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Platinum Metals Rev., 1961, 5, (4), 161

SUBJECT INDEX TO VOLUME 5

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Acetaldehyde, manufacture, a 154
Anodic Protection,
  of iron and alloy steels, a 117
  theory of, a 117
Bushings, Rh-Pt, for glass fibre manufacture 51
Catalysis,
  heterogeneous, a study, a 35
  homogeneous, using Ru complexes 88
Catalysts,
  in petroleum industry, new U.S.A. patents, a 116, 155
  Palladium, black, synthesis of H 2O 2, a 115
    colloidal, hydrogenation of
    alkylacetylenes & phenylacetylene, a 35
    hydrogenation of vinylacetylene, a 34
    film, deuteration of cyclohexene, a 116
    hydrogenolysis of ethyl halides, a 155
    heterogeneous reactions with deuterium & hydrogen, a 35
    hydrogenation of C6H6, a 35
    reduction of HNO3 plant tail gas, a 116
  Pd/AI 2O3, decomposition of N20, a 75
    hydrogen adsorption on, liquid phase, a 155
    hydrogenation of cycloolefins, a 76
    hydrogenation of C2.H2 in C2H4 plant, a 75
    synthesis of H2O 2, a 115
  Pd/BaCO3, synthesis of penicillin derivatives 131
  Pd/BaSO4, hydrogenation of monovinyl-acetylene, a 154
  Pd/C, decarbonylation of aromatic aldehydes, a 117
    hydrogenation activity of 122
    hydrogenation of cycloolefins, a 76
    hydrogenation of fatty oils, a 35
    hydrogenation of methyl oleate, a 35
    synthesis of H20 2. a 115
  Pd/Si02, hydrogenation of C2H2 & C2H4, a 75
    synthesis of H 202, a 115
  Pd/SrCO2, hydrogenolysis of ketosteroids, a 36
  Pd/Th02, hydrogen-oxygen recombination, a 36
  Pd/WO3, synthesis of H 2O2, a 115
  PdCI2, CH3CHO manufacture, a 154
    oxidation of olefins, a 114
    reactions with olefins, a 36
  PdO/Al203/Si02, effect of irradiation on, a 115
  Pd-Pb, hydrogenation of linolenic acid, a 154
  Pd-Ru, hydrogenation of C2H2, NO & COS in coke oven gas, a 75
  Platinum, colloidal, hydrogenation of nitrocompounds, a 114
    dissociation of hydrogen & oxygen, a 76
    film, hydrogenolysis of ethyl halides, a 155
    deuteration of cyclohexene, a 116
    gauze, for HNO8 manufacture 54
    heterogeneous reactions with deuterium & hydrogen, a 35
    hydrogen-oxygen reaction, a 36
    isomerisation of n -pentane, a 155
    oxidation of CO in hydrogen, a 35
    oxidation of hydrogen, CO & CH4, a 115
    platinised, in liquid phase hvdrogenation, a 115
    reaction between NH3 & NO, a 115
    reaction with N2O, a 36
    reduction of HNO3 plant tail gas, a 116
    reforming 9, 101
  Pt/Al2O3, activity & physical properties, a 37
    aromatisation of hydrocarbons, a 154
    decomposition of N2O,a 75
    dehydrogenation of methylcyclohexane, a 77
    hydrogen adsorption on, liquid phase, a 155
    isomerisation of n -pentane, a 37
    reforming, aging of, a 115
    in U.S.S.R., a 155
    poisoning by thiophene, a 37
  Pt/AI2O3/SiO2, hydrogenation of n -nonane, a 37
    hydrogenation of saturated bicyclic hydrocarbons, a 115
    reforming, a 115, 154
  Pt/Cd, decomposition of H2O2, a 76
  Pt/C, hydrogenation of furans, a 36
    in hydrosen-oxysen fuel cells, a 76
  Pt/MgO, cyclodehydrogenation of N,N´-diphenylphenylenediamines, a 155
  Pt/pumice, hydrogenation of methylene-cyclopropane & methylenecyclobutane, a 75
  Pt/SiO2, hydrogenation of C6H6 a 76, 117
    hydrogenation of hydrocarbons, a 114
    reforming, a 115, 154
  PtCl„ activation of molecular hydrogen, a 116
  PtO, hydrogenation of C6H5N02 & CH3NO2 a 114
  PtO 2, activation of molecular hydrogen, a 116
    hydrogenation of cyclohexenes, a 76
    hydrogenation of cycloolefins, a 76
    hydrogenation of hydroxybenzenes, a 155
  Pt-Li, colloidal, hydrogenation of cyclohexene, a 11
  Platinum Metals, electron-transfer reactions in solution, a 36
    hydrogenation & dehydrogenation, a 35
    in organic chemistry, a 114
    on pumice, hydrogenation of cyclopropane & methylcyclopropane, a 75
    petroleum refining, review, a 37
    polymerisation of acetylenic compounds, a 35
    reduction of HNO3 plant tail gas, a 37, 116
    oxides, hydrogenation of organic compounds, a 116
  Rhodium, film, decomposition of C2H6 a 154
    hydrogenolysis of ethyl halides, a 155
    heterogeneous reactions with deuterium & hydrogen, a 35
    oxidation of CO in hydrogen, a 35
    reduction of HNO3plant tail gas, a 116
  Rh/AI2O3, decomposition of N2O, a 75, 154
    hydrogenation of hydroxybenzenes, a 155
  Rh/C, hydrogenation of furans, a 36
  Rh-Pt. oxidation of CO in hydrogen, a 35
    gauze, in HNO3 manufacture, a 116
  Rh-Pt Oxide, hydrogenation of organic compounds, a 116
  Ruthenium, oxidation of CO in hydrogen, a 35
  RuCI8Complexes, hydrogen reduction of Ruiv & FeIII, a 155
  Ru Complexes, hydrogenation of olefinic compounds 88
  RuO2, hydrogenation of pyridines, a 115
Cathodic Protection,
  impressed current anodes for, a 77
  Pt-Pd anodes for, a 77
  theory of, a 117
  of water heaters 12
Cermets, rare earth-Pd, fabrication of 56
Deuterium, absorption by Pd, a 111
Diodes, Ir-Pt wire 95
Electrical Contacts,
  Ir-Pt, in moving coil relay 143
  mechanism of material transfer, a 156
  Pd, effect of other materials on, a 38
  Pd-Ag, effect of other materials on, a 38
  Pt metals, light duty 42
  surface contamination of, a 156
  telephone switching, a 156
Electrodeposition of,
  Palladium, survey, a 113
  Platinum, a 34, 113
  Rhodium, addition of Al, Mg & Se, a 153
    survey, a 113
    to specification 13
  Ruthenium, a 113
Electrodes,
  Ir-Pt, microelectrode, a 74
  Palladium, absorption & evolution of hydrogen by, a 113
    effect of adsorbed anions on behaviour of, a 152
  Pd-H, electrical phenomena of, a 113
    proton transfer with Pd-Pt-H electrodes, a 33
  Pd-H-H 2, impedance of, a 112
  Pd-Pt-H, proton transfer with Pd-H electrodes, a 33
  Pd-Ti, behaviour in H2SO4, and HCl electrolytes, a 152
  Platinum, anodes, for cathodic protection, a 77
    anodes, in removal of chloride contaminants from HNO3 128
    anodic behaviour in H2SO4, a 112
    behaviour in HCl, a 74
    bright, anodic passivation of, a 152
    disc, determination of diffusion coefficients, a 33
    double layer capacity in molten LiCl-KCl, a 73
    effect of a.c. on corrosion of, a 112
    effect of irradiation on, a 112
    effects of anodic electrolysis on, a 112
    effects of γ-radiation on, a 73
    e.m.f. measurement at glass-refractory interface, a 33, 156
    exchange current in redox solutions, a 74
    hydrogen evolution on, a 34, 113
    hydrogen overpotential on, a 152
    in the solion, a 11
    oxide films on, a 33
    potential in an irradiated H2SO4 solution, a 112
    surface changes, a 34
    surface oxidation of, a 152
    use in baths of oxygenated salts, a 74
  Pt-clad brass, in anodic protection, a 117
  Pt oxide, electrochemical reactions at, a 152
  Pt/Pb, bielectrodes, in chloride solutions, a 112, 113
  Pt/Ta/Ti, anodes, for cathodic protection 12
  Pt/Ti, effect of a.c. on corrosion of, a 112
    electrochemical applications, a 153
    in chlorine cell, a 112
  Pt/C/Cl, potential of, a 74
  Pt-Au, exchange current in redox solutions, a 14
  Pt-Pd, absorption & evolution of hydrogen, a 113
    anodes, for cathodic protection, a 77
  Pt-Ti, behaviour in H2SO4 & HCI electrolytes, a 152
  Rhodium, hydrogen evolution on, a 113
  Rh-Pd-H, catalytic activity & electronic structure, a 33
Electroless Plating of
  Palladium, a 153
  Platinum, a 153
  Rhodium, a 153
  Ruthenium, a 153
Fuel Cells, intermediate temperature, a 153
Furnace, platinum, for production of optical glass 126
  in powder camera 96
  Pt-lined, fluorination 92
  Rh-Pt wound, in microscope 139
  with Rh-Pt-Al2O3 ring elements, a 153
Gas Recombination, catalytic, hydrogen-oxygen, a 36
Glass, effect of Pt metals on crystallisation 117, 140
  fibre manufacture 51, 156
  optical, continuous melting of 126
  Pt-to-Pyrex seals, a 34
  uses of Pt in production of, a 38
  wetting of Pt by, a 117
Hydrogen, adsorption on Pt black, a 111
  diffusion through Pd, a 74, 111
  isotopes, exchange on Pd, a 111
Hydrogenation,
  of C2H2, a 75
  of alkylacetylenes & phenylacetylene, a 35
  of C6H6 a 35, 76, 117
  of cyclohexenes, a 76, 77
  of cycloolefins, a 76
  of cyclopropane, a 75
  of C2H4 a 75
  of fatty oils, a 35
  of hydroxybenzenes, a 155
  of linolenic acid, a 154
  of methyl oleate, a 35
  of monovinylacetylene, a 154
  of nitrocompounds, liquid phase, a 114
  of n -nonane, a 37
  of olefinic compounds 88
  of pyridines, a 115
  of saturated bicyclic hydrocarbons, a 115
  of vinylacetylene, a 34
Hydrogen Peroxide, synthesis, a 115
Iridium,
  adsorption of hydrogen & oxygen, a 33
  discovery of 146
  high-temperature oxidation, a 110
  magnetic susceptibility, a 110
  vaporisation of, a 151
Iridium Alloys,
  Iridium-Platinum, tensile creep properties 144
    thermal & magnetic properties, a 31
    potentiometer windings in artificial horizons 57
  lridium-Tellurium, constitution, a 30
Iridium Trioxide, thermodynamic data, a 31
Lithium-Rhodium Hydryls, preparation of Li4RhH4 & Li4RhH5, a 71
Magnets, permanent Co-Pt, processing & properties 82
Nitric Acid Manufacture, dual pressure process at Ardeer, a 116
  intermediate pressure NH3 oxidation 54
  tail gas reduction, a 37
  use of Pt metal catalysts, a 116
Osmium,
  discovery of 146
  melting point, a 32,109
  spectral emissivity, a 109
Osmium Alloys,
  Osmium-Boron, crystal structure, a 150
  Osmium-Tantalum, constitution, a 110
Osmium Carbide, preparation & crystal structure, a 70
Osmium Oxides, mass spectrometric study of, a 31
Oxidation,
  of hydrogen, CO & CH„ a 115
  of olefins, a 114
Oxygen Gauge, construction, a 154
Palladium,
  absorption of deuterium by, a 111
  absorption of hydrogen by, a 72, 73, 113
  addition to Ti & stainless steel, a 151
  adsorption of hydrogen & oxygen, a 33
  anodic oxidation, a 73
  dehydrogenated, excess free energy, a 110
  desorption of hydrogen & deuterium from, a 72
  diffusion of hydrogen through, a 34, 74, 111
  elastic constants, a 32
  exchange of hydrogen isotopes, a 111
  high temperature oxidation of, a 110
  magnetic susceptibility, a 110
  on SiO2 glass, adsorption of C2H2 & C2H4 a 75
  prevention of hydrogen embrittlement of Ta, a 14
  vapour pressure, a 32
Palladium Alloys,
  Palladium-Carbon, with Mg, Al, Zn, Ga, Ge, Cd, In, Sn, Hg, Tl & Pb, crystal structure, a 149
  Palladium-Chromium-Hydrogen, magnetic properties, a 70
  Palladium-Chromium-Titanium, corrosion resistance, a 111
  Palladium-Cobalt, magnetic properties, a 150
  Palladium-Cobalt-Hydrogen, Hall effect in, a 150
  Palladium-Copper, thermodynamic properties, a 71
  Palladium-Copper-Nickel, solid solubility of C in, a 111
  Palladium-Copper-Silver, solid solubility of Cin, a 111
  Palladium-Hydrogen, α-Pd-H, electrical resistance, a 151
    desorbed, electrical resistivity & thermoelectric power, a 73
    diffusion of hydrogen, a 72
    electrical properties, a 30, 111, 113
    heat capacity & resistivity anomalies, a 151
    hysteresis, a 72
    optical properties, a 72
    physical properties & constitution 21
  Palladium-Iron, intermelallic diffusion of γFe&Pd, a 150
    magnetic properties, a 32, 150
  Palladium-Iron-Nickel, melting points, a 110
  Palladium-Iron-Silver, constitution, a 109
  Palladium-Manganese, magnetic properties, a 150
  Palladium-Molybdenum-Titanium, corrosion resistance, a 111
  Palladium-Nickel, electrical resistivity, a 109
    Hall effect & resistivity, a 70
    intermetallic diffusion of Ni & Pd, a 150
    magnetic properties, a 32, 150
    thermoelectric properties, a 109
  Palladium-Nickel-Hydrogen, electrical properties, low temperature, a 30
  Palladium-Platinum, hydrogen absorption by, a 30, 113
    hydrogen evolution by, a 113
    tensile creep properties 144
  Palladium-Rhodium, thermal & magnetic properties, a 31
  Palladium-Rhodium-Gold, constitution & properties, a 109
  Palladium-Samarium, use in cermet production 56
  Palladium-Silicon-Chromium, use in high temperature brazing, a 114
  Palladium-Silver, brushes in artificial horizons, 57
    optical properties, a 149
    use for electrical contacts, a 156
  Palladium-Silver-Hydrogen, pressure-concentration-temperature relationships 21
  Palladium-Titanium, constitution & properties, a 109
    corrosion resistance, a 32, 72, 111, 151, 152
  Palladium-Tungsten, constitution, a 149
Palladium Chlorides, at high temperature, a 71, 110
Palladium Complexes, magnetic properties, a 31
Palladium Nitrides, structure, a 32
    Penicillins, synthesis of 131
Petroleum Refining, heterogeneous catalysis processes, review, a 37
  Platforming Saharan naphthas, a 75
  reforming, in China 101
  reforming of Bakinski gasoline, a 155
  reforming, review, a 37, 154
Platinised Carbon, adsorption of Cs & Br, a 32
Platinum,
  activities of Mn in, a 71
  adsorption of hydrogen & oxygen, a 31
  atomic diffusion in Au, a 71
  black, adsorption of hydrogen, a 111
  Brownrigg’s investigations, 18th century 66
  chemical plant, a 38
  chemical reactions at surface of, a 151
  complex hydrides, a 110
  contamination by fission products, a 30
  cores for oxide cathodes, a 77
  effect on crystallisation of glass, a 117, 156
  effect on strength of devitrified glass, a 156
  electrochemical corrosion of, a 153
  Faraday’s lecture 26
  films, oxygen absorption at, a 151
  high temperature oxidation, a 110
  history of 18
  magnetic susceptibility, a 110
  mining at Rustenburg 102
  oxidation of, a 150
  prevention of hydrogen embrittlement of Ta, a 74
  seals for Pyrex glass, a 34
  screen, support for fused salts, a 34
  specific heat, a 31
  structural chemistry, a 32
  tensile creep nronerties 144
  use in passivation of Ti in HCI, a 73
  vapour pressure, a 32
  wetting by glass, a 117
Platinum Alloys,
  Platinum-Carbon, with Mg, Al, Zn, Ga, Ge, Cd, In, Sn, Hg, TI, & Pb, crystal structure, a 149
  Platinum-Cobalt, Platinax II, properties & applications 82
  Platinum-Gold, Kirkendall effect & diffusion in, a 149
    miscibility & critical point, a 32
    precipitation in, a 70
    tensile creep properties 144
    thermal & magnetic properties, a 31
  Platinum-Hydrogen, electrical resistance, a 31
  Plalinum-Iridium, tensile creep properties 144
    thermal & magnetic properties, a 31
  Platinum-Iron, magnetic properties, a 32
    modulus of elasticity & internal friction in Fe3Pt, a 72
  Platinum-Magnesium, constitution, a 32
  Platinum Niobium, constitution, a 109
  Platinum-Palladium, hydrogen absorption by, a 30
    tensile creep properties 144
  Platinum-Rhodium, constitution & properties 58, 97
    film, preshadowing in electron microscopy, a 74
    tensile creep properties 144
  Platinum-Ruthenium, tensile creep properties 144
  Platinum-Silver, ageing of, a 149
  Platinum-Titanium, corrosion resistance, a 32, 151, 152
  Platinum-Zirconium, constitution, a 149
Platinum Complexes, magnetic properties, a 31
Platinum Compounds, sulphides, selenides & tellurides, a 71
Platinum Nitrides, structure, a 32
Platinum Oxide, anodic, electrochemical properties, a 152
  thermodynamic data, a 31
Platinum Metals, arsenides of, structures, a 150
  borides of, properties & structure 93
  in chemical plant construction, a 77
  effect on crystallisation of glass 140
  gaseous oxides of, thermodynamics of 134
  industrial uses, a 31
  intermediate phases with rare earths, Sc, Y, Hf, & Th, a 72
  phosphides of, properties & structure 93
  production & uses 101
  refractory, properties of 19
  silicides of, properties & structure 93
  tensile properties, a 30
Platinum Metal Alloys, high temperature oxidation, a 110
  with C, solidus temperatures, a 70
  with Cr, corrosion resistance 141
  with Ti, Zr or Hf, constitution, a 110
Radiation Source, high temperature, a 157
Resistance Thermometers, platinum 89
  platinum, calibration of, a 156
  platinum, for use at high temperatures, a 77
  platinum, measurement of fast-changing temperatures, a 156
Rhodium, adsorption of hydrogen & oxygen, a 33
  high temperature oxidation, a 110
  magnetic susceptibility, a 110
  specific heat, a 31
  vaporisation of, a 151
Rhodium Alloys
  Rhodium-Palladium, thermal & magnetic properties, a 31
  Rhodium-Palladium-Gold, constitution & properties, a 109
  Rhodium-Platinum, constitution & properties 58, 97
    tensile creep properties 144
Ruthenium,
  chemisorption of hydrogen on surface, a 151
  high temperature oxidation, a 110
  magnetic susceptibility, a 110
  melting point & spectral emissivity, a 109
  powder metallurgy of, a 113
Ruthenium Alloys,
  Ruthenium-Boron, crystal structure, a 150
  Ruthenium-Gadolinium, magnetic properties, a 70
  Ruthenium-Gadolinium-Cerium, magnetic properties, a 70
  Ruthenium-Iron, constitution, a 30
  Ruthenium-Molybdenum, constitution, a 71
  Ruthenium-Platinum, tensile creep properties 144
  Ruthenium-Tantalum, constitution, a 110
  Ruthenium-Tungsten, constitution, a 110
Ruthenium Carbide, preparation & crystal structure, a 70
Ruthenium Chlorides, gaseous, thermodynamic properties, a 110
Ruthenium Hexafluoride, preparation of, a 150
Ruthenium Phosphide, structure, a 109
Ruthenium Tetroxide, adsorption on SiO2 gel, a 71
Ruthenium Trioxide, preparation, a 71
Solion, operating principles & applications, a 77
Spinnerets, Pt alloy, viscose rayon production 2
Tantalum, prevention of hydrogen embrittlement by Pt metals, a 74
Temperature Measurement, Fourth Symposium, review 89
  in C atmospheres, a 117
  in vacuum radiation furnace, a 118
  of average & differential temperatures, a 156
  with Pt metal thermoelements, a 78
Thermocouples,
  Gold-Palladium-Platinum : Gold-Palladium 89
  Iridium: graphite, use in C atmospheres, a 117
  Iridium: Iridium-Rhodium, for high temperatures 89
    contamination of 132
  Palladium-Gold :Rhodium-PIatinum, in calorimetry, a 38
  Platinum :Rhodium-PIatinum, calibration of, a 118
    contamination of 132
    effect of pressure on e.m.f. of, a 118
    effects of radiation on 89
    properties & applications, a 78
  Rhodium-Platinum :Rhodium-Platinum, a 118
  Platinum Metals, properties & applications, review, a 78
Titanium, corrosion & passivation of, a 73
Viscose Rayon, production of 2

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