Subject Index to Volume 47

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Platinum Metals Rev., 2003, 47, (4), 195

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a = abstract
Acetoxylation, oxidative, of alkenes	20
Acetylcholine, sensor, a	185
Acetylenes, phenyl-, living polymerisation, a	135
terminal, Sonogashira couplings, a	91
Actuators, shape memory alloys	58
Air, photocatalytic purification	61
Alcohols, dehydration	20
ethyl, electrooxidation, a	40
in fuel cells	28
methyl, adsorption, desorption, a	132
electrooxidation, a	40, 92, 136, 187
oxidation	27, 134, 135
selective	20, 185
Aldehydes, from alcohols, a	134, 185
oxidation, a	135
Alkanes, dehydrogenation	13, 39
oxidation	20
Alkenes, acetoxylation, alkoxylation, oxidative	20
from alkanes, a	39
from alkynes	44
hydroformylation	14, 91, 135
hydrogenation, a	90, 134, 135
oxidation	20, 135
Alkoxylation, oxidative, of alkenes	20
Alkylation, asymmetric, 1,3-diphenylallylic systems, a	135
Alkynes, intramolecular couplings, a	40
oxidation, a	135
reduction	44
Alloys, dental, a	187
mechanical properties	46, 111
Amination, amino ester + aryl bromides, a	186
Amines, carbonylation, oxidative, a	91
Amino Acids, aromatic, reduction, a	134
Pt clusters, growth	98
Ammonia, oxidation	36, 111
reaction with NO, a	39
Antibacterial Agents, Ag/Pt coated polymers	131
Antimicrobial Agents, Ru(II)-arenes, a	136
Antisense Drugs, trans-Pt^II-modified PNA oligomers, a	AquaCat^®, pgm recovery, from spent catalysts	163
Arenes, iodo-, carbonylation, a	40
oxidation, a	135
Aryl Halides, coupling reactions, a	39, 90, 91, 134, 135, 186
Aryl Triflates, Suzuki-Miyaura couplings, a	90
Arylation, intramolecular, of pyrimidines, a	40
Aryldiazonium Salts, cross-coupling reactions, a	39
Autocatalysts	13, 15, 20, 96, 140, 157
Benzene, photodegradation	183
Biomass, gasification, a	39
Biphenyls, by coupling, of substituted halobenzenes, a	39
Book Reviews, “Electron Microscopy in Heterogeneous Catalysis”	110
‘Polymeric platinum-containing drugs in the treatment of cancer’	109
“Surface Chemistry and Catalysis”	120
“The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of Platinum-Group Elements”	59
Cancer, anti-, pgm complexes	92, 109, 136
Capacitors, HD memory, RuTiN diffusion barrier, a	187
microsuper-, RuO₂ electrode, W-RuO₂ electrode, a	187
Pd alloy powders	36
Carbenes	37, 39, 73, 88, 184
Carbon Oxides, CO, adsorption energy, a	184
CO/H₂ mixtures, oxidation, a	90
for intramolecular alkyne–alkyne couplings, a	40
oxidation	20
poisoning, in PEMFC	107
sensors, a	89, 185
tolerance, in PEMFC, a	91
CO₂, production, in benzene photodegradation	183
solvent, a	91, 34
Carbonylation, iodoarenes, a	40
oxidative, amines, a	91
RuCl₃·3H₂O, to Ru carbonyls, a	37
5-vinyloxazolidin-2-ones, a	90
Carbonyls, Pd(+1) clusters, as catalysts	20
[Rh(CO)₄]⁺, luminescence, a	89
Ru, from RuCl₃·3H₂O, a	37
Carboxylic Acids, aryl, thermolysis of Pd₄(CO)₄(OAc)₄	20
from alcohols, a	185
hydrogenation, a	90
Catalysis, book reviews	110, 120
in CO₂ solvent, a	91, 34
conferences	13, 28
electron microscopy, use of	110
in H₂O solvent	60, 174
heterogeneous, a	39, 90, 134, 185–86
history	175
homogeneous, a	39–40, 90–91, 134–135, 186
surface chemistry	120
Catalysts, agglomeration	44
deactivation	13, 44
metal loss	44
model	120
pgm, supported single crystals	120
poisoning, chemical, physical	44
recycling	13, 39, 134, 186
Selectra^™ Shift, for reformer	28
spent, precious metal recovery	163
three-way, see Three-Way Catalysts
Catalysts, Iridium, Ir, in lean-burn gasoline engine	157
Ir/SrTiO₃, H₂O photocleavage	2
Ir/TiO₂, H₂O photooxidation	2
Ir(0) nanoclusters, cyclohexene hydrogenation, a	135
Catalysts, Iridium Complexes, cyclooctadienylIr(I) hexafluoropentanedionate, D labelling, a	186
Ir-HetPHOX, asymmetric hydrogenations, a	186
IrCl(CO)(PPh₃)₂, alkyne–alkyne couplings, a	40
Vaska’s complex, alkyne–alkyne couplings, a	40
Catalysts, Osmium, Os/SrTiO₃, H₂O photocleavage	2
Catalysts, Osmium Complexes, OsO₄/polymer	174
PVI-Os(dpa)₂Cl, with diaphorase, a	92
Catalysts, Palladium, APK-2/α-Al₂O₃, NOx conversion	20
electrocatalysts, PtPd/C	28, 91
Lindlar’s catalyst, reduction of alkynes	44
palladised metal(IV) phosphates, hydrogenations, a	90
Pd, HC emission oxidation	157
nanostructured, in pellistor sensors	72
supported, CH₄ combustion, a	90
Pd clusters/Sibunit, hydrocarbon oxidation	20
Pd clusters/spherical SiO₂ particles, CO, HC, oxidation	20
Pd nanoparticles, hydrogenation of olefins, a	134, 186
phen protected, a	186
Pd powder, + KF/Al₂O₃, solventless Suzuki coupling, a	134
Pd-Cu/C, thermal treatments	110
Pd-Fe, dehalogenation of trihalomethanes, a	186
Pd-zeolite beta spheres, preparation, a	90
Pd/Al₂O₃, CH₄ combustion, S poisoning	13
sintering mechanisms	110
Pd/C, + NaCl, for debenzylation, a	186
spent, Pd recovery	163
+ tetrabutylammonium bromide, biphenyl synthesis, a	39
Pd/CaCO₃ + Pb, reduction of alkynes	44
Pd/Rh, TWC, high thermal durability	15
Pd/SrTiO₃, H₂O photocleavage	2
Pd/Ti silicalite, synthesis of propylene oxide, a	134
Pd/TiO₂, H₂O photoreduction	2
H₂O purification	61
STM studies	13
Pd₄(CO)₄(OCOR)₄ + bipy/oxide carrier, oxidations	20
NOx reduction, by CH₄	20
Pd₄(CO)₄(OCOR)₄ + phen/α-Al₂O₃, NOx conversion	20
Pd₄(CO)₄(OCOR)₄ + phen/oxide carrier, oxidations	20
NOx reduction, by CH₄	20
Pt/Pd/Rh, TWC, pgm loading	157
TiO₂-Pd(II) chloride	61
Catalysts, Palladium Complexes, (η³-allyl)Pd, addition
polymerisation of norbornene-type monomers, a	40
monocarbenepalladium(0), coupling reactions, a	39
Na{Pd₄[CpMo(CO)₃]₄}, dehydration of alcohols	20
PAMAM dendrimer-Pd(RcN)₂Cl₂/SiO₂, -Pd(tetra-methylethylenediamine)Me₂/SiO₂, a	40
Pd(+1) carbonyl clusters, oxidations	20
Pd with P,N -ferrocenyl ligands, allylic alkylation, a	135
Pd-dendrimer nanocomposites, olefin hydrogenation, a	40
Pd-phosphine-PS-PEG resin, reactions in H₂O	60
Pd/C + PPh₃, Sonogashira coupling, a	91
Pd₂(dba)₃/BINAP/NaO^tBu, coupling amination, a	186
Pd₄(CO)₄(OCOR)₄/bipy, /phen, olefin oxidation	20
PdCl₂/HP(adamantyl)₂, /HP(t -butyl)₂, Heck reactions, a	39
PdCl₂(dppf), Suzuki coupling, solid phase, a	135
PdCl₂(dppf)·CH₂Cl₂/Cs₂CO₃, S.-M. coupling, a	90
PdCl₂(PPh₃)₂, preparation of δ-lactam, a	90
Suzuki-Miyaura coupling, a	135
PdI₂ + KI, oxidative carbonylation of amines, a	91
Pd(OAc)₂, in TBAB-H₂O, Suzuki coupling, a	91
Pd(OAc)₂ + NBu₃/P(o -tolyl)₃, Heck reaction, a	91
Pd(OAc)₂/PPh₃, Sonogashira coupling, a	91
Pd(OAc)₂/PPh₃/NEt₄Cl/K₂CO₃, cyclisations, a	186
Pd(OAc)₂/PPh₃/TlOAc, cyclisations, a	186
Pd(OAc)₂(PPh₃)₂ + base, arylation, intramolecular, a	40
Pd(PPh₃)₄, Sonogashira coupling, a	91
removal, by polymer-bound ethylenediamines, a	135
Catalysts, Platinum, electrocatalysts, nanoparticles, Pt, on C, for DMFC, a	40
Pt, on C, Ru deposition, MeOH oxidation, a	136
Pt, on polypyrrole nanotubules, for fuel cells a	187
Pt, Pt-Ru, spheres, on C	28
Pt, for fuel cells	28, 40, 135, 136, 187
Pt/carbon-CH₂CH₂PO₃H₂, for PEMFCs, a	135
Pt, + Cr, Fe, Mn, Mo, Pd, for fuel cells	28
Pt/Ni, for DMFCs, a	187
PtPd₄/C, for PEMFCs, a	91
PtRh, EtOH electrooxidation, a	40
PtRu, for fuel cells	28, 92, 107, 136, 187
PtRuMo, for PEMFCs, reactivity imaging	107
Pt-Ru-P/C nanocomposites, anodes, for DMFCs, a	187
HPS-Pt-THF, direct L-sorbose oxidation, a	185
platinised metal(IV) phosphates, hydrogenations, a	90
Pt, addition, Ru-Sn/active C, hydrogenations, a	90
in autocatalysts, emission control: diesel, gasoline, lean-burn gasoline	15, 157
filter, aldehydes, CO, HC conversion, from diesel	157
ceramic foam, PM removal, from diesel emissions	157
PM, from diesel emissions	15, 157
HC + NOx	157
oxidation, CO, HC, NO	157
MeOH, a	136
NOx-traps	15, 157
with Ru/C, hydrogenation of glucose to sorbitol	13
Pt, Bi/C, N₂O decomposition, a	39
Pt, Bi/C, 1-octanol to octanoic acid, a	185
2-octanol to 2-octanone, a	185
Pt-Rh/SiO₂, heat treatment; under N₂	110
Pt-Ru-Sn/active C, hydrogenations, a	90
Pt-Sn-K/, Pt-Sn-K-Fe/Al₂O₃, dehydrogenations, a	39
Pt–WO_x, MeOH oxidation, a	136
Pt/Al₂O₃, butane dehydrogenation	13
CCl₄ hydrodechlorination, a	90
CH₄ combustion, S poisoning	13
sintering mechanisms	110
Pt/Al₂O₃-coated monolith, oxidation of CO/H₂, a	90
Pt/B/TiO₂, H₂O photocleavage	2
Pt/Ba + Rh, NOx storage/reduction	13
Pt/C, N₂O decomposition, a	39
spent, Pt recovery	163
Pt/fluorinated C, NO + NH₃, a	39
Pt/Pd/Rh, TWC, pgm loading	157
Pt/polypyrrole, electrooxidation of MeOH, a	187
Pt/Rh, TWC, high thermal durability	15
Pt/’RuO₂’/TiO₂_, H₂O photocleavage	2
Pt/’RuO₂’/TiO₂ doped with Cr, H₂O photocleavage	2
Pt/SiO₂, hydrogenation, of ethene, ethyne, a	134
Pt/Sn/Al₂O₃ filaments, a	39
Pt/SrTiO₃, H₂O photocleavage	2
Pt/TiO₂, air purification	61
benzene photodegradation, magnetic field effects	183
H₂O, photocleavage, photoreduction, purification	2, 61
Pt/TiO₂/SiO₂, H₂O photoreduction	2
Pt/WO₃, H₂O photooxidation	2
Ru, Pt/C, oxidation of alcohols, a	185
TiO₂-Pt(IV) chloride, H₂O purification	61
Catalysts, Rhodium, autocatalysts, NOx reduction	13, 157
Pd/Rh, TWC, high thermal durability	15
Pt-Rh/SiO₂, heat treatment; under N₂	110
Pt/Pd/Rh, TWC, pgm loading	157
Pt/Rh, TWC, high thermal durability	15
PtRh, EtOH electrooxidation, a	40
Rh, EtOH electrooxidation, a	40
Rh/Al₂O₃, CH₄ combustion, S poisoning	13
reduction of aromatic amino acid derivatives, a	134
Rh/C, reduction of aromatic amino acid derivatives, a	134
Rh/CeO₂/SiO₂, biomass gasification, a	39
Rh/TiO₂, H₂O, photooxidation, photoreduction	2
STM studies	13
Rh/WO₃, H₂O photooxidation	2
TiO₂-Rh(III) chloride	61
Catalysts, Rhodium Complexes, [(cod)RhL’Cl]	73
[(nbd)RhCl]₂/PH₂C=C(Ph)Li/Ph₃P, polymerisation, a	135
Rh with P,N -ferrocenyl ligands, hydroboration, a	135
Rh POSS dendrimers, oct-1-ene hydroformylation	14
[RH₂(OAc)₄]/phosphines, hydroformylation in sc-CO₂, a	91
RH₂[(R)-DDBNP]₄, RH₂[(S )-DOSP]₄, a	91
Rh(bpy)₃³⁺/TiO₂, H₂O photoreduction	2
[RhCl(cod)]₂, alkyne-alkyne couplings, a	40
[Rh(L-L)NBD]BF₄/Nafion, hydroformylation, a	135
[Rh(L)₂NBD]BF₄/Nafion, hydroformylation, a	135
Catalysts, Ruthenium, Cu-Ru/C, CO, H₂ treatments	110
electrocatalysts, PtRu, for fuel cells	28, 92, 107, 136, 187
PtRuMo, for PEMFCs, reactivity imaging	107
Ru-Se, for fuel cells	28
Pt-Ru-Sn/active C, hydrogenation of carboxylic acids, a	90
Pt/’RuO₂’/TiO₂, H₂O photocleavage	2
Pt/’RuO₂’/TiO₂ doped with Cr, H₂O photocleavage	2
Ru, Pt/C, oxidation of alcohols, a	185
Ru^IV-Co^III oxide, oxidation of alcohols, a	134
Ru-Sn/active C, hydrogenation of carboxylic acids, a	90
Ru/Al₂O₃, oxidation of alcohols	27
Ru/C cathode, electroreduction of N₂, a	184
with Pt, hydrogenation of glucose to sorbitol	13
Ru/SrTiO₃, H₂O photocleavage	2
Ru/TiO₂, H₂O photooxidation	2
oxidation of organic pollutants, in H₂O	13
Ru/WO₃, H₂O photooxidation	2
‘RuO₂’/BaTi₄O₉, H₂O photocleavage	2
‘RuO₂7In_1-xNi_xTaO₄, H₂O photocleavage	2
RuO₂/WO₃, H₂O photooxidation	2
RuO₂·xH₂O/WO₃, H₂O photooxidation	2
Catalysts, Ruthenium Complexes, Grubbs catalysts, a	186
Ru benzylidenes, ROMP, a	186
Ru bipy, Ru phen, WGSR, a	40
RuO₄, oxidations, in dimethyl carbonate-H₂O, a	135
CCRT^™, for diesel emission control	15, 157
Cerium, addition to, Pt-Pd-Rh, mechanical properties	111
Chagas’ Disease, Ru complexes	87
Chemical Vapour Deposition, macroporous films, a	185
Chemiluminescence, see Luminescence
Chlorate, electrolysis, a	133
Choline, sensor, a	185
Chromatography, Pd, Rh, Ru	123
CHT^™, for gasoline emission control	15, 157
Clusters, Pd(+1) carbonyls, as catalysts	20
Pd, nucleation and growth, on biopolymers	98
[PdBi₁₀]⁴⁺, a	184
Pt, nucleation and growth, on biopolymers	98
in solution	98
[Ru₅C(CO)₁₅], gas sensor activity, a	89
Coatings, Ag/Pt, on polymers, antibacterial activity	131
Ir-Re, by plasma-based ion implantation, a	38
Pd-Ni, for microcantilevers, in H₂ sensor, a	89
Pt, for cantilevers, in scanning microscopy probes, a	38
see also Deposition and Electrodeposition
Combinatorial Chemistry, fuel cell cataysts	107
Suzuki couplings, a	135
use of K alkenyltrifluoroborates, a	90
Combustion, CH₄	13, 90
Conferences, 4th Noble and Rare Metals: NRM-2003, Donetsk, Ukraine, 2003	36
8th Grove Fuel Cell Symposium, London, 2003	31
Catalyst Life Cycle, University of Bath, U.K., 2002	13
Fuel Cells – Science and Technology 2002, Amsterdam, 2002	28
Hannover Messe, Hydrogen + Fuel Cells, 2003	108
IFSSEHT-2003, Sarov, Russia, 2003	166
SAE, Detroit, U.S.A.	15, 157
Coupling Reactions	39, 40, 73, 186
see also Heck Reactions and Suzuki Couplings
Creep, -rupture curves, Pt-Pd-Rh, + Ce, + Ru	111
CRT^™, for diesel emission control	15, 96, 157
Cyclisation, to pyrazolidines, a	186
Cyclometallates, Pd phenylbipyridines, luminescence, a	38
L-Cysteine, determination of, a	89
L-Cystine, determination of, a	89
Debenzylation, in synthesis of quinolinones, a	186
Decomposition, N₂O, a	39
Dehalogenation, trihalomethanes, a	186
Dehydration, alcohols	20
Dehydrogenation, alkanes	13, 39
Dendrimers, as catalysts	14, 40
Dental, alloys, a	187
Deoxymannojirimycin, synthesis, a	90
Deposition, Pd, on dielectric surfaces, a	185
see also Coatings and Electrodeposition
Deuterium, interaction with Pd, Pd alloys	166
labelling, a nilines, benzylamines, N heterocycles, a	186
Diacyls, from thermolysis of Pd₄(CO)₄(OCOR)₄	20
Diesel, particulate filters, for emissions control	15, 96, 157
PM, control, by CCRT^™	15, 157
by CRT^™
15, 96, 157
by EGR-CRT^™	157
by SCRT^™	157
S content	96
Dihydroxylation, asymmetric, olefins	174
Dispersion Hardening, of alloys, for glass production	36
Displacive Transformations, Pt alloys	142
DNA, Pt clusters, growth	98
EGR-CRT^™, for diesel emission control	157
Electrical Contacts, ohmic, Pd/Ru/p-GaN, a	92
Pt, on p-GaN, a	136
Electrochemistry, a	88, 133, 184
oximes, on Pt(100) surfaces, on Pt(111) surfaces, a	88
[SiW₁₁O₃₉Ru^III(H₂O)]^5–, a	88
[SiW₁₁O₃₉Ru^IVORu^IIISiW₁₁O₃₉]^11–, a	88
Electrodeposition, Pd, codeposition of H, a	89
films, nanostructured, on Si	72
on Ni, a	89
Rh, on Ti substrates, a	38
see also Coatings and Deposition
Electrodeposition and Surface Coatings, a	38, 89, 133, 185
Electrodes, C paste, Ir, + Cu, Pd, Ru, in glucose sensor, a	38
FePO₄, + RuO₂, for Li cells, a	184
in fuel cells, see Fuel Cells
[Os(bpy)₂(bpy-(CH₂)₁₃SH)]²⁺/Au, with ascorbic acid, a	88
with dopamine, a	88
Pd/C, anode, in electroreduction of N₂, a	184
Pt nanoparticles, embedded, in C film, a	185
Ru-based DSA^®, chlorate electrolysis, a	133
Ru/C, cathode, in electroreduction of N₂, a	184
RuO₂, W-RuO₂, in microsupercapacitors, a	187
Ti/IrO₂-TaO₅, microstructure, a	88
Electroless Plating, Pd, on α-Al₂O₃, a	134
on TiN barrier films, for electroless Cu, a	133
Electrolysis, chlorate, a	133
Emission Control, motor vehicles	13, 15, 96, 140, 157
Etching, Pt ultrathin films, a	89
Ethers, oxidation, a	135
Films, Pd, on Au single crystals, a	184
nanostructured	72
Pt, Pt-Pd, macroporous, by CVD, a	185
Ru β-diketonato polypyridyls on TiO₂, a	38
see also Thin Films
‘Final Analysis’	44, 96, 140
Foils, Fe/Pt, a	132
Fracture, brittle, in Ir, Ir alloys	36
in Pt-Pd-Rh alloys, Ce addition, Ru addition	111
Fuel Cells, a	40, 91–92, 135–136, 187
bio-, anodes, a	92
catalysts, Pt nanoparticles/C, + Ru deposition, a	136
Pt/C, PtRu/C, MeOH electrochemical oxidation, a	136
conferences	28, 31, 108
direct 2-propanol fuel cell	28
DMFC, anodes, Pt-Ru/, Pt-Ru-P/C, nanocomposites, a	187
cathode, Ru-Se	28
electrocatalysts, high throughput screening, a	91
Pt/polypyrrole, a	187
Pt nanoparticles/polypyrrole nanotubules, a	187
Pt/Ni, a	187
Pt-Ru/mesocarbon microbead support, a	92
electrodes, a	40
MEAs, a	91
electrodes, Pt, Pt–WO_x, MeOH oxidation, a	136
fuel, H₂	28, 108, 119, 166
low temperature, electrocatalysts, Pt/C, a	187
MCFC, with gas turbines	28
membrane electrode assemblies	28, 91
nanoparticles	28, 40, 136, 187
PEMFC, CO poisoning	107
CO tolerance, a	91
electrocatalysts, Pt, Pt alloys	28, 135
Pt nanoparticles/polypyrrole nanotubules, a	187
Pt/carbon-CH₂CH₂PO₃H₂, a	135
PtPd₄/C, a	91
PtRu, PtRuMo, reactivity imaging	107
Pt-Ru/C, a	92
electrodes, Pt	107, 108
MEAs	28
as power sources, for camcorder	108
for fork-lift truck	108
for public transport	108
for video camera	108
SOFC, with gas turbines	28
Gasification, biomass, a	39
Gasoline, S content	96
Gauzes, NH₃ oxidation	36, 111
Geology, book	59
Glass, production, using dispersion hardened alloys	36
Glucose, hydrogenation	13
sensors, a	38, 185
Gorsky Effect, on H diffusion coefficients, in Pd₇₇Ag₂₃	32
Heck Reactions, a	39, 91
Heterocycles, synthesis, a	40
High Throughput Screening, fuel cell catalysts	91, 107
History, Enrico Fermi	167
Ir isotopes, discoverers	167
Pd discovery, uses	175
Rh discovery, uses	175
Smithson Tennant	175
William Hyde Wollaston, Wollaston Medal	175
Hydroboration, styrene, with catechol borane, a	135
Hydrocarbons, emission control	15, 96, 157
hydrogenation, a	134
oxidation	20
reforming	28, 108
Hydrodechlorination, CCl₄, a	90
Hydroformylation, alkenes	14, 91, 135
Hydrogen, atomic, adsorption energy, a	184
by photocleavage, photoreduction, of H₂O	2
CO/H₂ mixtures, oxidation, a	90
codeposited, in Pd electrodeposition, a	89
diffusion coefficents, in Pd₇₇Ag₂₃ membranes	32
economy	166
electrooxidation, a	187
extraction	166
fuel, for fuel cells	28, 108, 119, 166
interaction, with Pd, Pd alloys, Pt, Pt alloys, Rh	166
with Pd, hydride phases, video studies	119
purification	32
safety	166
sensors	89, 166
separation, from gases	134, 166
transport	166
Hydrogen Peroxide, electrooxidation, a	185
sensor, a	185
Hydrogen Sulfide, sensor, a	89
Hydrogenation, alkenes, a	90, 134, 135
asymmetric, imines, olefins, a	186
carboxylic acids, a	90
ethyne, a	134
glucose	13
hydrocarbons, a	134
olefins, a	40, 134, 186
Imines, hydrogenation, asymmetric, a	186
Ion Exchange, Pd ions, Rh ions, Ru ions	74, 123
Ionic Liquids, solvents, a	186
Iridium, brittle fracture	36
for C paste electrodes, a	38
Ir(110), N₂O dissociation, a	37
isotopes, history of the discoveries	167
thin films, by MOCVD, a	133
Iridium Alloys, brittle fracture	36
Ir-Re coatings, by plasma-based ion implantation, a	38
Iridium Complexes, cyclometallation-induced formation of M–C bonds to sp² C of aryl and vinyl groups	73
Ir carbenes	73, 184
Ir(COD)(MeCp), for MOCVD, a	133
[Ir(pik)(phen)Cl₂]⁺, luminescence, a	185
K[Ir(pik)Cl₄], spectral properties, a	185
phosphorescence	6, 89
Iridium Compounds, electrodes, a	88
Isocyanides, for alkyne–alkyne couplings, a	40
Isomerism, coordination, M(II) salicylhydroxamates, a	184
Isotopes, detector, double-sided silicon strip	167
Ir, discoveries	167
Jewellery, Pt, Pt alloys	36
Johnson Matthey, AquaCat^®	163
Catalysts division, ECT, PCT	121
emission control, motor vehicles	15, 96, 157
FP05 prototype reformer	28
“Platinum 2003”	122
‘Platinum Today’ website	121
Johnson, Percival Norton	175
Ketones, synthesis, a	91, 185
Labelling, D₂, anilines, benzylamines, N heterocycles, a	186
Langmuir-Bodgett Films, conducting polymer/Ru³⁺, a	134
Lasers, welding, of dental alloys, a	187
LEDs, Os bpy, Ru bpy, Ru phen, a	38
Luminescence, chemi-, Ru(bipy)₃²⁺, a	89
cyclometallated Pd(II) complexes, a	38
[Ir(pik)(phen)Cl₂]⁺, a	185
Pt(II) terpyridyl-capped C-rich molecular rods, a	185
[Rh(CO)₄]⁺, [Rh(CO)₄](1-Et-CB₁₁F₁₁), a	89
Ru(II) poly(pyridine)s, a	133
Magnetism, Co/Pt nanomultilayers, properties, a	37
effects, on benzene photodegradation	183
D-Mannolactam, synthesis, a	90
Mass Spectrometry, Ru complexes, + PS, + PP, a	88
MEAs, array, high throughput screening, a	91
in fuel cells	28
Mechanical Properties, CoPt, FePd, NiPt, Pd₃Fe, Pt₃Co	46
Pt-Pd-Rh, + Ce, + Ru	111
Medical Uses	87, 92, 109, 136, 187
Membranes, Pd, H₂ permeation	32
Pd alloys, H₂ permeation	32, 166
Pd-Cu, Pd-Y, Pd-In-Ru, H extraction	166
Pd/Ag, reactor, microstructured filament catalyst, a	39
Pd/Ag on α-Al₂O₃, for H separation, a	134
Pd₇₇Ag₂₃, hydrogen diffusion coefficients	32
Pd/Si, Pt/Si, for H separation	166
Memory, capacitors, a	187
Metallabenzenes, platinabenzene, synthesis, a	37
Methane, combustion	13, 90
in NOx reduction	20
sensor	72
Microscopy, electron, in heterogeneous catalysis	110
Microwaves, to prepare, aryl isonipecotic acids, a	186
Pt nanoparticles/C, a	40
in solventless Suzuki couplings, a	134
MOCVD, Ir thin films, a	133
NADH, electrochemical oxidation, a	92
Nanocomposites, Pt-Ru/, Pt-Ru-P/C, electrocatalysts, a	187
Nanomultilayers, Co/Pt, magnetic anisotropy, a	37
Nanoparticles, Pd, phen protected, a	186
Pt, embedded, in C film electrode, a	185
Pt, fuel cell electrocatalysts	28, 40, 136, 187
Nanostructures, LB film, conducting polymer + Ru³⁺, a	134
Pd films	72
Pd₃₀-, Pd₅₄-core, nanosized, synthesis, a	132
Nitric Acid, manufacture	111
Nitrogen, adsorption, Rh(II) benzoate pyrazine, a	88
desorption, from Ir(110), Pd(110), Rh(110), a	37
electroreduction, a	184
Nitrogen Oxides, NO, reaction with NH₃, a	39
scavengers, Ru(III) polyaminocarboxylates, a	136
NOx, catalytic control systems	15, 157
in PM combustion	15, 157
reduction, by CH₄	20
selective catalytic reduction of diesel emissions	157
storage/reduction	13
-traps	15, 96, 157
N₂O, decomposition, a	39
dissociation, on Ir(110), Pd(110), Rh(110), a	37
Nitrosoarenes, reaction with Pd₄(CO)₄(OCOR)₄	20
Nuclear Waste, HLLWs, recovery, of Pd, Rh, Ru	74, 123
Ohmic Contacts, see Electrical Contacts
Oils, engine, additives	140
OLEDs, red, Os(II)(N–N)₂L–L in PVK/PBD, a	38
Olefins, asymmetric dihydroxylation	174
coupling reactions, a	39, 135
hydrogenation, a	40, 134, 186
asymmetric, a	186
oxidation	20
Osmium, recovery and separation	36
Osmium Complexes, electrodes, a	88
Os bpy, in LEDs, a	38
Os(II)(N–N)₂L–L, phosphorescence, a	38
Osmium Compounds, Ba₃LiOs₂O₉, Ba₃NaOs₂O₉, a	132
Oxidation, alcohols	27, 134, 135
aldehydes, a	135
alkanes	20
alkenes	20, 135
alkynes, a	135
arenes, a	135
CO	20
CO/H₂ mixtures, a	90
electro-, EtOH, a	40
H₂, a	187
H₂O₂, a	185
MeOH, a	40, 92, 136, 187
electrochemical, NADH, a	92
ethers, a	135
hydrocarbons	20
NH₃	36, 111
olefins	20
organic pollutants, in H₂O	13
selective, alcohols	20, 185
L-sorbose, a	185
unsaturated compounds	20
using supercritical H₂O, of spent catalysts	163
Oxygen, by photocleavage, photooxidation, of H₂O	2
sensors, a	133
Palladium, addition to, Mg-Ni, for H storage	28
deposition, on dielectric surfaces, a	185
discovery, history	175
electrodeposition	72, 89
electrodes, a	38, 184
in fuel cells, see Fuel Cells
electroless plating, a	133, 134
films, for CH₄ detection	72
hydride phases, video studies	119
interaction with D₂, interaction with H₂	166
membranes	32
overlayers, on Au single crystals, a	184
palladised, Co oxide, Mn oxide, interaction with H₂	166
Pd/Ru/p-GaN ohmic contacts, a	92
Pd(110), N₂O dissociation, a	37
Pd(111), MeOH adsorption, MeOH desorption, a	132
recovery, from nuclear waste	74, 123
from spent catalysts	163
Palladium Alloys, Au-Cu-Pd, phase diagrams	36
Bi₂Pd, intermetallic phase, a	184
capacitors	36
dental, Pd-Ag-Cu-Au, a	187
interaction with D₂, interaction with H₂	166
mechanical properties, FePd, Pd₃Fe	46
Pt-Pd-Rh, + Ce, + Ru	111
membranes	32, 39, 134, 166
Pd-Ni, coatings, for microcantilevers, in H₂ sensor, a	89
Pd/V, MeOH adsorption, MeOH desorption, a	132
Pt-Pd films, macroporous, by CVD, a	185
shape memory effect, Fe-Pd	37, 58
Fe-Pd-Pt, a	37
TiPdNi, a	184
Palladium Complexes, BINAP(O) Pd, synthesis, a	132
clusters, nucleation and growth, on biopolymers	98
[(COD)PdMe(L)]ⁿ⁺, synthesis, a	88
[(COD)PdMe(OH)], hydrolysis reactions, a	88
Me-Pd^II N -heterocyclic, germylenes, silylenes, a	88
Na₂{Pd₄[CpMo(CO)₃]₄}, synthesis	20
[(μ-OH){(COD)PdMe}₂]⁺, hydrolysis reactions, a	88
Pd carbenes, a	39, 88, 184
[Pd₄(CO)₂L₄]X₄, L = bipy, phen, synthesis	20
Pd₄(CO)₄(OAc)₄, Pd₄(CO)₄(OCOR)₄, synthesis	20
[Pd₃₀(CO)₂₆(PEt₃)₁₀], [Pd₅₄(CO)₄₀(PEt₃)₁₄], nano core, a	132
[Pd(C₄H₇)(hfac)], [Pd(hfac)₂], in CVD, a	185
Pd^II(hfac)₂, + reduced S-terminated silanes, a	185
[Pd(HL)Cl₂], HL = thiohydrazone derivatives, a	92
Pd(II), with reducing sugars, a	184
Pd(II) salicylhydroxamates, coordination isomerism, a	184
[Pd(Ln)Cl], Ln = bipy derivatives, luminescence, a	38
Palladium Compounds, Bi₁₄PdBr₁₆, [pdBi₁₀]⁴⁺, a	184
PdO/SnO₂, CO sensitivity, a	185
Patents	41-43, 93-95, 137-139, 188-190
searching of	156
Phase Diagrams, Au-Cu-Pd	36
Pt-Al-Ni, -Al-Ru, -Ti-Ni, -Ti-Ru	142
Phosphorescence, btp₂Ir(acac)	60
electro-, Ir p -substituted 2-phenylpyridines, a	89
Ir(ppy)₃	60
Os(II)(N-N)₂L-L, a	38
Pt(II) diimine bis(pyrenylacetylide), a	133
Photocatalysis, benzene degradation	183
by semiconductors	2, 61
Photocleavage, semiconductor-sensitised, H₂O	2
Photoconversion, a	38, 89, 133, 185
Os bpy, a	38
[Rh(NH₃)₅L]⁴⁺, a	92
Ru bpy, Ru phen, a	38
[Ru(bpy)₂dppz]²⁺, light-switch effect	19
Ru β-diketonato polypyridyls on TiO₂, a	38
Photoluminescence, see Luminescence
Photolysis, laser, Rh(III) porphyrins, a	133
Photomineralisation, organic pollutants, a	61
Photooxidation, semiconductor-sensitised, of H₂O	2
Pholeftroperties, chloro-pgm-, chloro-Pt(IV)-titania	61
[Ir(pik)(phen)Cl₂]⁺, K[Ir(pik)Cl₄], a	185
pgm/TiO₂, pgm oxide/TiO₂	2, 61
trans-[Ru^II(NH₃)₄(SO₂)X]Y, isomerisation of SO₂, a	89
Photoreactions, semiconductor-sensitised	2
Photoreduction, semiconductor-sensitised, of H₂O	2
Photosensitisation, semiconductors	2
Photovoltaic Cell, Pt/C₆₀/In/Al, a	92
Plasma, ion implantation, of Ir-Re coatings, a	38
Plasma Technology, ‘PM-plasmoceramic’ system	36
“Platinum 2003”	122
Platinum, Ag/Pt coated polymers, antibacterial activity	131
in CeO₂ O₂ sensors, a	133
coatings, for scanning microscopy probes, a	38
electrical contacts, Pt, on p -GaN, a	136
electrodes, in fuel cells, see Fuel Cells
films, macroporous, by CVD, a	185
interaction with H₂	166
isoleftes	174
jewellery	36
membranes	166
nanoparticles	28, 40, 136, 185, 187
photovoltaic cell, a	92
Pt(100), Pt(111), reactivity of oximes, a	88
recovery, from spent catalysts	163
ultrathin films, a	89
Platinum Alloys, Co/Pt nanomultilayers, magnetism, a	37
Fe/Pt foils, a	132
interaction with H₂	166
jewellery	36
mechanical properties, CoPt, NiPt, Pt₃Co	46
Pt-Pd-Rh, + Ce, + Ru	111
nanoparticles	28
Pt-Al, -Al-Ni, -Al-Ru, -Cr, -Cu, -Fe, -Ga, -Mn, -Ti, -Ti-Ni, -Ti-Ru, -V	142
Pt-Pd films, macroporous, by CVD, a	185
shape memory effect, Fe-Pd-Pt, a	37
Pt₃Al, PtFe₃, PtTi, (Pt, Ni)Ti	142
Platinum Complexes, cationic porphyrin-Pt, cancer, a	136
clusters, nucleation, growth, on biopolymers, in solution	98
dimers, trimers, formation	98
platinabenzene, synthesis, from [Pt(cod)Cb], a	37
polymeric, a nticancer drugs, a nticancer prodrugs	109
Pt amine hydroxamates, biological activity, a	136
trans-Pt^II-modified PNA oligomers, a ntisense drugs, a	92
Pt(II) diimine pyrenylacetylide, phosphorescence, a	133
Pt(II) salicylhydroxamates, coordination isomerism, a	184
Pt(II) terpyridyl-capped C-rich molecular rods, a	185
[Pt(L)₂Cl₂], HL = thiohydrazone derivatives, a	92
[PtMe₂(COD)], precusor for CVD, a	185
Platinum Compounds, K₂PtCl₄, reduction	98
Pt₆Cl₁₂, structure and bonding, a	132
PtO/SnO₂, CO sensitivity, a	185
Platinum Group Elements,geology book	59
PLEDs, Ir phenylpyridines	60, 89
Pollution Control, in AquaCat^® process	163
dehalogenation of trihalomethanes, a	186
off-gas, from metallurgical, petrochemical plants	20
organics, oxidative degradation, a	135
semiconductor photocatalysis, of air, H₂O	13, 61
see also Emission Control
Polymerisation, living, of phenylacetylenes, a	135
ROMP, a	186
vinyl addition, of norbornene-type monomers, a	40
Polymers, with Ag/Pt coatings, antibacterial activity	131
bio-, nucleation sites, for Pd clusters, Pt clusters	98
-bound ethylenediamines, Pd removal, a	135
conducting, + mer-[RuCl₃(dppb)(py)], LB films, a	134
conjugated star polymers, star block copolymers, a	135
from norbornenedicarboxylic acid ester, by ROMP, a	186
polypropylene, + (RuC₅Me₅)₃H₅, MS, a	88
polypyrrole nanotubules, Pt support, electrocatalysts, a	187
polystyrene, + [Ru(C₅H₅)(NCCH₃)₃][PF₆], MS, a	88
Pt-containing, as anticancer drugs, prodrugs	109
Precipitation, Pd, Rh, Ru	74, 123
Probes, with Pt coating, scanning probe microscopy, a	38
Propylene Oxide, synthesis, a	134
Pyrochemistry, Pd, Rh, Ru	74, 123
Pyrones, alkenylmethyl-, alkynylmethyl-, synthesis, a	91
Quinolinones, synthesis, a	186
Reactors, fixed bed catayst, Pd-zeolite beta spheres, a	90
fluidised bed continuous feeding, a	39
membrane, microstructured by filamentous catalyst, a	39
Recovery, Os	36
Pd, Pt, Rh, from spent catalysts	163
Pd, Rh, Ru, from nuclear waste	74, 123
Reduction, alkynes	44
aromatic amino acid derivatives, a	134
chemical, Pd(II), Rh(III), Ru(IV)	74
electrochemical, Pd(II)	74, 123
electro-, N₂, a	184
NOx	20
Refining, Rh	36
Reforming, H₂ generation, for fuel cells	28, 108
Rhodium, discovery, history	175
electrodeposition, on Ti substrates, a	38
interaction with H₂	166
recovery, from nuclear waste	74, 123
from spent catalysts	163
refining	36
Rh(110), N₂O dissociation, a	37
Rhodium Bicentenary Competition winner, research	73
Rhodium Alloys, Pt-Pd-Rh, + Ce, + Ru	111
Rhodium Complexes, luminescence, a	89
Rh carbenes	73, 184
Rh(II), Rh(III), with bis(oxazoline) pincer ligands, a	132
[Rh₂(O₂CPh)₄(pyz)]_∞, N₂ adsorption, a	88
Rh(II) trifluoroacetamidate, with 4,4’-bipy, 1,4-diaza-bicyclo [2.2.2]octane, pyrazine, as polymers, a	37
[Rh(NH₃)₅L]⁴⁺, photocytotoxic agent, a	92
(x^-)(PPh₃)Rh^III-OEP, -TPP, laser photolysis, a	133
ROMP, norbornenedicarboxylic acid ester, a	186
Ruthenium, addition to, Mg-Ni, for H storage	28
Pt-Pd-Rh, mechanical properties	111
electrodes, a	38, 133, 184
in fuel cells, see Fuel Cells
Pd/Ru/p-GaN ohmic contacts, a	92
recovery, from nuclear waste	74, 123
RuTiN, as diffusion barrier, in memory capacitors, a	187
thin films, by atomic layer deposition, a	133
Ruthenium Alloys, membranes	166
nanoparticles	28
Pt-Al-Ru, Pt-Ti-Ru	142
RuTa, shape memory effect, a	132
Ruthenium Complexes, luminescence, a	89, 133
photoconversion	19, 38
photoproperties, a	89
+ PP, + PS, in mass spectrometry, a	88
Ru carbene, chiral, a	37
Ru carbonyls, by carbonylation of RuCl₃·3H₂O, a	37
[RuCl₂(p-cymene)]₂, reaction with diphosphine, a	37
[Ru^IICl^II(DMSO)₂semicarbazone], Chagas’ disease	87
mer -[RuCl₃(dppb)(py)], in LB films, a	134
RuCp₂, for atomic layer deposition, a	133
Ru(II)-arenes, antimicrobial properties, a	136
Ru(III) polyaminocarboxylates, NO scavengers, a	136
Ruthenium Compounds, electrodes, a	184, 187
[Ru₅C(CO)₁₅], gas sensor activity, a	89
RuCl₃·3H₂O, carbonylation, a	37
[SiW₁₁O₃₉Ru^III(H₂O)]^5-, [SiW₁₁O₃₉Ru^IVORu^IIISiW₁₁O₃₉]^11- a	88
Schottky Barriers, Pt/C₆₀ interface, a	92
SCRT^™, for diesel emission control	157
Selective Catalytic Reduction, NOx	157
Semiconductors, photosensitisation	2, 61
Sensitisers, visible light, chloro-pgm-titania	2, 61
Sensors, acetylcholine, choline, a	185
CH₄	72
CO, a	89, 185
glucose, a	38, 185
H₂	89, 166
H₂O₂, a	185
H₂S, a	89
O₂, a	133
pellistor	72
SO₂, a	89
taste: HCl, NaCl, quinine, sucrose, a	134
Shape Memory Effect, Fe-Pd	37, 58
Fe-Pd-Pt, a	37
Pt₃Al, PtFe₃, PtTi, (Pt, Ni)Ti	142
RuTa, a	132
TiPdNi, a	184
Single Crystals, Ba₃LiOs₂O₉, Ba₃NaOs₂O₉, a	132
Solvent Extraction, Pd, Rh, Ru	74, 123
Sonogashira Couplings, a	91
Sorbitol, from glucose	13
L-Sorbose, oxidation, a	185
Sputtering, Ir-Re coatings, a	38
Pt ultrathin films, a	89
Sugars, Pd(II) complexes, a	184
Sulfur, in diesel, gasoline	96
Sulfur Oxides, SO₂, sensor, a	89
Superelastic Properties, TiPdNi, a	184
Suzuki Couplings, a	39, 91, 134, 135
Suzuki-Miyaura Couplings, a	90, 135
Thermolysis, Pd₄(CO)₄(OCOR)₄	20
Thin Films, Ir, by MOCVD, a	133
Ru, by atomic layer deposition, a	133
ultra-, Pt, on porous GaN, electroless etching, a	89
see also Films
Three-Way Catalysts	13, 15, 96, 157
Titanium, substrates, for electrodeposition of Rh, a	38
TiO₂, deposition, of pgms, pgm oxides	2, 61
Trihalomethanes, dehalogenation, a	186
Ureas, from amines, a	91
5-Vinyloxazolidin-2-ones, carbonylation, a	90
VOCs, destruction, by semiconductor photocatalysis	61
Water, oxidation, photocleavage, photoreduction	2
photocatalytic purification	61
as solvent, for catalytic reactions	60, 174
supercritical, oxidation, of spent catalysts	163
Water Gas Shift Reaction	28, 40
Welding, laser, of dental alloys, a	187

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Subject Index to Volume 47