pt coatings, antibacterial activity | 131 |
bio-, nucleation sites, for Pd clusters, Pt clusters | 98 |
-bound ethylenediamines, Pd removal, a | 135 |
conducting, + mer-[RuCl3(dppb)(py)], LB films, a | 134 |
conjugated star polymers, star block copolymers, a | 135 |
from norbornenedicarboxylic acid ester, by ROMP, a | 186 |
polypropylene, + (RuC5Me5)3H5, MS, a | 88 |
polypyrrole nanotubules, Pt support, electrocatalysts, a | 187 |
polystyrene, + [Ru(C5H5)(NCCH3)3][PF6], MS, a | 88 |
Pt-containing, as anticancer drugs, prodrugs | 109 |
Precipitation, Pd, Rh, Ru | 74, 123 |
Probes, with Pt coating, scanning probe microscopy, a | 38 |
Propylene Oxide, synthesis, a | 134 |
Pyrochemistry, Pd, Rh, Ru | 74, 123 |
Pyrones, alkenylmethyl-, alkynylmethyl-, synthesis, a | 91 |
Quinolinones, synthesis, a | 186 |
Reactors, fixed bed catayst, Pd-zeolite beta spheres, a | 90 |
fluidised bed continuous feeding, a | 39 |
membrane, microstructured by filamentous catalyst, a | 39 |
Recovery, Os | 36 |
Pd, Pt, Rh, from spent catalysts | 163 |
Pd, Rh, Ru, from nuclear waste | 74, 123 |
Reduction, alkynes | 44 |
aromatic amino acid derivatives, a | 134 |
chemical, Pd(II), Rh(III), Ru(IV) | 74 |
electrochemical, Pd(II) | 74, 123 |
electro-, N2, a | 184 |
NOx | 20 |
Refining, Rh | 36 |
Reforming, H2 generation, for fuel cells | 28, 108 |
Rhodium, discovery, history | 175 |
electrodeposition, on Ti substrates, a | 38 |
interaction with H2 | 166 |
recovery, from nuclear waste | 74, 123 |
from spent catalysts | 163 |
refining | 36 |
Rh(110), N2O dissociation, a | 37 |
Rhodium Bicentenary Competition winner, research | 73 |
Rhodium Alloys, Pt-Pd-Rh, + Ce, + Ru | 111 |
Rhodium Complexes, luminescence, a | 89 |
Rh carbenes | 73, 184 |
Rh(II), Rh(III), with bis(oxazoline) pincer ligands, a | 132 |
[Rh2(O2CPh)4(pyz)]∞, N2 adsorption, a | 88 |
Rh(II) trifluoroacetamidate, with 4,4’-bipy, 1,4-diaza-bicyclo [2.2.2]octane, pyrazine, as polymers, a | 37 |
[Rh(NH3)5L]4+, photocytotoxic agent, a | 92 |
(x-)(PPh3)RhIII-OEP, -TPP, laser photolysis, a | 133 |
ROMP, norbornenedicarboxylic acid ester, a | 186 |
Ruthenium, addition to, Mg-Ni, for H storage | 28 |
Pt-Pd-Rh, mechanical properties | 111 |
electrodes, a | 38, 133, 184 |
in fuel cells, see Fuel Cells | |
Pd/Ru/p-GaN ohmic contacts, a | 92 |
recovery, from nuclear waste | 74, 123 |
RuTiN, as diffusion barrier, in memory capacitors, a | 187 |
thin films, by atomic layer deposition, a | 133 |
Ruthenium Alloys, membranes | 166 |
nanoparticles | 28 |
Pt-Al-Ru, Pt-Ti-Ru | 142 |
RuTa, shape memory effect, a | 132 |
Ruthenium Complexes, luminescence, a | 89, 133 |
photoconversion | 19, 38 |
photoproperties, a | 89 |
+ PP, + PS, in mass spectrometry, a | 88 |
Ru carbene, chiral, a | 37 |
Ru carbonyls, by carbonylation of RuCl3·3H2O, a | 37 |
[RuCl2(p-cymene)]2, reaction with diphosphine, a | 37 |
[RuIIClII(DMSO)2semicarbazone], Chagas’ disease | 87 |
mer -[RuCl3(dppb)(py)], in LB films, a | 134 |
RuCp2, for atomic layer deposition, a | 133 |
Ru(II)-arenes, antimicrobial properties, a | 136 |
Ru(III) polyaminocarboxylates, NO scavengers, a | 136 |
Ruthenium Compounds, electrodes, a | 184, 187 |
[Ru5C(CO)15], gas sensor activity, a | 89 |
RuCl3·3H2O, carbonylation, a | 37 |
[SiW11O39RuIII(H2O)]5-, [SiW11O39RuIVORuIIISiW11O39]11- a | 88 |
Schottky Barriers, Pt/C60 interface, a | 92 |
SCRT™, for diesel emission control | 157 |
Selective Catalytic Reduction, NOx | 157 |
Semiconductors, photosensitisation | 2, 61 |
Sensitisers, visible light, chloro-pgm-titania | 2, 61 |
Sensors, acetylcholine, choline, a | 185 |
CH4 | 72 |
CO, a | 89, 185 |
glucose, a | 38, 185 |
H2 | 89, 166 |
H2O2, a | 185 |
H2S, a | 89 |
O2, a | 133 |
pellistor | 72 |
SO2, a | 89 |
taste: HCl, NaCl, quinine, sucrose, a | 134 |
Shape Memory Effect, Fe-Pd | 37, 58 |
Fe-Pd-Pt, a | 37 |
Pt3Al, PtFe3, PtTi, (Pt, Ni)Ti | 142 |
RuTa, a | 132 |
TiPdNi, a | 184 |
Single Crystals, Ba3LiOs2O9, Ba3NaOs2O9, a | 132 |
Solvent Extraction, Pd, Rh, Ru | 74, 123 |
Sonogashira Couplings, a | 91 |
Sorbitol, from glucose | 13 |
L-Sorbose, oxidation, a | 185 |
Sputtering, Ir-Re coatings, a | 38 |
Pt ultrathin films, a | 89 |
Sugars, Pd(II) complexes, a | 184 |
Sulfur, in diesel, gasoline | 96 |
Sulfur Oxides, SO2, sensor, a | 89 |
Superelastic Properties, TiPdNi, a | 184 |
Suzuki Couplings, a | 39, 91, 134, 135 |
Suzuki-Miyaura Couplings, a | 90, 135 |
Thermolysis, Pd4(CO)4(OCOR)4 | 20 |
Thin Films, Ir, by MOCVD, a | 133 |
Ru, by atomic layer deposition, a | 133 |
ultra-, Pt, on porous GaN, electroless etching, a | 89 |
see also Films | |
Three-Way Catalysts | 13, 15, 96, 157 |
Titanium, substrates, for electrodeposition of Rh, a | 38 |
TiO2, deposition, of pgms, pgm oxides | 2, 61 |
Trihalomethanes, dehalogenation, a | 186 |
Ureas, from amines, a | 91 |
5-Vinyloxazolidin-2-ones, carbonylation, a | 90 |
VOCs, destruction, by semiconductor photocatalysis | 61 |
Water, oxidation, photocleavage, photoreduction | 2 |
photocatalytic purification | 61 |
as solvent, for catalytic reactions | 60, 174 |
supercritical, oxidation, of spent catalysts | 163 |
Water Gas Shift Reaction | 28, 40 |
Welding, laser, of dental alloys, a | 187 |