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Platinum Metals Rev., 2003, 47, (4), 195

Subject Index to Volume 47

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a = abstract
Acetoxylation, oxidative, of alkenes 20
Acetylcholine, sensor, a 185
Acetylenes, phenyl-, living polymerisation, a 135
terminal, Sonogashira couplings, a 91
Actuators, shape memory alloys 58
Air, photocatalytic purification 61
Alcohols, dehydration 20
ethyl, electrooxidation, a 40
in fuel cells 28
methyl, adsorption, desorption, a 132
electrooxidation, a 40, 92, 136, 187
oxidation 27, 134, 135
selective 20, 185
Aldehydes, from alcohols, a 134, 185
oxidation, a 135
Alkanes, dehydrogenation 13, 39
oxidation 20
Alkenes, acetoxylation, alkoxylation, oxidative 20
from alkanes, a 39
from alkynes 44
hydroformylation 14, 91, 135
hydrogenation, a 90, 134, 135
oxidation 20, 135
Alkoxylation, oxidative, of alkenes 20
Alkylation, asymmetric, 1,3-diphenylallylic systems, a 135
Alkynes, intramolecular couplings, a 40
oxidation, a 135
reduction 44
Alloys, dental, a 187
mechanical properties 46, 111
Amination, amino ester + aryl bromides, a 186
Amines, carbonylation, oxidative, a 91
Amino Acids, aromatic, reduction, a 134
Pt clusters, growth 98
Ammonia, oxidation 36, 111
reaction with NO, a 39
Antibacterial Agents, Ag/Pt coated polymers 131
Antimicrobial Agents, Ru(II)-arenes, a 136
Antisense Drugs, trans-PtII-modified PNA oligomers, a AquaCat®, pgm recovery, from spent catalysts 163
Arenes, iodo-, carbonylation, a 40
oxidation, a 135
Aryl Halides, coupling reactions, a 39, 90, 91, 134, 135, 186
Aryl Triflates, Suzuki-Miyaura couplings, a 90
Arylation, intramolecular, of pyrimidines, a 40
Aryldiazonium Salts, cross-coupling reactions, a 39
Autocatalysts 13, 15, 20, 96, 140, 157
Benzene, photodegradation 183
Biomass, gasification, a 39
Biphenyls, by coupling, of substituted halobenzenes, a 39
Book Reviews, “Electron Microscopy in Heterogeneous Catalysis” 110
‘Polymeric platinum-containing drugs in the treatment of cancer’ 109
“Surface Chemistry and Catalysis” 120
“The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of Platinum-Group Elements” 59
Cancer, anti-, pgm complexes 92, 109, 136
Capacitors, HD memory, RuTiN diffusion barrier, a 187
microsuper-, RuO2 electrode, W-RuO2 electrode, a 187
Pd alloy powders 36
Carbenes 37, 39, 73, 88, 184
Carbon Oxides, CO, adsorption energy, a 184
CO/H2 mixtures, oxidation, a 90
for intramolecular alkyne–alkyne couplings, a 40
oxidation 20
poisoning, in PEMFC 107
sensors, a 89, 185
tolerance, in PEMFC, a 91
CO2, production, in benzene photodegradation 183
solvent, a 91, 34
Carbonylation, iodoarenes, a 40
oxidative, amines, a 91
RuCl3·3H2O, to Ru carbonyls, a 37
5-vinyloxazolidin-2-ones, a 90
Carbonyls, Pd(+1) clusters, as catalysts 20
[Rh(CO)4]+, luminescence, a 89
Ru, from RuCl3·3H2O, a 37
Carboxylic Acids, aryl, thermolysis of Pd4(CO)4(OAc)4 20
from alcohols, a 185
hydrogenation, a 90
Catalysis, book reviews 110, 120
in CO2 solvent, a 91, 34
conferences 13, 28
electron microscopy, use of 110
in H2O solvent 60, 174
heterogeneous, a 39, 90, 134, 185–86
history 175
homogeneous, a 39–40, 90–91, 134–135, 186
surface chemistry 120
Catalysts, agglomeration 44
deactivation 13, 44
metal loss 44
model 120
pgm, supported single crystals 120
poisoning, chemical, physical 44
recycling 13, 39, 134, 186
Selectra Shift, for reformer 28
spent, precious metal recovery 163
three-way, see Three-Way Catalysts
Catalysts, Iridium, Ir, in lean-burn gasoline engine 157
Ir/SrTiO3, H2O photocleavage 2
Ir/TiO2, H2O photooxidation 2
Ir(0) nanoclusters, cyclohexene hydrogenation, a 135
Catalysts, Iridium Complexes, cyclooctadienylIr(I) hexafluoropentanedionate, D labelling, a 186
Ir-HetPHOX, asymmetric hydrogenations, a 186
IrCl(CO)(PPh3)2, alkyne–alkyne couplings, a 40
Vaska’s complex, alkyne–alkyne couplings, a 40
Catalysts, Osmium, Os/SrTiO3, H2O photocleavage 2
Catalysts, Osmium Complexes, OsO4/polymer 174
PVI-Os(dpa)2Cl, with diaphorase, a 92
Catalysts, Palladium, APK-2/α-Al2O3, NOx conversion 20
electrocatalysts, PtPd/C 28, 91
Lindlar’s catalyst, reduction of alkynes 44
palladised metal(IV) phosphates, hydrogenations, a 90
Pd, HC emission oxidation 157
nanostructured, in pellistor sensors 72
supported, CH4 combustion, a 90
Pd clusters/Sibunit, hydrocarbon oxidation 20
Pd clusters/spherical SiO2 particles, CO, HC, oxidation 20
Pd nanoparticles, hydrogenation of olefins, a 134, 186
phen protected, a 186
Pd powder, + KF/Al2O3, solventless Suzuki coupling, a 134
Pd-Cu/C, thermal treatments 110
Pd-Fe, dehalogenation of trihalomethanes, a 186
Pd-zeolite beta spheres, preparation, a 90
Pd/Al2O3, CH4 combustion, S poisoning 13
sintering mechanisms 110
Pd/C, + NaCl, for debenzylation, a 186
spent, Pd recovery 163
+ tetrabutylammonium bromide, biphenyl synthesis, a 39
Pd/CaCO3 + Pb, reduction of alkynes 44
Pd/Rh, TWC, high thermal durability 15
Pd/SrTiO3, H2O photocleavage 2
Pd/Ti silicalite, synthesis of propylene oxide, a 134
Pd/TiO2, H2O photoreduction 2
H2O purification 61
STM studies 13
Pd4(CO)4(OCOR)4 + bipy/oxide carrier, oxidations 20
NOx reduction, by CH4 20
Pd4(CO)4(OCOR)4 + phen/α-Al2O3, NOx conversion 20
Pd4(CO)4(OCOR)4 + phen/oxide carrier, oxidations 20
NOx reduction, by CH4 20
Pt/Pd/Rh, TWC, pgm loading 157
TiO2-Pd(II) chloride 61
Catalysts, Palladium Complexes,3-allyl)Pd, addition
polymerisation of norbornene-type monomers, a 40
monocarbenepalladium(0), coupling reactions, a 39
Na{Pd4[CpMo(CO)3]4}, dehydration of alcohols 20
PAMAM dendrimer-Pd(RcN)2Cl2/SiO2, -Pd(tetra-methylethylenediamine)Me2/SiO2, a 40
Pd(+1) carbonyl clusters, oxidations 20
Pd with P,N -ferrocenyl ligands, allylic alkylation, a 135
Pd-dendrimer nanocomposites, olefin hydrogenation, a 40
Pd-phosphine-PS-PEG resin, reactions in H2O 60
Pd/C + PPh3, Sonogashira coupling, a 91
Pd2(dba)3/BINAP/NaOt Bu, coupling amination, a 186
Pd4(CO)4(OCOR)4/bipy, /phen, olefin oxidation 20
PdCl2/HP(adamantyl)2, /HP(t -butyl)2, Heck reactions, a 39
PdCl2(dppf), Suzuki coupling, solid phase, a 135
PdCl2(dppf)·CH2Cl2/Cs2CO3, S.-M. coupling, a 90
PdCl2(PPh3)2, preparation of δ-lactam, a 90
Suzuki-Miyaura coupling, a 135
PdI2 + KI, oxidative carbonylation of amines, a 91
Pd(OAc)2, in TBAB-H2O, Suzuki coupling, a 91
Pd(OAc)2 + NBu3/P(o -tolyl)3, Heck reaction, a 91
Pd(OAc)2/PPh3, Sonogashira coupling, a 91
Pd(OAc)2/PPh3/NEt4Cl/K2CO3, cyclisations, a 186
Pd(OAc)2/PPh3/TlOAc, cyclisations, a 186
Pd(OAc)2(PPh3)2 + base, arylation, intramolecular, a 40
Pd(PPh3)4, Sonogashira coupling, a 91
removal, by polymer-bound ethylenediamines, a 135
Catalysts, Platinum, electrocatalysts, nanoparticles, Pt, on C, for DMFC, a 40
Pt, on C, Ru deposition, MeOH oxidation, a 136
Pt, on polypyrrole nanotubules, for fuel cells a 187
Pt, Pt-Ru, spheres, on C 28
Pt, for fuel cells 28, 40, 135, 136, 187
Pt/carbon-CH2CH2PO3H2, for PEMFCs, a 135
Pt, + Cr, Fe, Mn, Mo, Pd, for fuel cells 28
Pt/Ni, for DMFCs, a 187
PtPd4/C, for PEMFCs, a 91
PtRh, EtOH electrooxidation, a 40
PtRu, for fuel cells 28, 92, 107, 136, 187
PtRuMo, for PEMFCs, reactivity imaging 107
Pt-Ru-P/C nanocomposites, anodes, for DMFCs, a 187
HPS-Pt-THF, direct L-sorbose oxidation, a 185
platinised metal(IV) phosphates, hydrogenations, a 90
Pt, addition, Ru-Sn/active C, hydrogenations, a 90
in autocatalysts, emission control: diesel, gasoline, lean-burn gasoline 15, 157
filter, aldehydes, CO, HC conversion, from diesel 157
ceramic foam, PM removal, from diesel emissions 157
PM, from diesel emissions 15, 157
HC + NOx 157
oxidation, CO, HC, NO 157
MeOH, a 136
NOx-traps 15, 157
with Ru/C, hydrogenation of glucose to sorbitol 13
Pt, Bi/C, N2O decomposition, a 39
Pt, Bi/C, 1-octanol to octanoic acid, a 185
2-octanol to 2-octanone, a 185
Pt-Rh/SiO2, heat treatment; under N2 110
Pt-Ru-Sn/active C, hydrogenations, a 90
Pt-Sn-K/, Pt-Sn-K-Fe/Al2O3, dehydrogenations, a 39
Pt–WOx, MeOH oxidation, a 136
Pt/Al2O3, butane dehydrogenation 13
CCl4 hydrodechlorination, a 90
CH4 combustion, S poisoning 13
sintering mechanisms 110
Pt/Al2O3-coated monolith, oxidation of CO/H2, a 90
Pt/B/TiO2, H2O photocleavage 2
Pt/Ba + Rh, NOx storage/reduction 13
Pt/C, N2O decomposition, a 39
spent, Pt recovery 163
Pt/fluorinated C, NO + NH3, a 39
Pt/Pd/Rh, TWC, pgm loading 157
Pt/polypyrrole, electrooxidation of MeOH, a 187
Pt/Rh, TWC, high thermal durability 15
Pt/’RuO2’/TiO2, H2O photocleavage 2
Pt/’RuO2’/TiO2 doped with Cr, H2O photocleavage 2
Pt/SiO2, hydrogenation, of ethene, ethyne, a 134
Pt/Sn/Al2O3 filaments, a 39
Pt/SrTiO3, H2O photocleavage 2
Pt/TiO2, air purification 61
benzene photodegradation, magnetic field effects 183
H2O, photocleavage, photoreduction, purification 2, 61
Pt/TiO2/SiO2, H2O photoreduction 2
Pt/WO3, H2O photooxidation 2
Ru, Pt/C, oxidation of alcohols, a 185
TiO2-Pt(IV) chloride, H2O purification 61
Catalysts, Rhodium, autocatalysts, NOx reduction 13, 157
Pd/Rh, TWC, high thermal durability 15
Pt-Rh/SiO2, heat treatment; under N2 110
Pt/Pd/Rh, TWC, pgm loading 157
Pt/Rh, TWC, high thermal durability 15
PtRh, EtOH electrooxidation, a 40
Rh, EtOH electrooxidation, a 40
Rh/Al2O3, CH4 combustion, S poisoning 13
reduction of aromatic amino acid derivatives, a 134
Rh/C, reduction of aromatic amino acid derivatives, a 134
Rh/CeO2/SiO2, biomass gasification, a 39
Rh/TiO2, H2O, photooxidation, photoreduction 2
STM studies 13
Rh/WO3, H2O photooxidation 2
TiO2-Rh(III) chloride 61
Catalysts, Rhodium Complexes, [(cod)RhL’Cl] 73
[(nbd)RhCl]2/PH2C=C(Ph)Li/Ph3P, polymerisation, a 135
Rh with P,N -ferrocenyl ligands, hydroboration, a 135
Rh POSS dendrimers, oct-1-ene hydroformylation 14
[RH2(OAc)4]/phosphines, hydroformylation in sc-CO2, a 91
RH2[(R)-DDBNP]4, RH2[(S )-DOSP]4, a 91
Rh(bpy)33+/TiO2, H2O photoreduction 2
[RhCl(cod)]2, alkyne-alkyne couplings, a 40
[Rh(L-L)NBD]BF4/Nafion, hydroformylation, a 135
[Rh(L)2NBD]BF4/Nafion, hydroformylation, a 135
Catalysts, Ruthenium, Cu-Ru/C, CO, H2 treatments 110
electrocatalysts, PtRu, for fuel cells 28, 92, 107, 136, 187
PtRuMo, for PEMFCs, reactivity imaging 107
Ru-Se, for fuel cells 28
Pt-Ru-Sn/active C, hydrogenation of carboxylic acids, a 90
Pt/’RuO2’/TiO2, H2O photocleavage 2
Pt/’RuO2’/TiO2 doped with Cr, H2O photocleavage 2
Ru, Pt/C, oxidation of alcohols, a 185
RuIV-CoIII oxide, oxidation of alcohols, a 134
Ru-Sn/active C, hydrogenation of carboxylic acids, a 90
Ru/Al2O3, oxidation of alcohols 27
Ru/C cathode, electroreduction of N2, a 184
with Pt, hydrogenation of glucose to sorbitol 13
Ru/SrTiO3, H2O photocleavage 2
Ru/TiO2, H2O photooxidation 2
oxidation of organic pollutants, in H2O 13
Ru/WO3, H2O photooxidation 2
‘RuO2’/BaTi4O9, H2O photocleavage 2
‘RuO27In1-xNixTaO4, H2O photocleavage 2
RuO2/WO3, H2O photooxidation 2
RuO2·xH2O/WO3, H2O photooxidation 2
Catalysts, Ruthenium Complexes, Grubbs catalysts, a 186
Ru benzylidenes, ROMP, a 186
Ru bipy, Ru phen, WGSR, a 40
RuO4, oxidations, in dimethyl carbonate-H2O, a 135
CCRT, for diesel emission control 15, 157
Cerium, addition to, Pt-Pd-Rh, mechanical properties 111
Chagas’ Disease, Ru complexes 87
Chemical Vapour Deposition, macroporous films, a 185
Chemiluminescence, see Luminescence
Chlorate, electrolysis, a 133
Choline, sensor, a 185
Chromatography, Pd, Rh, Ru 123
CHT, for gasoline emission control 15, 157
Clusters, Pd(+1) carbonyls, as catalysts 20
Pd, nucleation and growth, on biopolymers 98
[PdBi10]4+, a 184
Pt, nucleation and growth, on biopolymers 98
in solution 98
[Ru5C(CO)15], gas sensor activity, a 89
Coatings, Ag/Pt, on polymers, antibacterial activity 131
Ir-Re, by plasma-based ion implantation, a 38
Pd-Ni, for microcantilevers, in H2 sensor, a 89
Pt, for cantilevers, in scanning microscopy probes, a 38
see also Deposition and Electrodeposition
Combinatorial Chemistry, fuel cell cataysts 107
Suzuki couplings, a 135
use of K alkenyltrifluoroborates, a 90
Combustion, CH4 13, 90
Conferences, 4th Noble and Rare Metals: NRM-2003, Donetsk, Ukraine, 2003 36
8th Grove Fuel Cell Symposium, London, 2003 31
Catalyst Life Cycle, University of Bath, U.K., 2002 13
Fuel Cells – Science and Technology 2002, Amsterdam, 2002 28
Hannover Messe, Hydrogen + Fuel Cells, 2003 108
IFSSEHT-2003, Sarov, Russia, 2003 166
SAE, Detroit, U.S.A. 15, 157
Coupling Reactions 39, 40, 73, 186
see also Heck Reactions and Suzuki Couplings
Creep, -rupture curves, Pt-Pd-Rh, + Ce, + Ru 111
CRT, for diesel emission control 15, 96, 157
Cyclisation, to pyrazolidines, a 186
Cyclometallates, Pd phenylbipyridines, luminescence, a 38
L-Cysteine, determination of, a 89
L-Cystine, determination of, a 89
Debenzylation, in synthesis of quinolinones, a 186
Decomposition, N2O, a 39
Dehalogenation, trihalomethanes, a 186
Dehydration, alcohols 20
Dehydrogenation, alkanes 13, 39
Dendrimers, as catalysts 14, 40
Dental, alloys, a 187
Deoxymannojirimycin, synthesis, a 90
Deposition, Pd, on dielectric surfaces, a 185
see also Coatings and Electrodeposition
Deuterium, interaction with Pd, Pd alloys 166
labelling, a nilines, benzylamines, N heterocycles, a 186
Diacyls, from thermolysis of Pd4(CO)4(OCOR)4 20
Diesel, particulate filters, for emissions control 15, 96, 157
PM, control, by CCRT 15, 157
by CRT
15, 96, 157
by EGR-CRT 157
by SCRT 157
S content 96
Dihydroxylation, asymmetric, olefins 174
Dispersion Hardening, of alloys, for glass production 36
Displacive Transformations, Pt alloys 142
DNA, Pt clusters, growth 98
EGR-CRT, for diesel emission control 157
Electrical Contacts, ohmic, Pd/Ru/p-GaN, a 92
Pt, on p-GaN, a 136
Electrochemistry, a 88, 133, 184
oximes, on Pt(100) surfaces, on Pt(111) surfaces, a 88
[SiW11O39RuIII(H2O)]5–, a 88
[SiW11O39RuIVORuIIISiW11O39]11–, a 88
Electrodeposition, Pd, codeposition of H, a 89
films, nanostructured, on Si 72
on Ni, a 89
Rh, on Ti substrates, a 38
see also Coatings and Deposition
Electrodeposition and Surface Coatings, a 38, 89, 133, 185
Electrodes, C paste, Ir, + Cu, Pd, Ru, in glucose sensor, a 38
FePO4, + RuO2, for Li cells, a 184
in fuel cells, see Fuel Cells
[Os(bpy)2(bpy-(CH2)13SH)]2+/Au, with ascorbic acid, a 88
with dopamine, a 88
Pd/C, anode, in electroreduction of N2, a 184
Pt nanoparticles, embedded, in C film, a 185
Ru-based DSA®, chlorate electrolysis, a 133
Ru/C, cathode, in electroreduction of N2, a 184
RuO2, W-RuO2, in microsupercapacitors, a 187
Ti/IrO2-TaO5, microstructure, a 88
Electroless Plating, Pd, on α-Al2O3, a 134
on TiN barrier films, for electroless Cu, a 133
Electrolysis, chlorate, a 133
Emission Control, motor vehicles 13, 15, 96, 140, 157
Etching, Pt ultrathin films, a 89
Ethers, oxidation, a 135
Films, Pd, on Au single crystals, a 184
nanostructured 72
Pt, Pt-Pd, macroporous, by CVD, a 185
Ru β-diketonato polypyridyls on TiO2, a 38
see also Thin Films
‘Final Analysis’ 44, 96, 140
Foils, Fe/Pt, a 132
Fracture, brittle, in Ir, Ir alloys 36
in Pt-Pd-Rh alloys, Ce addition, Ru addition 111
Fuel Cells, a 40, 91–92, 135–136, 187
bio-, anodes, a 92
catalysts, Pt nanoparticles/C, + Ru deposition, a 136
Pt/C, PtRu/C, MeOH electrochemical oxidation, a 136
conferences 28, 31, 108
direct 2-propanol fuel cell 28
DMFC, anodes, Pt-Ru/, Pt-Ru-P/C, nanocomposites, a 187
cathode, Ru-Se 28
electrocatalysts, high throughput screening, a 91
Pt/polypyrrole, a 187
Pt nanoparticles/polypyrrole nanotubules, a 187
Pt/Ni, a 187
Pt-Ru/mesocarbon microbead support, a 92
electrodes, a 40
MEAs, a 91
electrodes, Pt, Pt–WOx, MeOH oxidation, a 136
fuel, H2 28, 108, 119, 166
low temperature, electrocatalysts, Pt/C, a 187
MCFC, with gas turbines 28
membrane electrode assemblies 28, 91
nanoparticles 28, 40, 136, 187
PEMFC, CO poisoning 107
CO tolerance, a 91
electrocatalysts, Pt, Pt alloys 28, 135
Pt nanoparticles/polypyrrole nanotubules, a 187
Pt/carbon-CH2CH2PO3H2, a 135
PtPd4/C, a 91
PtRu, PtRuMo, reactivity imaging 107
Pt-Ru/C, a 92
electrodes, Pt 107, 108
MEAs 28
as power sources, for camcorder 108
for fork-lift truck 108
for public transport 108
for video camera 108
SOFC, with gas turbines 28
Gasification, biomass, a 39
Gasoline, S content 96
Gauzes, NH3 oxidation 36, 111
Geology, book 59
Glass, production, using dispersion hardened alloys 36
Glucose, hydrogenation 13
sensors, a 38, 185
Gorsky Effect, on H diffusion coefficients, in Pd77Ag23 32
Heck Reactions, a 39, 91
Heterocycles, synthesis, a 40
High Throughput Screening, fuel cell catalysts 91, 107
History, Enrico Fermi 167
Ir isotopes, discoverers 167
Pd discovery, uses 175
Rh discovery, uses 175
Smithson Tennant 175
William Hyde Wollaston, Wollaston Medal 175
Hydroboration, styrene, with catechol borane, a 135
Hydrocarbons, emission control 15, 96, 157
hydrogenation, a 134
oxidation 20
reforming 28, 108
Hydrodechlorination, CCl4, a 90
Hydroformylation, alkenes 14, 91, 135
Hydrogen, atomic, adsorption energy, a 184
by photocleavage, photoreduction, of H2O 2
CO/H2 mixtures, oxidation, a 90
codeposited, in Pd electrodeposition, a 89
diffusion coefficents, in Pd77Ag23 membranes 32
economy 166
electrooxidation, a 187
extraction 166
fuel, for fuel cells 28, 108, 119, 166
interaction, with Pd, Pd alloys, Pt, Pt alloys, Rh 166
with Pd, hydride phases, video studies 119
purification 32
safety 166
sensors 89, 166
separation, from gases 134, 166
transport 166
Hydrogen Peroxide, electrooxidation, a 185
sensor, a 185
Hydrogen Sulfide, sensor, a 89
Hydrogenation, alkenes, a 90, 134, 135
asymmetric, imines, olefins, a 186
carboxylic acids, a 90
ethyne, a 134
glucose 13
hydrocarbons, a 134
olefins, a 40, 134, 186
Imines, hydrogenation, asymmetric, a 186
Ion Exchange, Pd ions, Rh ions, Ru ions 74, 123
Ionic Liquids, solvents, a 186
Iridium, brittle fracture 36
for C paste electrodes, a 38
Ir(110), N2O dissociation, a 37
isotopes, history of the discoveries 167
thin films, by MOCVD, a 133
Iridium Alloys, brittle fracture 36
Ir-Re coatings, by plasma-based ion implantation, a 38
Iridium Complexes, cyclometallation-induced formation of M–C bonds to sp2 C of aryl and vinyl groups 73
Ir carbenes 73, 184
Ir(COD)(MeCp), for MOCVD, a 133
[Ir(pik)(phen)Cl2]+, luminescence, a 185
K[Ir(pik)Cl4], spectral properties, a 185
phosphorescence 6, 89
Iridium Compounds, electrodes, a 88
Isocyanides, for alkyne–alkyne couplings, a 40
Isomerism, coordination, M(II) salicylhydroxamates, a 184
Isotopes, detector, double-sided silicon strip 167
Ir, discoveries 167
Jewellery, Pt, Pt alloys 36
Johnson Matthey, AquaCat® 163
Catalysts division, ECT, PCT 121
emission control, motor vehicles 15, 96, 157
FP05 prototype reformer 28
“Platinum 2003” 122
‘Platinum Today’ website 121
Johnson, Percival Norton 175
Ketones, synthesis, a 91, 185
Labelling, D2, anilines, benzylamines, N heterocycles, a 186
Langmuir-Bodgett Films, conducting polymer/Ru3+, a 134
Lasers, welding, of dental alloys, a 187
LEDs, Os bpy, Ru bpy, Ru phen, a 38
Luminescence, chemi-, Ru(bipy)32+, a 89
cyclometallated Pd(II) complexes, a 38
[Ir(pik)(phen)Cl2]+, a 185
Pt(II) terpyridyl-capped C-rich molecular rods, a 185
[Rh(CO)4]+, [Rh(CO)4](1-Et-CB11F11), a 89
Ru(II) poly(pyridine)s, a 133
Magnetism, Co/Pt nanomultilayers, properties, a 37
effects, on benzene photodegradation 183
D-Mannolactam, synthesis, a 90
Mass Spectrometry, Ru complexes, + PS, + PP, a 88
MEAs, array, high throughput screening, a 91
in fuel cells 28
Mechanical Properties, CoPt, FePd, NiPt, Pd3Fe, Pt3Co 46
Pt-Pd-Rh, + Ce, + Ru 111
Medical Uses 87, 92, 109, 136, 187
Membranes, Pd, H2 permeation 32
Pd alloys, H2 permeation 32, 166
Pd-Cu, Pd-Y, Pd-In-Ru, H extraction 166
Pd/Ag, reactor, microstructured filament catalyst, a 39
Pd/Ag on α-Al2O3, for H separation, a 134
Pd77Ag23, hydrogen diffusion coefficients 32
Pd/Si, Pt/Si, for H separation 166
Memory, capacitors, a 187
Metallabenzenes, platinabenzene, synthesis, a 37
Methane, combustion 13, 90
in NOx reduction 20
sensor 72
Microscopy, electron, in heterogeneous catalysis 110
Microwaves, to prepare, aryl isonipecotic acids, a 186
Pt nanoparticles/C, a 40
in solventless Suzuki couplings, a 134
MOCVD, Ir thin films, a 133
NADH, electrochemical oxidation, a 92
Nanocomposites, Pt-Ru/, Pt-Ru-P/C, electrocatalysts, a 187
Nanomultilayers, Co/Pt, magnetic anisotropy, a 37
Nanoparticles, Pd, phen protected, a 186
Pt, embedded, in C film electrode, a 185
Pt, fuel cell electrocatalysts 28, 40, 136, 187
Nanostructures, LB film, conducting polymer + Ru3+, a 134
Pd films 72
Pd30-, Pd54-core, nanosized, synthesis, a 132
Nitric Acid, manufacture 111
Nitrogen, adsorption, Rh(II) benzoate pyrazine, a 88
desorption, from Ir(110), Pd(110), Rh(110), a 37
electroreduction, a 184
Nitrogen Oxides, NO, reaction with NH3, a 39
scavengers, Ru(III) polyaminocarboxylates, a 136
NOx, catalytic control systems 15, 157
in PM combustion 15, 157
reduction, by CH4 20
selective catalytic reduction of diesel emissions 157
storage/reduction 13
-traps 15, 96, 157
N2O, decomposition, a 39
dissociation, on Ir(110), Pd(110), Rh(110), a 37
Nitrosoarenes, reaction with Pd4(CO)4(OCOR)4 20
Nuclear Waste, HLLWs, recovery, of Pd, Rh, Ru 74, 123
Ohmic Contacts, see Electrical Contacts
Oils, engine, additives 140
OLEDs, red, Os(II)(N–N)2L–L in PVK/PBD, a 38
Olefins, asymmetric dihydroxylation 174
coupling reactions, a 39, 135
hydrogenation, a 40, 134, 186
asymmetric, a 186
oxidation 20
Osmium, recovery and separation 36
Osmium Complexes, electrodes, a 88
Os bpy, in LEDs, a 38
Os(II)(N–N)2L–L, phosphorescence, a 38
Osmium Compounds, Ba3LiOs2O9, Ba3NaOs2O9, a 132
Oxidation, alcohols 27, 134, 135
aldehydes, a 135
alkanes 20
alkenes 20, 135
alkynes, a 135
arenes, a 135
CO 20
CO/H2 mixtures, a 90
electro-, EtOH, a 40
H2, a 187
H2O2, a 185
MeOH, a 40, 92, 136, 187
electrochemical, NADH, a 92
ethers, a 135
hydrocarbons 20
NH3 36, 111
olefins 20
organic pollutants, in H2O 13
selective, alcohols 20, 185
L-sorbose, a 185
unsaturated compounds 20
using supercritical H2O, of spent catalysts 163
Oxygen, by photocleavage, photooxidation, of H2O 2
sensors, a 133
Palladium, addition to, Mg-Ni, for H storage 28
deposition, on dielectric surfaces, a 185
discovery, history 175
electrodeposition 72, 89
electrodes, a 38, 184
in fuel cells, see Fuel Cells
electroless plating, a 133, 134
films, for CH4 detection 72
hydride phases, video studies 119
interaction with D2, interaction with H2 166
membranes 32
overlayers, on Au single crystals, a 184
palladised, Co oxide, Mn oxide, interaction with H2 166
Pd/Ru/p-GaN ohmic contacts, a 92
Pd(110), N2O dissociation, a 37
Pd(111), MeOH adsorption, MeOH desorption, a 132
recovery, from nuclear waste 74, 123
from spent catalysts 163
Palladium Alloys, Au-Cu-Pd, phase diagrams 36
Bi2Pd, intermetallic phase, a 184
capacitors 36
dental, Pd-Ag-Cu-Au, a 187
interaction with D2, interaction with H2 166
mechanical properties, FePd, Pd3Fe 46
Pt-Pd-Rh, + Ce, + Ru 111
membranes 32, 39, 134, 166
Pd-Ni, coatings, for microcantilevers, in H2 sensor, a 89
Pd/V, MeOH adsorption, MeOH desorption, a 132
Pt-Pd films, macroporous, by CVD, a 185
shape memory effect, Fe-Pd 37, 58
Fe-Pd-Pt, a 37
TiPdNi, a 184
Palladium Complexes, BINAP(O) Pd, synthesis, a 132
clusters, nucleation and growth, on biopolymers 98
[(COD)PdMe(L)]n+, synthesis, a 88
[(COD)PdMe(OH)], hydrolysis reactions, a 88
Me-PdII N -heterocyclic, germylenes, silylenes, a 88
Na2{Pd4[CpMo(CO)3]4}, synthesis 20
[(μ-OH){(COD)PdMe}2]+, hydrolysis reactions, a 88
Pd carbenes, a 39, 88, 184
[Pd4(CO)2L4]X4, L = bipy, phen, synthesis 20
Pd4(CO)4(OAc)4, Pd4(CO)4(OCOR)4, synthesis 20
[Pd30(CO)26(PEt3)10], [Pd54(CO)40(PEt3)14], nano core, a 132
[Pd(C4H7)(hfac)], [Pd(hfac)2], in CVD, a 185
PdII(hfac)2, + reduced S-terminated silanes, a 185
[Pd(HL)Cl2], HL = thiohydrazone derivatives, a 92
Pd(II), with reducing sugars, a 184
Pd(II) salicylhydroxamates, coordination isomerism, a 184
[Pd(Ln)Cl], Ln = bipy derivatives, luminescence, a 38
Palladium Compounds, Bi14PdBr16, [pdBi10]4+, a 184
PdO/SnO2, CO sensitivity, a 185
Patents 41-43, 93-95, 137-139, 188-190
searching of 156
Phase Diagrams, Au-Cu-Pd 36
Pt-Al-Ni, -Al-Ru, -Ti-Ni, -Ti-Ru 142
Phosphorescence, btp2Ir(acac) 60
electro-, Ir p -substituted 2-phenylpyridines, a 89
Ir(ppy)3 60
Os(II)(N-N)2L-L, a 38
Pt(II) diimine bis(pyrenylacetylide), a 133
Photocatalysis, benzene degradation 183
by semiconductors 2, 61
Photocleavage, semiconductor-sensitised, H2O 2
Photoconversion, a 38, 89, 133, 185
Os bpy, a 38
[Rh(NH3)5L]4+, a 92
Ru bpy, Ru phen, a 38
[Ru(bpy)2dppz]2+, light-switch effect 19
Ru β-diketonato polypyridyls on TiO2, a 38
Photoluminescence, see Luminescence
Photolysis, laser, Rh(III) porphyrins, a 133
Photomineralisation, organic pollutants, a 61
Photooxidation, semiconductor-sensitised, of H2O 2
Pholeftroperties, chloro-pgm-, chloro-Pt(IV)-titania 61
[Ir(pik)(phen)Cl2]+, K[Ir(pik)Cl4], a 185
pgm/TiO2, pgm oxide/TiO2 2, 61
trans-[RuII(NH3)4(SO2)X]Y, isomerisation of SO2, a 89
Photoreactions, semiconductor-sensitised 2
Photoreduction, semiconductor-sensitised, of H2O 2
Photosensitisation, semiconductors 2
Photovoltaic Cell, Pt/C60/In/Al, a 92
Plasma, ion implantation, of Ir-Re coatings, a 38
Plasma Technology, ‘PM-plasmoceramic’ system 36
“Platinum 2003” 122
Platinum, Ag/Pt coated polymers, antibacterial activity 131
in CeO2 O2 sensors, a 133
coatings, for scanning microscopy probes, a 38
electrical contacts, Pt, on p -GaN, a 136
electrodes, in fuel cells, see Fuel Cells
films, macroporous, by CVD, a 185
interaction with H2 166
isoleftes 174
jewellery 36
membranes 166
nanoparticles 28, 40, 136, 185, 187
photovoltaic cell, a 92
Pt(100), Pt(111), reactivity of oximes, a 88
recovery, from spent catalysts 163
ultrathin films, a 89
Platinum Alloys, Co/Pt nanomultilayers, magnetism, a 37
Fe/Pt foils, a 132
interaction with H2 166
jewellery 36
mechanical properties, CoPt, NiPt, Pt3Co 46
Pt-Pd-Rh, + Ce, + Ru 111
nanoparticles 28
Pt-Al, -Al-Ni, -Al-Ru, -Cr, -Cu, -Fe, -Ga, -Mn, -Ti, -Ti-Ni, -Ti-Ru, -V 142
Pt-Pd films, macroporous, by CVD, a 185
shape memory effect, Fe-Pd-Pt, a 37
Pt3Al, PtFe3, PtTi, (Pt, Ni)Ti 142
Platinum Complexes, cationic porphyrin-Pt, cancer, a 136
clusters, nucleation, growth, on biopolymers, in solution 98
dimers, trimers, formation 98
platinabenzene, synthesis, from [Pt(cod)Cb], a 37
polymeric, a nticancer drugs, a nticancer prodrugs 109
Pt amine hydroxamates, biological activity, a 136
trans-PtII-modified PNA oligomers, a ntisense drugs, a 92
Pt(II) diimine pyrenylacetylide, phosphorescence, a 133
Pt(II) salicylhydroxamates, coordination isomerism, a 184
Pt(II) terpyridyl-capped C-rich molecular rods, a 185
[Pt(L)2Cl2], HL = thiohydrazone derivatives, a 92
[PtMe2(COD)], precusor for CVD, a 185
Platinum Compounds, K2PtCl4, reduction 98
Pt6Cl12, structure and bonding, a 132
PtO/SnO2, CO sensitivity, a 185
Platinum Group Elements,geology book 59
PLEDs, Ir phenylpyridines 60, 89
Pollution Control, in AquaCat® process 163
dehalogenation of trihalomethanes, a 186
off-gas, from metallurgical, petrochemical plants 20
organics, oxidative degradation, a 135
semiconductor photocatalysis, of air, H2O 13, 61
see also Emission Control
Polymerisation, living, of phenylacetylenes, a 135
ROMP, a 186
vinyl addition, of norbornene-type monomers, a 40
Polymers, with Ag/Pt coatings, antibacterial activity 131
bio-, nucleation sites, for Pd clusters, Pt clusters 98
-bound ethylenediamines, Pd removal, a 135
conducting, + mer-[RuCl3(dppb)(py)], LB films, a 134
conjugated star polymers, star block copolymers, a 135
from norbornenedicarboxylic acid ester, by ROMP, a 186
polypropylene, + (RuC5Me5)3H5, MS, a 88
polypyrrole nanotubules, Pt support, electrocatalysts, a 187
polystyrene, + [Ru(C5H5)(NCCH3)3][PF6], MS, a 88
Pt-containing, as anticancer drugs, prodrugs 109
Precipitation, Pd, Rh, Ru 74, 123
Probes, with Pt coating, scanning probe microscopy, a 38
Propylene Oxide, synthesis, a 134
Pyrochemistry, Pd, Rh, Ru 74, 123
Pyrones, alkenylmethyl-, alkynylmethyl-, synthesis, a 91
Quinolinones, synthesis, a 186
Reactors, fixed bed catayst, Pd-zeolite beta spheres, a 90
fluidised bed continuous feeding, a 39
membrane, microstructured by filamentous catalyst, a 39
Recovery, Os 36
Pd, Pt, Rh, from spent catalysts 163
Pd, Rh, Ru, from nuclear waste 74, 123
Reduction, alkynes 44
aromatic amino acid derivatives, a 134
chemical, Pd(II), Rh(III), Ru(IV) 74
electrochemical, Pd(II) 74, 123
electro-, N2, a 184
NOx 20
Refining, Rh 36
Reforming, H2 generation, for fuel cells 28, 108
Rhodium, discovery, history 175
electrodeposition, on Ti substrates, a 38
interaction with H2 166
recovery, from nuclear waste 74, 123
from spent catalysts 163
refining 36
Rh(110), N2O dissociation, a 37
Rhodium Bicentenary Competition winner, research 73
Rhodium Alloys, Pt-Pd-Rh, + Ce, + Ru 111
Rhodium Complexes, luminescence, a 89
Rh carbenes 73, 184
Rh(II), Rh(III), with bis(oxazoline) pincer ligands, a 132
[Rh2(O2CPh)4(pyz)], N2 adsorption, a 88
Rh(II) trifluoroacetamidate, with 4,4’-bipy, 1,4-diaza-bicyclo [2.2.2]octane, pyrazine, as polymers, a 37
[Rh(NH3)5L]4+, photocytotoxic agent, a 92
(x-)(PPh3)RhIII-OEP, -TPP, laser photolysis, a 133
ROMP, norbornenedicarboxylic acid ester, a 186
Ruthenium, addition to, Mg-Ni, for H storage 28
Pt-Pd-Rh, mechanical properties 111
electrodes, a 38, 133, 184
in fuel cells, see Fuel Cells
Pd/Ru/p-GaN ohmic contacts, a 92
recovery, from nuclear waste 74, 123
RuTiN, as diffusion barrier, in memory capacitors, a 187
thin films, by atomic layer deposition, a 133
Ruthenium Alloys, membranes 166
nanoparticles 28
Pt-Al-Ru, Pt-Ti-Ru 142
RuTa, shape memory effect, a 132
Ruthenium Complexes, luminescence, a 89, 133
photoconversion 19, 38
photoproperties, a 89
+ PP, + PS, in mass spectrometry, a 88
Ru carbene, chiral, a 37
Ru carbonyls, by carbonylation of RuCl3·3H2O, a 37
[RuCl2(p-cymene)]2, reaction with diphosphine, a 37
[RuIIClII(DMSO)2semicarbazone], Chagas’ disease 87
mer -[RuCl3(dppb)(py)], in LB films, a 134
RuCp2, for atomic layer deposition, a 133
Ru(II)-arenes, antimicrobial properties, a 136
Ru(III) polyaminocarboxylates, NO scavengers, a 136
Ruthenium Compounds, electrodes, a 184, 187
[Ru5C(CO)15], gas sensor activity, a 89
RuCl3·3H2O, carbonylation, a 37
[SiW11O39RuIII(H2O)]5-, [SiW11O39RuIVORuIIISiW11O39]11- a 88
Schottky Barriers, Pt/C60 interface, a 92
SCRT, for diesel emission control 157
Selective Catalytic Reduction, NOx 157
Semiconductors, photosensitisation 2, 61
Sensitisers, visible light, chloro-pgm-titania 2, 61
Sensors, acetylcholine, choline, a 185
CH4 72
CO, a 89, 185
glucose, a 38, 185
H2 89, 166
H2O2, a 185
H2S, a 89
O2, a 133
pellistor 72
SO2, a 89
taste: HCl, NaCl, quinine, sucrose, a 134
Shape Memory Effect, Fe-Pd 37, 58
Fe-Pd-Pt, a 37
Pt3Al, PtFe3, PtTi, (Pt, Ni)Ti 142
RuTa, a 132
TiPdNi, a 184
Single Crystals, Ba3LiOs2O9, Ba3NaOs2O9, a 132
Solvent Extraction, Pd, Rh, Ru 74, 123
Sonogashira Couplings, a 91
Sorbitol, from glucose 13
L-Sorbose, oxidation, a 185
Sputtering, Ir-Re coatings, a 38
Pt ultrathin films, a 89
Sugars, Pd(II) complexes, a 184
Sulfur, in diesel, gasoline 96
Sulfur Oxides, SO2, sensor, a 89
Superelastic Properties, TiPdNi, a 184
Suzuki Couplings, a 39, 91, 134, 135
Suzuki-Miyaura Couplings, a 90, 135
Thermolysis, Pd4(CO)4(OCOR)4 20
Thin Films, Ir, by MOCVD, a 133
Ru, by atomic layer deposition, a 133
ultra-, Pt, on porous GaN, electroless etching, a 89
see also Films
Three-Way Catalysts 13, 15, 96, 157
Titanium, substrates, for electrodeposition of Rh, a 38
TiO2, deposition, of pgms, pgm oxides 2, 61
Trihalomethanes, dehalogenation, a 186
Ureas, from amines, a 91
5-Vinyloxazolidin-2-ones, carbonylation, a 90
VOCs, destruction, by semiconductor photocatalysis 61
Water, oxidation, photocleavage, photoreduction 2
photocatalytic purification 61
as solvent, for catalytic reactions 60, 174
supercritical, oxidation, of spent catalysts 163
Water Gas Shift Reaction 28, 40
Welding, laser, of dental alloys, a 187

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