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Platinum Metals Rev., 1962, 6, (4), 165

Subject Index To Volume 6

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Aromatic Hydrocarbons, production from petroleum 86, 157
   
Bursting Discs, Pt, protection of chemical plant 42
   
Catalysis,  
behaviour of Pt metals, a 122
in petroleum refining, a 158
Catalysts,  
Adams’, history of 150
H2PtCl2, additon of HSiCl3, to olefins, a 157
In petroleum industry, recent U.S.A. patents a 80
Ir/C, dehydrogenation of dihydrofurans, a 122
Noble Metal, hydrocracking, a 120
Os/Al2O3, hydrogenation of unsaturated hydrocarbons 12
Os/C, dehydrogenation of dihydrofurans, a 122
OsC4, oxidation of olefins, a 122
Palladium, black, isotopic exchange of. p -xylene with D2O, a 157
detoxication of, a 159
film, conversion of cyclohexene and cyclohexadiene, a 121
exchange of n-hexane and deuterium, a 79
exchange of polymethylcyclopentanes with deuterium, a 159
Raney-type, for fuel cell electrodes 136
supported, activation by irradiation, a 36
activity in hydrogenation, a 79
surface area of, a 122
Pd/Al2O3, hydrogenation of C2-fraction, a 158
hydrogenation of C3-fractions, a 157
hydrogenation of linolenate, a 157
isomerisation of paraffins, a 157
oxidation of CO, a 34, 37
oxidation of CH,, a 34
Pd/BaSO4, hydrogenation of acetylenes, a 120
hydrogenation of C6H5COCl, a 159
hydrogenation of cycloalkanes, a 34
nuclear reduction of pyrimidines, a 158
Pd/B2O3/Al2O3, isomerisation of paraffins, a 157
Pd/CaCO3, hydrogenation of acetylenes, a 120
Pd/C, activation by irradiation, a 120
dehydrogenation of α, β-unsaturated lactams, a 35
hydrogenation of acetylenes, a 120
hydrogenation of cycloalkanes, a 34
hydrogenation of fatty acids, a 34
hydrogenation of α-keto acids, a 79
hydrogenation of linolenate, a 157
hydrogenation of nitrosamines, a 159
nuclear reduction of pyrimidines, a 158
production of margarine, a 158
reduction of aromatic nitro compounds, a 121
Pd/SiO2 gel, synthesis of HSO2, a 35
Pd/ThO2, detoxication of, a 159
Pd/zeolite, isomerisation of C5 and C6, paraffins, a 33
Pd/Re/Al2O3, isomerisation of alkanes, a 159
PdCl2, oxidation of olefins, a 79, 120
oxidation of propylene, a 80
PdCl2-olefin complexes, vinylation, a 37
Pd(OH)2/C, hydrogenation of α-keto acids, a 79
Platinum, black, isotopic exchange of p --xylene with D2O, a 157
oxidation of SO2, a 36
decomposition of acid H2O, solutions, a 34
evaporation rate, a 35
film, conversion of cyclohexene and cyclohexadiene, a 121
exchange of polymethylcyclopentanes with deuterium, a 159
hydrogen isotope exchange, a 121
thermal pretreatment of, a 37
gauze electrode, a 33
hydrocracking, a 119
hydrogenation of C6H6, a 159
hydrogenation of unsaturated com pounds, a 157
oxidation of SO2, a 36
petroleum refining, a 157
platinised, electrochemical oxidation and hydrogenation of, a 120
Raney-type, for fuel cell electrodes 136
reduction of aqueous CoSO4-NH4 (C2H3O2) solutions, a 80
reforming, a 35
effect of S on activity and selectivity, a 81
reforming and hydroisomerisation, a 37
supported, activation by irradiation, a 36
oxidation of CO, a 33
oxidation of ethylene glycol, a 121
reforming, a 35
synthesis of HCN 9
synthesis of polysaccharides, a 37
wire, decomposition of HCOOH, a 158
Pt/Al2O3, adsorption of hydrogen, oxygen and CO by, a 119
C5-debydrocyclisation of iso- C8,H18, a 119
crystallite size, a 36
dehydrocyclisation of n -heptane, a 35
dehydrogenation and dehydrocyclisation of hydrocarbons, a 159
effect of γ-irradiation on activity, a 81
hydrogenation of linolenate, a 157
isomerisation of paraffins, a 157
isomerisation of n -C5H12, a 121
light transmission and scattering of, a 159
oxidation of enamelling fumes, a 34
oxidation of CH,, a 34
poisoning by S, a 121
reforming, a 157
in W. Europe 86
valence state of Pt, a 79
Pt/Al2O3/B2O3, isomerisation of paraffins, a 157
Pt/Al2O3/Cl, sintering of, a 80
Pt/Al2O3,/SiO2, hydrocracking, a 33, 36
PtCdO, decomposition of H2O2, a 36
Pt/C, activation by irradiation, a 120
addition of SiHCl3 to acetylenes, a 80
dehydrocyclisation of iso -C3H13, a 80
effect of method of preparation on activity, a 81
heavy water production, a 121
hydrogen-liquid NH3, isotope exchange, a 79
hydrogenation of linolenate, a 157
hydrogenation of nitrosamines, a 159
isomerisation of paraffins, a 157
temperature dependence of activity, a 34
Pt/C/Al2O3, C5-dehydrocyclisation of iso- C8H,„a 119
Pt/C/SiO2, C5-dehydrocyclisation of iso- C8H18, a 119
Pt/oxide supports, activity in hydrogenation, a 79
Pt/rare earth oxides, decomposition of H2O2, a 159
Pt/SiO2, C8-dehydrocyclisation of iso- C8H18, a 119
hydrogen-liquid NH3 isotope exchange, a 79
isomerisation of paraffins, a 157
Pt/silk, preparation and activity, a 78
properties, a 78
Pt/Ni/AI2O3, decomposition of NO, a 80
Pt-Pd, supported, oxidation of ethylene glycol, a 121
Pt(II)-Olefin Complexes, addition of = Si-H,a 119
PtO2, Adams’ 150
hydrogenation of aromatic hydro carbons, a 156
hydrogenation of disubstituted benzenes, a 120
hydrogenation of linolenate, a 157
nuclear reduction of piperidines, a 158
Platinum Metals, in fuel cell electrodes, 8, 119
hydrogenation and dehydrogenation, a 34
hydrolysis of NaBH,, a 156
polybutadiene preparation 135
preparation by NaBH4 reduction, a 156
synthesis of HCN, a 35
on A12O3, conversion of cyclanes and alkanes, a 78
hydrogenation of unsaturated hydrocarbons, a 122
on SiOa gel, conversion of cyclanes and alkanes, a 78
Rhodium, film, cracking of C2H6 158
exchange of n-C6H14 and deuterium, a 79
exchange of polymethylcyclopentanes with deuterium, a 159
Raney-type, for fuel cell electrodes 136
Rh/Al2O3, hydrogenation of N -benzylidine- butylamine, a 35
hydrogenation of α-substituted benzyl alcohols, a 159
Rh/C, dehydrogenation of dihydrofurans, a 122
hydrogenation of N -benzylidinebutyl-amine, a 35
hydrogenation of nitrosamines, a 159
hydrogenation of substituted pyridines, a 36, 81
RhCl3, polymerisation of 1,4-butadiene 46
Rh(NO3)3, polymerisation of 1,4-butadiene 46
Rh-Pt Oxide, preparation, activity and selectivity, a 79
Ruthenium, hydrogenation of pyridines, a 81
synthesis of paraffin waxes 94
Ru/Al2O3, hydrogenation of unsaturated hydrocarbons 12
Ru/C, dehydrogenation of dihydrofurans, a 122
Ru2(CO)9, carbonylation of allene, a 36
RuCl2, homogeneous hydrogenation of olefinic compounds, a 120
RuCI3, carbonylation of allene, a 36
hydration of acetylenic compounds, a 78
polymerisation of butadiene 135
surface measurements of, a 158
Cathodic Protection, effect on cavitation damage 57
methods and applications, a 122
Pt anodes for, a 122
   
Deuterium, exchange with polymethylcyclo-pentanes, a 159
Diffusion Cells, for hydrogen purification, a 156
Ag-Pd, for hydrogen purification 47, 130
   
Electrical Contacts,  
Cu-Pd, material transfer properties, a 37
Pt and Pd, metal transfer, a 37
Rh and Pd, electrodeposited, a 123
Pt Metals, surface films on, a 122
transfer-inductance characteristics of 10
Electrodeposition of Iridium, from aqueous solution, a 78
from molten cyanide electrolytes, a 118
Palladium, a 78, 119
for electrical engineering, a 119
on telephone plugs and sockets 52
Platinum, for electrical engineering, a 119
from molten cyanide electrolytes, a 118
on thermionic grid material 147
Noble Metals, properties and applications, a 156
Rhodium, for electrical engineering, a 119
thickness measurements, a 78
Ruthenium, from molten cyanide electro lytes, a 118
Electrodes,  
Iridium, hydrogen adsorption by, a 118
in spark plugs 92
Palladium, in fuel cells 136
Pd-H, coexisting α- and β-phases, a 156
Pd-H-H2, hydrogen overvoltage and hydro gen diffusion, review. 22
Platinum, adsorption of anions on, a 118
anodes, for cathodic protection, a 122
effect of a.c. on corrosion of 100
oxidation of CH3OH, a 156
surface phenomena at 48
black, a 118
in Cl2-Cl-H2O system, a 118
effect of organic molecules on adsorptive properties, a 77
in fuel cells 136
hydrogen adsorption by, a 118
reduction of chemisorbed oxygen on, a 118
in silicate melts, a 33
in the solion, a 123
Pt/C, powder, a 118
in solutions containing CI, a 118
Pt-clad Ta, anodes, for cathodic protection studies 57
Pt/Ti, anodes, for cathodic protection, a 122
effect of a.c. on corrosion of 100
Pt-Pd, anodes, for cathodic protection, a 122
Platinum Metals, in hydrogen-oxygen fuel cells, a 77
Rhodium, in fuel cells 136
hydrogen adsorption by, a 118
Rh-Pd, hydrogen overvoltage at, a 11
Electroless Plating of  
Palladium, a 119
Platinum Metals, a 119
   
Fuel Cells, low temperature 8
Furnace, for HCN synthesis 9
Pt-wound, for glass devitrification studies 49
   
Glass, effect of Pt nucleation, a 38
fibre manufacture, a 81
Li2O.4SiO2, effect of Pt as a nucleating agent, a 81
tubing, manufacture of 59
wetting of Pt, a 38
   
Heavy Water, pilot-plant production of, a 121
Hydrogen Purification, diffusion cell for 47, 130
Hydrogenation of  
acetylenes, a 120
C6H6, a 156, 159
C6H5COCl, poisoning, a 159
C=N linkage 35
disubstituted benzenes, a 120
fatty acids, a 34
fatty oils, a 158
methyl linolenate, a 157
nitrosamines, a 159
olefinic compounds, a 120
polymethylbenzenes, a 156
substituted pyridines, a 36
C6H5CH8, a 156
unsaturated compounds, a 157
unsaturated hydrocarbons 12,122
Hydrogen Cyanide, synthesis 9
Hydrogen Peroxide, synthesis, a 35
   
Immersion Plating, of Pd 144
Iridium, adsorption of hydrogen, C2H8, C2H4 and C2H2 on, a 155
sources for γ-radiography 11
spark plug electrodes for aero engines 92
thermal conductivity and electrical resistivity 138
vapour pressure, a 32
Iridium Alloys,  
Iridium-Boron, crystal structure, a 153
Iridium-Chromium, superconductivity, a 116
Iridium-Magnesium, constitution, a 115
Iridium-Palladium, constitution, a 153
Iridium-Palladium-Silver, constitution and properties, a 75
Iridium-Silicon, structure and composition, a 115
Iridium-Thorium, crystal structure of Thlr, a 115
Iridium Carbonyl Complexes, substitution and exchange reactions in, a 117
Iridium Dioxide, oxygen pressures of formation 137
   
Magnets, permanent Co-Pt 56
in flow meter 98
   
Osmium, thermal conductivity and electrical resistivity 138
Osmium Alloys,  
Osmium-Boron, crystal structure, a 153
Osmium-Rhenium, constitution, a 153
Osmium-Ruthenium, constitution, a 153
Osmium-Silicon, structure and composition, a 115
Osmium-Tungsten, constitution, a 31
Osmocene, ring substitution reactions of, a 117
Oxidation of CO, a 33, 34, 37
enamelling fumes, a 34
ethylene glycol, a 121
CH4, a 34
olefins, a 122
C3H6, a 80
SO2, a 36
   
Palladium, adsorption of CO, a 32
coatings, properties, a 119
electrical properties, a 76
heat of adsorption of hydrogen on, a 155
hydrogen diffusion and solubility in, a 156
immersion plating of 144
molten, density, a 76
sorption of NO, a 116
surface oxidation, a 76
thermal conductivity and electrical resistivity 138
vapour pressure, a 32, 155
Palladium Alloys, for brazing, a 156
Palladium-Cadmium, electrical and magnetic properties, a 76
Palladium-Cobalt, magnetic properties of Pd3Co and PdCo, a 154
Palladium-Copper, contact properties, a 37
Hall effect, a 116
heat of formation, a 153
high-temperature brazing, a 33
thermoelectric properties, low temperature, a 116
Palladium-Deuterium, phase diagram, a 32
Palladium-Gold, effect of plastic deformation on resistivity, a 31
electrical and magnetic properties, a 76
electrical resistance and Hall constant, a 77
high-temperature brazing, a 33
Palladium-Gold-Nickel, constitution and properties, a 153
Palladium-Hydrogen, α-Pd-H, electrical resistance of, a 155
electrical resistance in aqueous solutions, a 116
phase diagram, a 32
physical properties, a 116
structure of α- and β-phase hydrides, a 155
Palladium-Indium, electrical and magnetic properties, a 76
Palladium-Iridium, constitution, a 153
Palladium-Iridium-Silver, constitution and properties, a 75
Palladium-Iron, magnetic properties of Pd„Fe and PdFe, a 154
oxidation of, a 117
thermoelectric properties, low temperature, a 116
Palladium-Iron-Cobalt, phase changes in, a 75
Palladium-Manganese, thermoelectric properties, low temperature, a 116
Palladium-Mercury, crystal structure, a 115
Palladium-Molybdenum, electrical and magnetic properties, a 76, 154
Palladium-Molybdenum-Titanium, corrosion resistance and mechanical properties, a 117
Palladium-Nickel, high-temperature brazing, a 33
thermoelectric properties, a 116
Palladium-Niobium, constitution and prop erties, a 75
electrical and magnetic properties, a 76
Palladium-Rhodium, electrical and magnetic properties, a 76
Parladium-Rnodium-Platinum, tensile and creep properties 148
Palladium-Rhodium-Silver, constitution and properties, a 31
Palladium-Ruthenium, electrical and magnetic properties, a 76
structure and properties, a 154
Palladium-Silver, constitution and proper ties, a 76
electrical and magnetic properties, a 76
electrical resistivity, a 154
Hall effect, a 116
heat of adsorption of hydrogen on, a 155
heat of formation, a 153
high-temperature brazing, a 33
hydrogen diffusion and solubility in, a 156
in hydrogen diffusion cells 47, 130
for hydrogen purification 47, 130
wetting properties, a 33
Palladium-Tellurium, constitituon and properties, a 75
Palladium-Tin, thermoelectric properties, low temperature, a 116
Palladium-Titanium, corrosion resistance, a 33
Palladium-Tungsten, electrical properties, a 154
Palladium-Zirconium, electrical and magnetic properties, a 76
with Ag, Cd, In, Rh, Ru, Mo, Nb, Zr, or V, electrical resistance and Hall constant, a 143
Palladium Chlorides, high temperature properties, a 32
Palladium Complexes, with 6-mercaptopurine, in cancer research 91
Petroleum Refining, hydrocracking, new noble metal catalyst, a 120
isomerisation of C5 and C6 paraffins, a 33
at Kalundborg, Denmark, a 80
at Misburg, W. Germany, a 80
reforming, a 35
at Erdölwerke Frisia refinery, Emden, a 120
review, a 34
in W. Europe 86
reforming and hydroisomerisation, a 37
Platinum, adsorption of fatty amines, a 117
adsorption of hydrogen, a 32
black, hydrogen and oxygen adsorption by, a 76
bursting discs 42
coating of Mo, diffusion studies 147
coatings, properties, a 119
cores for oxide cathodes, a 37, 160
effect on crystallisation of glass, a 38, 81
films, contact potential in, a 155
gauze, platinised, catalytic hydrogenation contact, a 33
heats of adsorption of He, Nc, Ar, and Kr on, a 155
junctions in thermoelectric generator 99
metallurgy of, early experiments recorded by Casanova 28
mining in Alaska 68
molten, density, a 76
surface tension, a 76
oxidation of, a 31
Percival Johnson’s first paper, 1812 112
resistivity 77, 138
surface oxidation, a 76
surface properties, a 117
surface structure, study by field ion microscopy 95
in Telstar satellite 143
thermal conductivity and electrical resis tivity 138
vapour pressure, a 32
wetting, by fluorinated heptadecanoic acids, a 117
by glasses, a 38
Platinum/Carbon, hydrogen and oxygen ad sorption by, a 76
Platinum Alloys,  
Platinum-Barium, thermionic work function, a 32
Platinum-Bismuth, constitution, a 153
Platinum-Calcium, thermionic work function, a 32
Platinum-Chromium, magnetic properties of Cr0.3Pt0.7, a 154
Platinum-Cobalt, corrosion resistant permanent magnets 56, 98
heat of formation, a 153
permanent magnet, remanence, a 77
structure, a 31
Platinum-Copper, heat of formation, a 153
thermoelectric properties, low temperature, a 116
Platinum-Gold, constitution and properties 60, 106
Platinum-Iron, activities of Fe in, a 154
thermoelectric properties, low temperature, a 116
Platinum-Manganese, magnetic properties of MnPt3, a 154
thermoelectric properties, low temperature, a 116
Platinum-Palladium-Silver, wetting proper ties, a 33
Platinum-Rhodium, emissivity, a 77
heating element for microscope, a 78
in manufacture of glass tubing 59
Platinum-Rhodium-Palladium, tensile and creep properties 148
Platinum-Silver, wetting properties, a 33
Platinum-Strontium, thermionic work function, a 32
Platinum-Tin, thermoelectric properties, low temperature, a 116
Platinum-Tungsten, oxidation of, a 115
with Al, Sc, Mg, Ca, Sr and Li, preparation, a 31
Platinum Complexes, with 6-mercaptopurine, in cancer research 91
Platinum Hexafluoride, preparation and properties, a 76
Platinum Metals, effect of molten NaOH and KOH on, a 31
high-temperature properties 58
prevention of hydrogen embrittlement of Ta, a 32
properties and applications, a 155
sensitisers in photographic emulsions 27
Platinum Metal Alloys, with Si and C, a 154
Polybutadiene, preparation 46
Pyrometers, immersion, in steel temperature measurement 2
   
Radiography, Ir192 as source 11
Resistance Thermometers, platinum, a 81
platinum, calibration, a 160
development of, a 123
modified Mueller bridge for, a 123
Rhodium, coatings, properties, a 119
electrodeposited, thickness measurements, a 78
high-purity, temperature coefficient of electrical resistance, a 155
thermal conductivity and electrical resistivity 138
vapour pressure, a 32, 77
Rhodium Alloys,  
Rhodium-Bismuth, constitution, a 115
Rhodium-Chromium, superconductivity, a 116
Rhodium-Iron, electrical and magnetic properties of FeRh, a 154
Rhodium-Palladium, electrical and magnetic properties, a 76
Rhodium-Palladium-Silver, constitution and properties, a 31
Rhodium-Platinum, emissivity, a 77
heating element for microscope, a 78
in manufacture of glass tubing 59
sheaths for thermocouples 126
Rhodium-Silicon, structure and composition, a l15
Rhodium-Thorium, crystal structure of ThRh2, a 115
Rhodium Carbonyl Complexes, substitution and exchange reactions in, a 117
Rhodium Chlorides, high temperature proper ties, a 32, 116
Rhodium Hexafluoride, physical and chemical properties, a 32
Ruthenium, thermal conductivity and electrical resistivity 138
Ruthenium Alloys,  
Ruthenium-Boron, crystal structure, a 153
Ruthenium-Chromium, constitution, a 75
superconductivity, a 116
Ruthenium-Nickel, constitution and properties, a 75
Ruthenium-Niobium, oxygen solubility in, a 116
Ruthenium-Osmium, constitution, a 153
Ruthenium-Palladium, electrical and magnetic properties, a 76
structure and properties, a 154
Ruthenium-Rhenium, constitution and properties, a 115
Ruthenium-Silicon, structure and composition, a 76,115
Ruthenium-Silver, wetting properties, a 33
Ruthenium-Tantalum, constitution, a 75
Ruthenium-Thorium, crystal structure of ThRu, a 115
Ruthenium Chlorides, high temperature proper ties, a 32
RuCI3,complex formation in aqueous solutions, a 117
Ruthenium Dioxide, oxygen pressures of formation 137
Ruthenium Hexafluoride, physical and chemical properties, a 32
Ruthenocene, ring substitution reactions of, a 117
   
Solion, operating principles and applications, a 124
   
Tantalum, prevention of hydrogen embrittlement of, by Pt Metals, a 32
Temperature Measurement, of gas turbine engine exhaust 126
of high transient surface temperatures 149
in open-hearth steelmaking 2
Thermal Analysis, of grey iron 20
Thermocouples, Iridium: Iridium-Rhodium, reference tables, a 160
Platinum: Rhodium-Platinum, effect of junction of uncertainty, a 160
gas turbine engine combustion tests 126
in immersion pyrometers 2
in iron foundry 20
open-contact, spring-loaded 149
Pt-clad, for glass studies 49
Platinum Metals, a 81
properties and limitations, review, a 160
Rhodium-Platinum: Rhodium-Platinum, calibration 96
Thermoelectric Generator 99
   
Uranium-Fissium Alloys, structure and proper ties, a 115

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